Supporting information. Nanofluidic electrokinetics in nanoparticle crystal Zhen Chen College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China Yunshan Wang Institute of Microelectronics, Peking University, Beijing 100871, China Prof. Wei Wang and Prof. Zhihong Li Institute of Microelectronics, National Key Laboratory of Micro/Nano Fabrication Technology, Peking University, Beijing 100871, China Corresponding author email: w.wang@pku.edu.cn Stacking structure and the element extraction. Figure S1 shows the relative vertical position of the layers of nanoparticles and interstices. For clarity, only two layers of solid spheres are shown. If the two adjacent layers of nanoparticles are denoted as AB, Figure S1a shows a layer of tetrahedral interstices that take the “a” positions while Figure S1b shows a layer of tetrahedral interstices that take the “b” positions. A planform of Figure S1c (not shown) could demonstrate that the center of the octahedron takes the “c” position. Figure S1e shows the resistance element extracted from the layers-structure. Each element contains two layers of tetrahedral sites and one layer of octahedral sites (the upper and bottom layer is counted with a coefficient of 1/2). Meanwhile, because each element has one layer of nanoparticles (Figure S1e), the layer of nanoparticles equal to the number of the resistance element. Figure S1. The side-view of two layers of close-packed nanoparticles. (a), (b), (c) illustrates the interstices formed by the adjacent layers of nanoparticles. (d) shows the relative vertical position of the layers. (e) shows a resistance element between two layers of octahedral interstices, just as the discussion in the text.