FIRE SAFETY TEST CENTRE «CIS NIIJB-POLIGON» (LLC)
REGISTRED IN THE RUSSIAN FEDERATION STATE REGISTER
Registration code № ТРПБ.RU.ИН25 validity up to 24.08.2015
 (499) 172-86-28
 info@fire-lab.ru
k.2, 22, Ryazansky prospekt, Moscow,
postcode 109428
Test results apply to the tested samples only.
No part of this report may be reproduced or
reprinted without the prior written
permission of the «CIS NIIJB-POLIGON»
(LLC)
«Approved»
Head of the certification centre
«POZH-AUDIT»
V.M. Gubin
16 feb 2012
TEST REPORT
№ C-2/02-2012
Microencapsulated extinguishing agent (composite) «AST»,
designed for use in autonomous fire extinguishing system
designed by
Standard of the organization
STO 13525135-005-2010
OKP Code 48 5480
Head of the fire safety test centre
«CIS NIIJB-POLIGON»
A.V. Shelkovsky
16 feb 2012
FIRE SAFETY TEST CENTRE «CIS NIIJB-POLIGON» (LLC)
№ C-2/02-2012 dated 16.02.2012 г.
Total pages 14
Page 1
CONTENTS
1. The name and the address of the applicant, manufacturer. ................................... 3
2. The specification of the test subject. ..................................................................... 3
3. Official reason for testing. ..................................................................................... 3
4. Description of the service being ordered. ............................................................. 3
5. Test methods. ......................................................................................................... 3
6. Sampling procedure............................................................................................... 3
7. Test procedure. ...................................................................................................... 3
8. Test equipment. ..................................................................................................... 6
9. Measuring means................................................................................................... 7
10. Test results........................................................................................................... 8
11. Executors. ............................................................................................................ 9
SUPPLEMENTARY INFORMATION ................................................................... 10
Appendix 1. ............................................................................................................. 11
Appendix 2. ............................................................................................................. 13
FIRE SAFETY TEST CENTRE «CIS NIIJB-POLIGON» (LLC)
№ C-2/02-2012 dated 16.02.2012 г.
Total pages 14
Page 2
1. The name and the address of the applicant, manufacturer.
Applicant:
Manufacturer:
Certification Centre «POZH-AUDIT». Address: k.1, h.5, 1st Vyazovsky
proezd, Moscow, Russia, post code 109428.
Telephone: +7 (495) 740-43-61.
Closed Joint Stock Company «Pirohimika». Address: h.4, Pokrovka street,
Moscow, Russia, post code 101000.
Telephone: +7 (495) 933-53-13.
2. The specification of the test subject.
Microencapsulated extinguishing agent (composite) «AST», designed for use in
autonomous fire extinguishing system (hereinafter - the composite). The composite is designed
for extinguishing fire (classes A, B, C, E according to the GOST 27331-87) in small volumes
(switchboards, electrical cabinets, control cabinets, storage values, small vaults, located in areas
with operating temperature range from − 40 °C to + 40 °C) without human intervention.
The thickness of the specimen made of a composite — 3,0 mm.
Color of the sample — white, with a slight yellow tinge, not transparent, with visible
reinforcing fibers.
3. Official reason for testing.
Tests were conducted on the basis of an internal purchase order for works № 01A/VZN-12
dated 31.01.2012 from the certification centre «POZH-AUDIT» and the contract № 01-01/I-12
dated 26.01.2012 between FIRE SAFETY TEST CENTRE «CIS NIIJB-POLIGON» (LLC) and
Closed Joint Stock Company «Pirohimika».
4. Description of the service being ordered.
Testing to determine the next indicators of fire danger:
- a group of smoke-forming ability according to the GOST 12.1.044-89*;
- an indicator of toxicity according to the GOST 12.1.044-89*;
- group of combustibility according to the GOST 30244-94
5. Test methods.
Determination of a group of smoke-forming ability (test method according to the GOST
12.1.044-89*).
Determination of a toxicity (test method according to the GOST 12.1.044-89*).
Determination of a group of combustibility (test method according to the GOST 3024494).
6. Sampling procedure.
The sampling was made using the technique of random selection by the expert of the
certification centre «POZH-AUDIT» from the manufacturer’s store as provided by the sampling
act № 01/AO-12 dated 30.01.2012 (Appendix 1).
7. Test procedure.
The test was performed at «CIS NIIJB-POLIGON» from 30.01.2012 to 16.02.2012.
FIRE SAFETY TEST CENTRE «CIS NIIJB-POLIGON» (LLC)
№ C-2/02-2012 dated 16.02.2012 г.
Total pages 14
Page 3
7.1. Environmental conditions during the testing.
Name of condition
Ambient temperature
Barometric absolute pressure
Relative humidity
Speed of the wind
Value
17-20 °С
745-757 mm Hg
50-66 %
< 0,5 м/сек
7.2. The order of testing procedure.
7.2.1. Determination of a smoke-forming ability.
Test.
10-15 samples of invistigated material sized 40x40 mm of actual thickness were prepared
for the test.
Before the test prepared samples were kept at temperature 20 ± 2 °С not less than 48 hours,
than were weighed with not more than 0,01 g.
The testing of the samples was performed in two modes: smouldering mode and burning
mode (with gas burner with the length of the flame from 10 to 15 mm).
The sample was chambered in a combustor, that was equipped with a heat-radiating panel,
which made 35 kW/m2 density of the heat flow, falling on the sample.
Smoke-forming ability is an indicator, that defines optical density of smoke, that is
produced in a smouldering mode or in a burning mode in a standard volume.
Classification.
According to the point 9 article 13 of the federal law № 123 «Technical regulations of the
fire safety requirements» dated 22.07.2008 the following groups of smoke-forming ability are
destinguished:
1) with low smoke-forming ability (group «D1»), with a smoke generation factor less than
50 m /kg
2
2) with moderate smoke-forming ability (group «D2»), with a smoke generation factor not
less than 50 m2/kg, but not more than 500 m2/kg;
3) with high smoke-forming ability (group «D3»), with a smoke generation factor more
than 500 m2/kg;
7.2.2. Determination of a group of combustibility.
Test
4 vertically oriented samples sized 1000x190 mm were fixed in a holder and exposured to
88 MJ/h gas burner output during 10 minutes. Emitted gases temperature and the time of self
burning were registred. After carrying out the test of the samples’ weight loss and the extent of
damage to the length were estimated.
Classification
According to the point 5 article 13 of the federal law № 123 «Technical regulations of the
fire safety requirements» dated 22.07.2008 the following groups combustibility are
destinguished:
1) low-combustible (group «G1») with the smoke temperature not more than 135 °С,
extent of damage to the length of a sample not more than 65 %, extent of damage to the sample’s
weight not more than 20%, 0 sec self burning time;
2) moderately-combustible (group «G2») with the smoke temperature not more than
FIRE SAFETY TEST CENTRE «CIS NIIJB-POLIGON» (LLC)
№ C-2/02-2012 dated 16.02.2012 г.
Total pages 14
Page 4
235 °С, extent of damage to the length of a sample not more than 85 %, extent of damage to the
sample’s weight not more than 50%, self burning time not more than 30 seconds;
3) normally-combustible (group «G3») with the smoke temperature not more than 450 °С,
extent of damage to the length of a sample not more than 85 %, extent of damage to the sample’s
weight not more than 50%, self burning time not more than 300 seconds;
4) high-combustible (group «G4») with the smoke temperature more than 450 °С, extent of
damage to the length of a sample more than 85 %, extent of damage to the sample’s weight more
than 50%, self burning more than 300 seconds.
According to the point 6 article 13 of the federal law № 123 «Technical regulations of the
fire safety requirements» dated 22.07.2008 the formation of burning melt drops during the test is
not allowed for the G1-G3 combustibility group materials (for the G1-G2 combustibility group
materials isn’t allowed the formation of melt drops).
7.2.3. Determination of a toxicity.
Preliminary test
In process of preliminary test the temperature of self burning and the temperature of
smouldering is being determined.
10 samples sized 40x40 mm of actual thickness were used for the test. The samples were
kept under laboratory conditions not less than 48 hours and were weighed with not more than
0,01 g error.
Preliminarily the samples were exposured to heat flow of various density, providing the
rise of sample’s temperature on 50 °С in each following test. At the time the temperature of the
smouldering mode test of material was found (it must be 50 °С lower than the sample’s self
ignition temperature).
Primary test.
Materials are tested in one of two modes – smouldering mode or burning mode,
specifically in the mode, that promotes release of more toxic volatile substances composites.
Burning mode is provided with 750 °С test temperature (density of falling heat flow is
65 kW×m-2). Primary test mode selection criterion is the greatest number of fatal outcomes in
comparison groups of experimental animals.
During the primary test in a chosen mode a range of values of combustion product toxic
action to the value of sample weight to installation cubature ratio relation is found. To get the
toxic effect below and above 50% fatal rate, the exhibition chamber cubature is changed while
the materials’ sizes remain the same.
8 white mice of 20 ± 2g weight were used in each test. The exposition time was 30
minutes. During exhibition time the air temperature in the prechamber didn’t exceed 30 °C, and
the oxygen concentration was not less than 16 % (volume).
Derived range of lethality to material relative weight relation values is used to calculate
toxicity indicator 𝐻𝐶𝐿50 (g × m-3). The calculation is made by the means of probit analysis and
other methods of average lethal doses and concentrations calculation.
In the case the value of 𝐻𝐶𝐿50 that was derived during the material test is close to the two
classes limit value, the test mode, sample decomposition time, combustion product composition
facts, information about detected compounds toxicity are considered when the material risk class
is being determined.
FIRE SAFETY TEST CENTRE «CIS NIIJB-POLIGON» (LLC)
№ C-2/02-2012 dated 16.02.2012 г.
Total pages 14
Page 5
Classification.
According to the GOST 12.1.044-89* chart, the following toxicity groups are
discriminated:
𝑯𝑪𝑳𝟓𝟎 , g
Danger class
Extremely dangerous
Highly dangerous
Moderately dangerous
Low dangerous
5
Under 25
25-70
70-210
Above 210
m-3, at exhibition time, min
15
Under 17
17-50
50-150
Above 150
30
Under 13
13-40
40-120
Above 120
60
Under 10
10-30
30-90
Above 90
According to point 10 article 13 of the federal law № 123 «Technical regulations of the fire
safety requirements» dated 22.07.2008 and chart 2 of the appendix to this federal law the
following toxicity groups are destinguished:
1) Low dangerous (group «T1»);
2) Moderately dangerous (group «T2»);
3) Highly dangerous (group «T3»);
4) Extremely dangerous (group «T4»)
8. Test equipment.
Chart № 1
Serial
number
Equipment name
Installation for determination of solid substances and
materials smoke generation factor, “Smoke”
Installation for determination of polymeric materials
combustion products toxicity, “Toxicity”
Installation for determination of construction materials
combustibility group, “Shaft-furnace”
03
02
05
Certificate
№ 33-12
till 25.01.2013
№ 54-12
till 25.01.2013
№ 42-12
till 25.01.2013
FIRE SAFETY TEST CENTRE «CIS NIIJB-POLIGON» (LLC)
№ C-2/02-2012 dated 16.02.2012 г.
Total pages 14
Page 6
9. Measuring means.
Chart № 2
№
Name of production
characteristic (parameter)
being determined (measured)
Measuring tool name, type
(model), works number, year
of production
1
2
Transformation of subject’s
physical parameters
(temperature) into electric
signals
3
1
2
3
4
5
6
7
8
9
10
11
12
Thermocouples ТТ 41 ХА
Work number № 1-20, 2003
Electronic balance ВР-04 МС
2/5-1БР
№ 6873 , 2003
Rotameter with local
Volume gas consumption
indications РТКА-0,25 ГУЗ
measurement
№ 03350, 2005
Rotameter with local
Volume gas consumption
indications РТКА-0,63 ГУЗ
measurement
№6123119, 2005
Electronic anemometer ЭА-70
Speed of the wind
model ЭА-70(1) Works
measurement
number №20, 2010
Mechanical seconds counter
Test time lags measurement
СОПпр-2а-3-000
Works number № 4200, 2010
Calipers
External and internal
ШЦЦ-I-150 0,01
measurements
№ 105021
Metal measuring rule
Linear dimension measurement
0-1000 mm
Works number № 2, 2010
Metal tape measure 0-5 m
Linear dimension measurement Works number № without
number , 2010
Registration device
Physical parameters recording
«ТЕРЕМ 4.1»
Works number № 154, 2008
Portable device for absolute
Barometric absolute pressure pressure measurement Testomeasurement
622
№39500351/911
Measurement of relative air
Combined device Testo-622
humidity indoors. Temperature
№39500351/911
measurement
Weight measurement
Gas analyzer ИНФРАКАР М1.01, Works number № 92,
2003
13
Measurement of СО, СО2, О2,
СН content in gas environment
14
Gas analyzer KANE 940
Measurement of СО, СО2, О2 ,
Works number № 23607026,
NO content in gas environment
2008
Metrological parameters of
measuring tools
Class of
Measuring
accuracy,
range
measurement
error
4
5
Certificate of
measuring tools
verification, number,
duration
6
0 … +600 ºС
2
№ 25/29/2/11
till 1.02.2013
Up to 15 kg
(2-5) g.
№ 25/14/2/13
till 1.02.2013
Qmax (m3/hour)
2,5;
± 2,5 %
№ 25/10/2/23
till 1.02.2014
Qmax (m3/hour)
6,3;
± 2,5 %
№ 25/34/2/19
till 1.02.2014
0,2-30 m/sec
0,1 m/sec № 207/11 - 0658п
(0,2 – 5 m/sec)
till 14.04.2012
0 sec…60 min
Scale factor 0,2
sec
Certificate
№4282А/001000
till 20.01.2012
0-125 mm
±0,02 mm
№ 203-4107
till 14.12.2012
0 … 1000 mm
Scale factor 1
mm
№ 08-12
till 17.01.2013
0…5000 mm
Scale factor 1
mm
№ 09-12
till 17.01.2013
-50-1250 ºС
0,1 %
№ 25/29/2/37
till 1.03.2012
(300-1200) gPa
±3 gPa+1
№ 191508
till 16.12.2012
(10-98)%;
(0-50) ºС
±3 %
± 0,5 К +1.
№ 191508
till 16.12.2012
2%
till 12.04.2012
1%
till 14.04.2012
0 – 10 % СО;
0-5000 СН;
0-20 СО2;
0-25 О2
(0-25)% О2;
(0-10000) СО;
(0-5000) NO;
(0-5000) CO2;
FIRE SAFETY TEST CENTRE «CIS NIIJB-POLIGON» (LLC)
№ C-2/02-2012 dated 16.02.2012 г.
Total pages 14
Page 7
10. Test results.
Chart № 3.
Smoke generation factor determination. Test results.
Weight of
Transparency
Test mode
the
reference, %
finally, %
sample
1
3,71
100
68,8
2
3,72
100
67,3
Smouldering
3
3,77
100
67,5
4
3,80
100
66,8
5
3,83
100
66,5
Medium value in the smouldering mode Dm(av) =
68
1
3,63
100
75,0
2
3,74
100
75,4
Burning
3
3,79
100
75,7
4
3,85
100
70,2
5
3,91
100
71,1
Medium value in the burning mode Dm(av) =
53
Sample’s
number
Smoke generation
factor, m2/kg
66
69
68
69
69
m2/kg
52
49
48
60
57
m2/kg
Chart № 4.
Toxicity determination. Test results.
Testing
temperature
(most
dangerous), ºС
Time of
decomposition,
min
750
15
The loss of mass
of the sample
(converted to
CO),
g
6,05
the percentage of
gaseous
substances,
%
НСL50
g/m3
65,6
92,9
Chart № 5.
0 16
0 15
0 16
Simple
average
112
0
2
3
4
16
16
15
15
16
15
15
16
16
16
16
16
Damage to the length, sm
16
Samples’ weight, g
(simple average )
Before the After the
test
test
748
704
750
712
744
710
The extent of
damage to the
weight, %
112
114
111
1
The extent of
damage to the
length, %
Smoke
temperature, ОС
1
2
3
Self burning
time, sec
Test number
Combustibility group determination. Test results.
6
5
5
5
FIRE SAFETY TEST CENTRE «CIS NIIJB-POLIGON» (LLC)
№ C-2/02-2012 dated 16.02.2012 г.
Total pages 14
Page 8
Thereby the test results established that samples of the microencapsulated extinguishing
agent (composite) «AST» (designed by the standard of the organization STO 13525135-0052010, manufacturer — Closed Joint Stock Company «Pirohimika») belong to the following
groups:
-
moderately smoke generation ability according to the GOST 12.1.044-89* (group
«D2» according to the clause 13 of the federal law № 123 «Technical regulations of
the fire safety requirements»);
-
moderately dangerous materials by combustion products toxicity factor, according to
the GOST 12.1.044-89* (group «T2» according to the clause 13 of the federal law №
123 «Technical regulations of the fire safety requirements»);
-
low-combustible materials according to the GOST 30244-94 (group «G1» according
to the clause 13 of the federal law № 123 «Technical regulations of the fire safety
requirements»)
11. Executors.
Test engineer
________ N.Afonin
Quality deputy administrator
of the FIRE SECURITY TEST CENTRE
________ D.Borisov
FIRE SAFETY TEST CENTRE «CIS NIIJB-POLIGON» (LLC)
№ C-2/02-2012 dated 16.02.2012 г.
Total pages 14
Page 9
SUPPLEMENTARY INFORMATION
1. This report is neither a fire safety certificate nor a conformance certificate.
2. The report is valid during the period of time when no changes are made (not more than 3
years):
- to the production or test method normative documents;
- to organization and (or) methods of production.
3. In case aforementioned occurs, the Customer must send a message about it to the
laboratory, which performed a test. On the ground of these changes effect analysis, the
laboratory decides about the test report duration.
4. The information contained in the test report as well as the name of the test center and its
emblem may not be used for public advertising purposes or in any other way without the
written permission of the test center.
5. Pages with the test results statement may not be used separately without the full test
report.
6. The obtained results and conclusions contained in the report apply only to the tested
sample(s) and don’t reflect the quality of the production-run where this sample was taken
from as well as the quality of all the output of this type.
7. If not specifically mentioned, this report is intended only for the Customer’s use.
8. Tested samples that were not destroyed during the test as well as unused remains of
samples are returned to the Customer within 30 days from the moment of the report’s
issuance.
FIRE SAFETY TEST CENTRE «CIS NIIJB-POLIGON» (LLC)
№ C-2/02-2012 dated 16.02.2012 г.
Total pages 14
Page 10
Appendix 1.
Sampling report.
FIRE SAFETY SERTIFICATION SYSTEM
CERTIFICATION centre
«POZH-AUDIT»
REGISTRED IN THE RUSSIAN FEDERATION STATE REGISTER
REGISTRATION CODE № ТРПБ.RU.ПБ34 DATED 24.08.2010
109428, Moscow, 1 Vyazovskiy pass., 5, 1 +7(495)7404361, 7404362
Sampling report №01/AO-12 dated 30.01.2012
For certification testing
Product name: Microencapsulated extinguishing agent (composite) «AST», made in
accordance with STO 13525135-005-2010
For the compliance with the requirements of:
Technical Regulations of fire security requirements (State Law №123-ФЗ dated
22.07.2008)
In the store of “Pirohimika” CJSC, 101000, Moscow, Pokrovka st., 4,
We, an CC «POZH-AUDIT» expert
In the presence of “Pirohimika” representative
Were sampled the production, made in accordance with the technical documentation,
approved by Technical Control Department.
Samples construct, composition and production technology are identical to the ones of the
products, supplied to the customer.
Number (weight)
Scope of
of the samples
Name of the tested
Production
№
Measure Supply №
supply
sample
date
(units)
Tested control
1.
Microencapsulated
extinguishing
agent (composite)
«AST», made in
accordance with
STO 13525135005-2010
M2
-
100
12.2011
10
0.5
Sampling made in accordance to the contract
Samples are packing in tare
Marked with CC «POZH-AUDIT» label
Completed with documentation ___________
Given to the CC in accordance with contract
Storage conditions store
Tested samples are to be destroyed
Control samples are to be responsible storage by Client
FIRE SAFETY TEST CENTRE «CIS NIIJB-POLIGON» (LLC)
№ C-2/02-2012 dated 16.02.2012 г.
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Page 11
Conclusion to the product identification
1. Product name
Microencapsulated extinguishing agent
(composite) «AST», made in accordance with
STO 13525135-005-2010
2. Production country
Russian Federation
3. Manufacturer name and address
Pirohimika CJSC, Russia, 101000, Moscow,
Pokrovka st., 4
4. Additional information
Conclusion: tested production is identificated/can’t be identificated with the sample
and/or its description.
Appendix: Documents, approving product acceptance by manufacturer/buyer and its
compliance with the regulatory document under which production (or it’s copies) is
manufacturing.
Signs of the sampling members
Acquainted with report:
Chief director of
“Pirohimika” CJSC
CC expert:
______________ Bliznec I.V.
___________ Poedincev I.A.
January, 30, 2012
FIRE SAFETY TEST CENTRE «CIS NIIJB-POLIGON» (LLC)
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Page 12
Appendix 2.
Photos.
Photo. The samples before testing.
FIRE SAFETY TEST CENTRE «CIS NIIJB-POLIGON» (LLC)
№ C-2/02-2012 dated 16.02.2012 г.
Total pages 14
Page 13
Photo. The samples after testing.
FIRE SAFETY TEST CENTRE «CIS NIIJB-POLIGON» (LLC)
№ C-2/02-2012 dated 16.02.2012 г.
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