Vidic, 14:00 R16 ENERGY Yun-Nuo Chi (yuc69@pitt.edu) reaction. The majority of the gas is then filtered out of the reaction chamber except for a small quantity trapped inside the petroleum produced, and will be released into the air when it is burned. The gas has been declared harmless by recent tests. Short term exposures to small quantities of metal gas will not effect the body. In other words, no immediate sickness will occur. However, because metal gas does not exist naturally, and is a relatively new chemical to us, the long term effects on the environment and humans remains unknown. The testing process will take up to 5 years because the wide use of petroleum will make the affected area tremendous. Once BP adopts the reaction process, metal gas will be released into the environment everywhere in the world where petroleum is used. Not only do we need to understand how metal gas affects the human body, the impact it could have on the environment also needs to be evaluated. For instance, metal gases have been know to break apart the O3 layer when released in large quantities. Since the gas is released in small quantities, it will not effect the Ozone layer, but as we increase utilization of this reaction process, more and more metallic gas will be released into the atmosphere; the effect it has in small quantities can accumulate and pose as a potential threat. Also, metals gas can affect the pH of rain, just like sulfur dioxide. The change in pH could effect the soil where metal gas is released and impact the crops around it. Ponds and rivers could also be effected by the change in pH; many plants and animals rely on a constant pH to survive. A change in ±1.3 pH could affect 10% of agricultural plants [4]. All of these are potential consequences of using metal gas. The good news is, tests conducted so far are offering promising positive results. Although the results are positive so far, cases such as Thalidomide has forced us to handle new chemicals with extreme care. Thalidomide was considered a wonder drug when it was first discovered. Women would take it to relieve morning sickness and it worked like a charm. But the drug was not tested properly and the laboratories never tested the drug on pregnant animals. As it turns out, Thalidomide can cause the babies of pregnant women to be deformed. It took over 15 years and 15,000 deformed children before the doctors linked the birth defects to the drug [3]. Another example of harmful consequences to humans because of the lack of understanding of newly discovered chemicals is the discovery of X-rays. Wilhelm Röntgen discovered X-rays in 1895. He named X-radiation to signify an unknown type of radiation. Later on all the researchers that were exposed to X-rays died of cancer. Therefore, it is essential to have a good understanding of new chemicals and reaction processes before utilizing them. 1. INTRODUCTION Extreme energy, a term coined by Hampshire College professor Michael Klare, refers to energy that is extremely hard to get; energy that requires ripping apart the earth: for instance by heating up the ground so that the oil in the tar sand formation of Canada can flow to the surface. Or by tearing holes in the crust a mile beneath the surface of the sea, as British Petroleum was doing when the Deepwater Horizon well exploded.[1] We as humans have attempted, time after time, to get energy from nature no matter the cost. We could have taken the dwindling supply and rising prices of oil as a signal to convert to sun, wind, and other none carbon forms of energy. Instead we’ve taken it as a signal to scour the world for more hydrocarbons [1]. The extreme methods led to the explosion of Deepwater Horizon Well. The explosion released 4.9 million barrels of oil into the Gulf of Mexico. The spill had an enormous effect on the wildlife of the surrounding area: killing countless animals and destroying their homes. Incidents such as this make us take a step back and think: is it worth destroying our environment over energy resources? The individualistic business theory states that the only obligation of a company is to make a profit. The company can do whatever it takes to make a profit, as long as they stay within the legal boundaries. In this particular incident, BP did not purposefully do anything unethical because the accident was a result of mechanical failure [2]. However, BP knew about the potential hazard that drilling in the area could cause, and chose to go forward with it. Sometimes, ethical dilemmas can not be labeled right and wrong; only after the event plays out does the decision result in good or bad outcomes. How we can strike a balance between business profits and environment protection is perhaps one of the hardest questions to answer. An opportunity to do business with the oil giant, British Petroleum, turned out as an ethical dilemma. The company offered a handsome amount of money to buy the research on turning BTEX into octane, the main component of petroleum. The research proposed a pathway of utilizing metal complexes as the catalyst, but a byproduct, metal gas, turns out to be a problem. More time is needed to confirm the properties of the metal gas. Despite the lack of information on the newly discovered metal gas, BP plans on installing the process at the end of the year. 2. METAL GAS Metal gas is released when the metal complex, titanium polyhydride, is returned to its original form at the end of the University of Pittsburgh, Swanson School of Engineering 2014-10-28 1 Chi, Yun-Nuo no matter what we do, petroleum is going to be harmful to the environment. The job of a petroleum engineer is to lower the “adverse impacts” as low as possible. The use of metallic complex fits the description potentially. Turning BTEX into petroleum would decrease the adverse impact petroleum is imposing on the atmosphere. 3. BTEX There is no room for error when it comes to new chemicals. On one hand, no tests have been able to prove that metal gas can cause harm to humans. On the other hand, BTEX, a chemical that is removed by a metal complex, is a known carcinogen. BP is only interested in incorporating metal complexes into their production process to increase production of petroleum, but BTEX is removed nonetheless. The question becomes, would the benefit of removing BTEX outweigh introducing a new chemical metal gas? By adopting the process early, BP would eliminate over 2 hundred thousand tons of BTEX from gasoline every year [6]. Furthermore, metal complexes can unlock the aromatic compounds that are inaccessible in biomass. More than 50% of organic compounds found in plants that are used to produce bio-fuels contain aromatic functional groups [7]. These aromatic functional groups cannot be used as biofuel because they are inactive. But with metallic complexes, the previously untouched energy stored in aromatic functional groups can be unlocked, resulting in a higher percent yield of biofuel from plants. The increased production would lower the price of biofuel and make sustainable energy even more effective. Sustainable energy alone is an intriguing reason to introduce metallic complexes into the production of petroleum. 5. BRITISH PETROLEUM The negative impacts of petroleum is unavoidable. But has the petroleum companies tried to minimize the negative impacts has on the environment, or are they only focused on maximizing profits? A quick search revealed that BP is not particularly known to be an environmental friendly company. According to McClatchyDC, British Petroleum, is notorious for their ethical violations. The London-based company has a penchant for putting profits ahead of just about everything else [9]. A review of BP's history reveals a pattern of ethically questionable and illegal behavior that goes back decades. BP's best known disaster took place in 2005, when an explosion at its refinery in Texas City near Galveston killed 15 workers, injured 180 people and forced thousands of nearby residents to remain sheltered in their homes. An investigation of the explosion by the U.S. Chemical Safety and Hazard Investigation Board blamed BP for the explosion and offered a scathing assessment of the company. It found "organizational and safety deficiencies at all levels of the BP Corporation [9]." Another instance took place in 2006. Despite warnings from a leak detection system, a badly corroded 34-inchdiameter pipeline in Prudhoe Bay leaked oil for at least five days before a worker driving down a nearby service road on March 2, 2006 smelled oil and spotted the spill, which covered at least two acres of tundra. Rep. Joe Barton, RTexas, suggested BP had decided to "bet the farm" that the pipeline wouldn't fail before Prudhoe Bay would run out of oil, saving it the cost of replacement. He accused the company of fostering a "corporate culture of seeming indifference to safety and environmental issues [9]." The approach BP has toward environmental precautions is worrying. If the metal gas turns out to have the slightest negative impact on the environment, the company would more than likely try to hide the results from the general public and keep producing the toxins. 4. ETHIC CODES According to the NSPE code of ethics for engineering: “Engineers are encouraged to adhere to the principles of sustainable development in order to protect the environment for future generations.” Sustainable development as defined by NSPE is the challenge of meeting human need for natural resources, energy and effective waste management, while conserving and protecting environmental quality and the natural resource base essential for future development. The results of incorporating metal complexes would definitely be a sustainable development, therefore be in line with the code. Ironically, installing metallic complex would also violate the NSPE code. The use of metallic complexes would introduce a potential threat, metal gas, to the environment. Petroleum is a product known to produce hazardous byproducts, and the industry is well aware of it. Past hazardous products such as carbon monoxide, sulfurous dioxide, nitrogen oxide and many other gas emissions are only dealt with after they have caused harm to the environment. Petroleum engineers have accepted the unavoidable negative impact petroleum has on the environment; according to the Society of Petroleum Engineers Ethic Code: “Engineers should seek to adopt technical and economic measures to render potentially adverse impacts to environment or the health, safety, and security of the public as low as realistic [8].” In other words, 6. OUTSIDE THE BOX Speeches given by motivational speakers, pastors, and even professors have stimulate conversation on such controversial topics. Greg Rowe once presented a decisionmaking framework, and one of the question depicted was: Would I mind having information regarding the decision publicized? If every action that the corporations take is announced to the public, would they make the same 2 Chi, Yun-Nuo decisions? Shouldn’t these big corporations who have such a huge impact on our environment be held responsible for their actions? Who get to decide what is more harmful and what is less harmful? Who gets to decide what level of harm is acceptable? A friend in the pharmaceutical field looked at it this way: He compared the situation to a treatment used on drug addicts when they go through rehabilitation. The treatment replaces the drug the addicts were taking with a weaker drug. The treatment is helpful for the patient even though the weaker drug would still harm the patient. Similarly, BTEX is a carcinogen, making it the stronger drug; Metal gas is not yet proven to be toxic, making it weaker compared to BTEX. According to this analogy, substituting BTEX with metal gas actually protects the environment even though metal gas is potentially harmful. Not burdening the environment is the ultimate goal, but at the present time it is not practical. Reducing the damage petroleum has on the environment is a more practical goal to strive for. [5] J. Dawson (2008). “Application of luminescent biosensors for monitoring the degradation and toxicity of BTEX compounds in soils.” Journal of applied Microbiology. (book). [6] Dr. Frederic Leusch and Dr. Michael Bartkow (2010). “A short primer on benzene, toluene, ethyl benzene and xylenes (BTEX) in the environment.” Smart Water Research Centre. (research paper). [7] (2009). “Towards Sustainable Production and Use of Resources: Assessing Biofuels.” United Nations Environment Programme. (UN website). www.unep.org [8] Board of directors (2013). “Code of conduct.” Society of Petroleum Engineers. (website). http://www.spe.org/about/docs/professionalconduct.pdf [9] Richard Mauer and Anna M. Tinsley (2010). “Gulf oil spill: BP has a long record of legal, ethical violations” McClatchyDC. (online article). http://www.mcclatchydc.com/2010/05/08/93779_bp-has-along-record-of-legal.html?rh=1 CONCLUSION ACKNOWLEDGEMENTS The negative impact of petroleum on the environment is unavoidable; lowering its impact, however, is achievable, and metallic complex is one of the ways to achieve it. How the new technology is handled also plays an important role in lowering the negative impact. Metal gas will likely be feared when it is first introduced to the public, and rightly so; metal gas should be monitored and handled with extreme care. BP, however, is not the company to be trusted with this delicate research. The use of metal complex will benefit the environment only if metal gas is monitored and treated with extreme care, and the researcher should bear the responsibility of making sure such measures will be put in place by the hands that receive the research. I gratefully acknowledge Colleen Chi for helping me revise this writing assignment, and Dan Long, high school organic chemistry instructor, for offering great insight on the subject. REFERENCES [1] Dr. Carl Mitcham (2012). “Extreme Energy & Ethics: Type I and Type II Analyses” National Academy of Engineering. (speech). www.onlineethics.org/Topics/Enviro/Energy/EnergyAPPE2 012/APPEMitcham2012.aspx [2] John Farrell. (2013, April 15). British Petroleum Deepwater Horizon Oil Spill. Business ethics cases. (online article). http://businessethicscases.com/2013/04/british-petroleumdeepwater-horizon-oil.html [3] S. V. Rajkumar (2004). “Thalidomide: Tragic Past and Promising Future.” Mayo Clinic Procedures 79:7 (Book). [4] Organic Gardening (2010). “Understanding pH” Organic Gardening. (Online Article). http://www.organicgardening.com/learn-andgrow/understanding-ph?page=0,0 3