Acids, Bases, and the pH Scale If you look in your medicine cabinet and refrigerator and on your kitchen shelves, you will find examples of groups of compounds known as acids and bases. Acids are found in aspirin, vitamin C, and eyewash. Fruits such as oranges, grapes, lemons, grapefruit, and apples contain acids. Milk and tea contain acids, as do pickles, vinegar, and carbonated drinks. Bases are found in products such as lye, milk of magnesia, deodorants, ammonia, and soaps. Name & Uses Formula Strong Acids Hydrochloric Pickling steel; HCl digesting food; cleaning bricks Sulfuric Manufacturing H2SO4 paints, plastics and fertilisers; dehydrating agent Nitric Removing HNO3 tarnish; making explosives and fertilisers Weak Acids Carbonic Fizzy drinks H2CO3 Boric Washing eyes H3BO3 Phosphoric Making H3PO4 fertilisers and detergents Acetic Making (vinegar) cellulose HC2H3O2 acetate used in fibres and films Citric Making soft H3C6H5O7 drinks Properties of Acids As a class of compounds, all acids have certain physical and chemical properties when dissolved in water. One of the physical properties all acids share is a sour taste. Lemons taste sour because they contain citric acid. Vinegar contains acetic acid. However, you should never use taste to identify a chemical substance. You should use other, safer properties. Acids affect the colour of indicators. Indicators are compounds that show a definite colour change when mixed with an acid or a base. Litmus paper, a common indicator, changes from blue to red in an acid solution. Another indicator, phenolphthalein, is colourless in an acid solution. Acids react with active metals to form hydrogen gas and a metal compound. This reaction wears away, or corrodes, the metal and produces a residue. For example, sulphuric acid in a car battery often corrodes the terminals and leaves a residue. Another property of acids can be identified by looking at a list of common acids. What do all acids have in common? Acids contain hydrogen. When dissolved in water, acids ionise to produce positive hydrogen ions (H+). A hydrogen ion is a proton. So acids can often be defined as proton donors. The hydrogen ion, or proton, produced by an acid is quickly surrounded by a water molecule. The attraction between the hydrogen ion (H+) and the water molecule (H20) results in the formation of a hydronium ion (H30+). H+ + H20 H30+ The definition of an acid as a proton donor helps to explain why all hydrogen containing compounds are not acids. Table sugar contains 22 hydrogen atoms, but it is not an acid. When dissolved in water, table sugar does not produce H+ ions. Table sugar is not a proton donor so it does not turn litmus paper red or phenolphthalein colourless. Common Acids The three most common acids in industry and the laboratory are sulphuric acid, nitric acid, and hydrochloric acid. These three acids are strong acids. This means they ionise to a high degree in water and produce hydrogen ions. The presence of hydrogen ions makes strong acids good for conducting electricity. Acetic acid, carbonic acid, and boric acid are weak acids. They do not ionise to a high degree in water, so they produce few hydrogen ions. Weak acids do not conduct electricity as well. Properties of Bases (Alkalis) Bases are also known as alkalis. When dissolved in water, all bases share certain physical and chemical properties. Bases usually taste bitter and are slippery to the touch. However, bases can be poisonous and corrosive so you should never use taste or touch to identify them. Bases turn litmus paper from red to blue and phenolphthalein to bright pink. Bases emulsify, or dissolve, fats and oils. They do this by reacting with the fat or oil to form a soap. The base ammonium hydroxide is used as a household cleaner because it “cuts” grease. The strong base sodium hydroxide, or lye, is used to clean clogged drains. All bases contain the hydroxide ion (OH-). When dissolved in water, bases produce this ion. Because a hydroxide ion (OH-) can combine with a hydrogen ion (H+) and form water (H20), a base is often defined as a proton acceptor. OH- + H+ H20 Name & Uses Formula Strong Bases Sodium Making soap; hydroxide drain cleaner NaOH Potassium Making soft hydroxide soap; battery KOH electrolyte Calcium Leather hydroxide production; making plaster Ca(OH)2 Magnesium Laxative; hydroxide antacid Mg(OH)2 Weak Bases Ammonium Household hydroxide cleaner NH4OH Aluminum Antacid; hydroxide deoderant Al(OH)3 Common Bases Strong bases dissolve readily in water to produce large numbers of ions. Therefore, strong bases are good electrolytes (conductors of electricity). Examples of strong bases include potassium hydroxide, sodium hydroxide, and calcium hydroxide. Weak bases do not produce large numbers of ions when dissolved in water. Therefore, weak bases on are poor electrolytes. Ammonium hydroxide, and aluminum hydroxide are weak bases. Review Questions 1. What are 3 properties of acids? of bases? 2. Why are acids called proton donors? 3. Why are bases called proton acceptors? 4. What are 3 common acids? bases? The pH Scale As you know some substances are acids and some are bases. Other substances are neutral. But, what does this mean? To measure the acidity of a solution, the pH scale is used. The pH of a solution is a measure of the hydronium ion (H3O+) concentration. Remember, the hydronium ion is formed by the attraction between a hydrogen ion (H+) from an acid and a water molecule. So, the pH of a solution indicates how acidic the solution is. The pH scale is a series of numbers from 0 to 14. The middle of the scale – 7 – is the neutral point. A neutral solution has a pH of 7. It is neither an acid nor a base. Pure water is a neutral liquid. A solution with a pH below 7 is an acid. Strong acids have low pH numbers. A solution with a pH above 7 is a base. Strong bases have high pH numbers. pH Indicators The pH of a solution can be determined by using an indicator. You already know about two indicators: litmus paper and phenolphthalein. Other indicators include pH paper, methyl orange, and bromothyl blue. Each indicator shows a specific colour change as the pH of a solution changes. Common household materials can be used as indicators. Red cabbage juice covers the entire pH range. Grape juice is bright pink in the presence of an acid and bright yellow in the presence of a base. Even tea can be an indicator. Have you ever noticed the colour of tea change when you add lemon juice? For accurate pH measurements, a pH metre is used. A universal indicator is used on pH indicator strips. A universal indicator is a combination of dyes which gives a different colour for each level in the pH scale. Indicator Litmus paper Phenolphthalein Red cabbage juice Grape juice Universal indicator In Acids red colourless red/purple bright pink red/orange/yellow In Bases Blue bright pink blue/green/yellow bright yellow blue/purple Review Questions 1. What is pH? Describe the pH scale. 2. What is the pH of an acid? a base? water? 3. How can the pH of a solution be determined? 4. What happens to litmus paper in an acid? a base? Concentration of Hydrogen ions compared to distilled water pH Scale Examples of solutions and their respective pH levels pH Indicators Lab Purpose ; How does the pH of a liquid show if that liquid is acidic or basic? Materials List: 1 test tube rack, with 6 test tubes About 25 mL of red cabbage juice, in a small beaker 1 Pipette 5 Paper Towels any 6 different testing liquids 1 marker for test tubes Procedure: 1. Read through the entire procedure. 2. Make an appropriate data table for collecting the data. (Title, How many rows & columns, labels for rows & columns) 3. Collect everything except the testing liquids. 4. Choose your testing liquids, BUT do NOT collect them yet! 5. Label each test tube, with the appropriate number for the liquid you will test. 6. Pour some of the liquid into the graduated cylinder marked with the same number, so it will be easier to pour into the test tube.(example – liquid #1 into grad. cylinder #1) 7. Fill each test tube ¼ full with the appropriate numbered liquid. Make sure you put the correct liquid in the correct test tube. 8. Add one pipette of red cabbage juice to each test tube. 9. Gently swirl the test tube. 10. Let sit and move onto the next test tube. 11. When you finish testing all of your liquids, record the final colour of the liquids on your data table. 12. Clean up your working area. Performance in Experiment Stays focused and on task yes Follows instructions given (including safety warnings) yes Works cooperatively with others yes Collects data accurately yes Treats equipment appropriately and respectfully yes Cleans up work space consistently/completely yes Grade for PLAB: partially partially partially partially partially partially /6 (not in academic grade) no no no no no no