Unit Theme Day 1 Date 2/20 Unit 4: Bonding Chm.1.2: Understand the bonding that occurs in simple compounds in terms of bond type, strength, and properties. Chm.1.2.1: Compare (qualitatively) the relative strengths of ionic, covalent, and metallic bonds. Chm.1.2.2: Infer the type of bond and chemical formula formed between atoms. Chm.1.2.3: Compare inter- and intra- particle forces. Chm.1.2.5: Compare the properties of ionic, covalent, metallic, and network compounds Standard(s) Student Friendly Topic Example/Rigor Chm.1.2.1 Which statement describes the Identify the type of bond compound formed between Describe metallic bonds: “metal ions between two atoms sodium and oxygen? plus ‘sea’ of mobile electrons” 2 2/23 3 2/24 a. It is NaO2, which is ionic. b. It is NaO2, which is covalent. c. It is Na2O, which is ionic. d. It is Na2O, which is covalent. Chm.1.2.2 Determine that a bond is predominately ionic by the location of the atoms on the Periodic Table (metals combined with nonmetals) or when EN > 1.7. Determine that a bond is predominately covalent by the location of the atoms on the Periodic Table (nonmetals combined with nonmetals) or when EN < 1.7. Chm.1.2.2 Predict chemical formulas of compounds using Lewis structures. Chm.1.2.5 Apply Valence Shell Electron Pair Repulsion Theory (VSEPR) for these electron pair geometries and molecular geometries, and bond angles - Electron pair - Molecular (bond angle); Linear framework – linear; Trigonal planar framework– trigonal planar, bent; Tetrahedral framework– tetrahedral, trigonal pyramidal, bent; Bond angles (include distorting effect of lone pair electrons – no specific angles, conceptually only) Draw ionic Lewis and covalent Lewis structures Draw the Lewis structure of MgCl2. Predict the shape of a molecule based on VSEPR theory The shape of CO2 is best described as ___________. 4 5 2/25 2/26 Chm.1.2.3 Explain why intermolecular forces are weaker than ionic, covalent or metallic bonds Explain why hydrogen bonds are stronger than dipole-dipole forces which are stronger than dispersion forces Apply the relationship between bond energy and length of single, double, and triple bonds (conceptual, no numbers). Describe intermolecular forces for molecular compounds. H-bond as attraction between molecules when H is bonded to O, N, or F. Dipole-dipole attractions between polar molecules. London dispersion forces (electrons of one molecule attracted to nucleus of another molecule) – i.e. liquefied inert gases. Relative strengths (H>dipole>London/van der Waals). Chm.1.2.5 Explain how ionic bonding in compounds determines their characteristics: high MP, high BP, brittle, and high electrical conductivity either in molten state or in aqueous solution. Explain how covalent bonding in compounds determines their characteristics: low MP, low BP, poor electrical conductivity, polar nature, etc. Explain how metallic bonding determines the characteristics of metals: high MP, high BP, high Define intermolecular forces. Identify the intermolecular forces between 2 molecules At STP, fluorine is a gas and iodine is a solid. Why? a. Fluorine has lower average kinetic energy than iodine. b. Fluorine has higher average kinetic energy than iodine. c. Fluorine has weaker intermolecular forces of attraction than iodine. d. Fluorine has stronger intermolecular forces of attraction than iodine. Predict the properties of a substance. An unknown substance is tested in the laboratory. The physical test results are listed below. Nonconductor of electricity Insoluble in water Soluble in oil Low melting point Based on these results, what is the unknown substance? a. ionic and polar. b. ionic and nonpolar. c. covalent and polar. d. covalent and nonpolar. 6 7 2/27 3/2 conductivity, malleability, ductility, and luster. Describe bond polarity. Polar/nonpolar molecules (relate to symmetry) ; relate polarity to solubility—“like dissolves like” Describe macromolecules and network solids: water (ice), graphite/diamond, polymers (PVC, nylon), proteins (hair, DNA) intermolecular structure as a class of molecules with unique properties. Cumulative Activity / Unit Wrap-Up / Lab Unit Test