Analysis of Particulate Matter Removal Efficiency Using the STC900 Unit Operation Karl Seltzer Department of Environmental Engineering Science, University of Florida, Gainesville, Florida Abstract— While the built environs continue to grow, the amount of impervious surfaces that invade our natural environments will proportionally enlarge as well. Not only do these impervious surfaces change the look of the predeveloped areas but, they also alter the hydrologic and pollutant loading found in surface runoff as well as the phase transport of all these pollutants. This increase of pollutants puts a strain on the receiving water bodies and the animals that live in these effluent ponds and streams. Eutrophication, fish kill and ground water contamination are consequences of such polluted rainfall-runoff. As a result of these unnatural changes, many new types of Unit Operations and Processes (UOPs) have been developed that seek to protect these receiving water bodies from high pollutant loadings. They can be installed both on site, in centralized locations or in-situ (at the source) and lower the amount of pollutants that eventually make their way off site. For this study, the integrity and efficiency of the STC900, a UOP that provides particle separation, was examined for removal of particulate matter, which carries a large amount of the total pollutant load. The unit is a hydrodynamic separator that specializes in removing mass limited species that are carried in stormwater. It was determined that the particulate matter removal efficiency increased as flow rate into the STC900 decreased but, was able to maintain a 56.17% capture of particles for maximum experimental flow rate into the unit. The significance of these values and the steps leading to them are discussed in the following report. 1. of Florida campus shows that a large mass of phosphorus and nitrogen eventually makes it way off site. Introduction Particulate matter in stormwater runoff has increasingly become problematic as expansion and development continues. When a rainfall-runoff event occurs, the sprawling impervious surfaces, which have now taken over a large part of the previously natural environments, transports pollutants to receiving water bodies. To put the amount of impervious surfaces in Florida into perspective, almost 4 million acres of land in this state have been “urbanized” in the last 42 years (Bergstrom 2001). Whether or not the land is transformed into a commercial setting or industrial site, damaging effects can be seen in the rainfall-runoff from these places. Figure 1. Breakdown of Nutrients and Particulate Matter on a University of Florida parking lot. The pollutants associated with runoff from these sites can potentially have a large diversity in the type and amount of pollutant washed into the natural environment. Some experience an abundance of organic matter, such as leaves and dirt, while others may contain many inorganic materials such as metals and oils. One local site that experiences both organic and inorganic constituents is the Reitz Union Parking Lot on the University of Florida campus. The impervious lot receives a large amount of nutrient and particulate matter pollution from the surrounding trees while inorganics pile up from the cars that are constantly being driven on its surface. A breakdown of the organic constituents can be seen below in Figure 1. This breakdown of particulate bound and soluble nutrients from a parking lot on the University As seen in Figure 1, only a small portion of the total phosphorus content in the runoff is made up of phosphate (a soluble form of phosphorus). The balance of the total phosphorus content is made up of particulate bound Phosphorus. Therefore, a UOP that specializes in removing particulate matter from runoff would in turn remove a significant portion of the phosphorus in the influent water stream. On the other hand, nitrogen is comprised of more soluble species, making it much more difficult to treat. The particulate matter breakdown in Figure 1 also displays a large portion of PM falling into the sediment category, which is greater than 75 microns. 1 These larger particles have larger mass and are therefore easier to settle and filter. Unlike their smaller counterparts, sediment-size particles tend to remain in the UOP once removed and much more difficult to scour. 2. The STC900, which is made by Imbrium Systems Corporation and a part of their Stormceptor System division of Units, is capable of holding 900 US Gallons. The diameter of the Unit is 6 feet and the height is about 4.5 feet. Also, according to Imbrium, the maximum flow rate that the Unit can handle is approximately 300 US gallons per minute (GPM). STC900 In this study, the Stormceptor 900 (STC 900) was examined and the removal of particulate matter through this system was quantified. This UOP requires no energy input and relies on head differentials to push the influent water through the system. When installed in the field, these units are typically buried underground but, for this study, an above ground STC900 was used. This allowed for much easier access to various ports that helped in the mass balance of the experiments and an overall view of the system in action. 3. Flow Determination and Conveyance System For any given storm, the runoff flow throughout the duration of the storm varies. In order to accurately depict these flow features that the STC900 will naturally see in the field, it was necessary to vary the duration and intensity of the surrogate storms that was passed through the system. For that reason, it was important to test a number of different hydrographs (runoff flow vs. time charts) and determine the particle removal efficiency from each. By weighting the particulate matter based on incremental volume from each hydrograph, total removal efficiency over any time period can be determined. Stormwater enters the STC900 through the inlet (seen in Figure 2) and utilizes the internal flow conveyance system to create a hydrodynamic separation process that keeps particles in the unit while allowing a much cleaner effluent to leave through an upflow orifice, as seen in Figure 3. A maximum flow rate of 290 gallons per minute was used as the stepping stone for all the surrogate storms in this research. . This value is the maximum inflow value for this particular UOP as specified by its manufacturer, Imbrium. As seen in Figure 4 below, a hydrograph was built around this maximum flow rate. As can be seen, the flow value starts at zero and rises to the maximum value over a near 15 minute span. From there, the flow decreases back down to zero flow. To create a number of different hydrographs, certain percentages of this peak flow were then determined and a delineated hydrograph of each were composed. Figure 5 shows the hydrograph that was used for a 50% peak flow analysis. Figure 6 shows the hydrograph that was used for a 25% peak flow analysis. Figure 2. STC900 Inlet Figure 4. Hydrograph for 100% Peak Flow Figure 3. STC900 View from Outlet Port 2 Figure 5. Hydrograph for 50% Peak Flow Figure 7. Tanks Used for Experimental Water Storage Figure 6. Hydrograph for 25% Peak Flow The water was then pulled from the storage tanks by the pumping system seen in the figure below. The water then traveled through an 8 inch PVC pipe conduit system and eventually makes its way to the STC900 unit. As seen above, each of these hydrographs represents unsteady flow conditions, which is how a real storm occurs. As the runoff values at each time interval change, the amount of water entering a UOP also changes, increasing the difficulty in treating stormwater due to increased turbulence. Figure 8. Pumping System In order to produce these surrogate hydrographs, a varying flow rate system was needed. To do this, a pumping station and a piping conduit made of 8-inch PVC pipe was used. Before any experimental run took place, it was necessary to have an adequate supply of water. The water towers seen below in Figure 7 served as storage units and housed the potable water that would eventually be pushed through the STC900 Unit. It was essential that tap was be used in the experimentation process. If random particles were to be present in the influent that were not defined by the influent particle size distribution, an inaccurate mass balance would result and an incorrect removal efficiency would be determined. Potable water provided the quality control of knowing that the influent water was clean and particle free. 3 Figure 9. Hydraulic Conveyance System 4. Influent PSD In order to determine the efficiency of the STC900, it is necessary to define what enters the system and compare it to the amount and type of particles that leave in the effluent. A set particle size distribution (PSD) was used for each slurry injection and maintained throughout the course of each individual hydrograph. A particle size distribution graph depicts the percentage of particles by mass that are below a given size. In the case of this study, the sizes were defined as microns (μm). Figure 11 below graphs the influent PSD that was used for each injection. This graph follows a NJDEP (New Jersey Department of Environmental Protection) gradation and encompasses all phases of the particulate matter spectrum (sediment, settleable and suspended). Figure 11. Influent PSD % finer by mass 100 Finally, once the water made its way through the conveyance system, it reached the STC900 inlet. A visual of this area can be viewed in Figure 3 and Figure 10. 80 60 Influent PSD 40 20 NJCAT gradation 0 10000 Figure 10. Entrance to the STC900 1000 100 10 1 0.1 Particle diameter, d (m) By utilizing the PSD above and comparing it to the PSD from the effluent, a total removal efficiency can be determined. As discussed earlier, the removal efficiency of the unit is dependent on the PSD, flow and velocity of the water as it travels through the STC900. The larger the flow, the faster the water makes its way through the Unit and the more difficult it is to settle out particles that are in the influent. This is due to the turbulence within the tank. To obtain a thorough understanding of the Units ability to remove particles, the weighted effluent PSD for a 100% flow, 50% flow and 25% flow rates were measured. 5. Particle Removal Efficiency for 100% Run When looking at the 100% flow hydrograph presented in Figure 4, there are two clear trends in the 4 graph. There is a portion in which the flow steadily increases to the peak and the rest of the hydrograph, which presents the flow decreasing from the peak to zero. For particles in the suspended range (less than 25 µm), the removal efficiency drastically drops and the removal becomes negligible. This is due to the turbulence and an overflow rate that is greater than a settling rate across most of the PSD. Hydrodynamic separation becomes tough and particles in that small range just move on through and exit with the effluent. However, the d50 of this max flow rate should be noted. Even when water is passing the STC900 at nearly 300 GPM, the d50 of particles removed is about 30 microns. For that reason, two separate PSD charts were made to show the trend of removal efficiency pre and post peak flow. Figure 12 below compares the influent PSD for the 100% peak flow and the effluent PSD from time 0 till the peak flow. Figure 12. 100% Flow Effluent PSD Comparison to Influent PSD from Q = 0 to Q = 0.2 6. 100 For the 50% flow run, the maximum flow is approximately 140 GPM. As a result, the turbulence within the STC900 should be drastically less and the residence time of the water in the system will proportionally increase. Due to these factors, it should be expected that a larger amount of particles are capable of being removed and that there won’t be as drastic a change between the PSD measurements throughout the “storm.” % finer by mass 0<t/tmax<0.2 80 60 Influent Q+ 40 20 0 10000 1000 100 10 1 Particle Removal Efficiency for 50% Run 0.1 Once again, the PSD charts were broken up into two separate parts; the time leading up to the peak flow and the time post peak flow that leads back down to a zero flow. The PSD plots for time zero up until peak flow are shown below in Figure 14. Particle diameter, d (m) As expected, when the flow increases, the velocity turbulence in the Unit increases and it becomes more difficult for particles to settle. For that reason, the PSD over time move further to the left, expressing that larger particles are leaving the system and that as a whole, the STC900 is less efficient in removing particles. Figure 14. 50% Flow Effluent PSD Comparison to Influent PSD from Q = 0 to Q = 0.4 100 0<t/tmax<0.4 % finer by mass Though, after the peak flow occurs, the opposite effect can be seen. As shown below in Figure 13, the PSDs start to move back to the right. This signifies a larger efficiency of the STC900 removing the bigger size particles. Thus a better total removal efficiency begins to occur. Figure 13. 100% Flow Effluent PSD Comparison to Influent PSD from Q = 0.2 to Q = 1.0 80 60 Influent Q+ 40 20 0 1000 100 10 1 0.1 Particle diameter, d (m) 100 % finer by mass 0.2<t/tmax<1 80 As seen in Figure 14, the PSD trend leading up the peak for the 50% flow storm follows the same trend as the 100% flow storm. As the flow picks up, more turbulence and a smaller particle residence time occurs in the Unit. Due to these phenomena, the PSD moves further to the left. Post peak flow, the PSD measurements start moving back to the right, indicating higher removal efficiency. This trend can be seen in Figure 15. Influent 60 Q- 40 20 0 10000 1000 100 10 1 0.1 Particle diameter, d (m) 5 Figure 15. 50% Flow Effluent PSD Comparison to Influent PSD from Q = 0.4 to Q = 1.0 Figure 17. 25% Flow Effluent PSD Comparison to Influent PSD from Q = 0.2 to Q = 1.0 100 100 0.2<t/tmax<1 80 % finer by mass % finer by mass 0.4<t/tmax<1 Q- 60 Influent 40 20 0 Q- 60 Influent 40 20 0 1000 100 10 1 0.1 1000 Particle diameter, d (m) 100 10 1 0.1 Diameter, d (m) As expected, the d50 for the maximum flow during the 50% run (approximately 25 microns) is smaller than the d50 at the maximum flow during the 100% run (approximately 30 microns), indicating a higher removal percentage. 7. 80 As the flow increases, the same trend occurs as previously shown, with the PSD measurements becoming steadily coarser. However, one observation is the very slight change in the difference between each PSD measurement. At this flow rate level and storm intensity, only a slight drop in removal efficiency is seen throughout the entire event. Particle Removal Efficiency for 25% Run For the final flow testing, 25% maximum flow was tested, which is approximately 70 GPM. As was the case between 100% and 50%, similar trends were also anticipated and an overall higher removal efficiency should be seen. Additionally, after post peak flow, the PSD chart lines move back to the right, indicating a slightly better removal efficiency. Again, the PSD charts were broken up into two separate figures. Figure 16 presents the PSD trend from time zero until the maximum flow (about 70 GPM) was achieved. Figure 17 presents the PSD trend from the maximum flow until the end of the “storm.” There is a variety of ways phosphorus and nitrogen can make their way into a receiving body through stormwater rainfall-runoff. These nutrients can be flow limited and mainly depend on their dissolved constituents or mass limited and proportionally reliant on particulate matter to transport them. Though both phosphorus and nitrogen are clumped together into the same category of “nutrients,” the limitations associated with each are completely different. 8. Figure 16. 25% Flow Effluent PSD Comparison to Influent PSD from Q = 0 to Q = 0.2 100 % finer by mass 0<t/tmax<0.2 A study on the University of Florida campus that collected data on the components of stormwater rainfall-runoff from the summer of 2008 showed that the approximately 68% of the Total Phosphorus in runoff is made up of particle bound phosphorus and about 41% of the Total Nitrogen in runoff is made up of particle bound nitrogen (FDEP). As these percentages show, phosphorus tends to be a more mass limited nutrient species while nitrogen tends to be a more flow limited species. Additionally, relating these numbers to the determined total particulate matter removal efficiency of the STC900 (56.17%), a 80 Q+ 60 Influent 40 20 0 1000 100 10 1 Particle Removal in Relation to Pollutants 0.1 Particle diameter, d (m) 6 total nutrient removal efficiency can also be determined. UOP at the forefront of such a system would be the STC900. Assuming that 56% of the particles entering the STC900 are removed, that equates to 56% of the particulate bound phosphorus and nitrogen are additionally stripped from the runoff. Relating these percentages, approximately 38% of the Total Phosphorus content and 23% of the Total Nitrogen content in this University of Florida runoff can theoretically be removed through the use of the STC900 UOP. Acknowledgements 9. I would first like to thank Dr. John Sansalone. Without his mentoring, this study would not have been possible. Giusi Garofalo and Annalisa Ciccarello who helped lead this research. And the entire University of Florida Stormwater Unit Operations and Process Lab of students. Conclusion The STC900 Unit Operation and Process specializes in removing particulate matter from a rainfall-runoff stream through hydrodynamic separation and sedimentation. While this may seem like a narrow scope of treatment, the chemistry behind stormwater enables the STC900 to reach out and treat a variety of other pollutants that embed themselves in stormwater stream. References (1) Bergstrom, C. (Ed.). (2001). Current Issues Associates with Land Values and Land Use Planning: Urbanization and Land Use Change in Florida and the South: Southern rural Development Center and Farm Foundation. (2) FDEP Contract Number WM 910 Management of Source Area Runoff Using In-situ Controls. University of Florida. Department of Environmental Engineering Sciences. (3) Kertesz, R., Maccarone, K., Raje, S., Seltzer, K., Siminari, M., Simms, P., Wood, B. (2009). Green Infrastructure and LID Design for Florida Constructed Environs, Subject to Rainfall Runoff Loadings. Team Pluvia Munda for Florida Water Environment Association. In addition to the 56% removal efficiency of particulate matter from runoff, particulate bound nutrients and particulate bound metals are also maintained by the STC900 through the removal of particulate matter. As determined previously, about 38% of the Total Phosphorus content and 23% of the Total Nitrogen content can be removed from runoff by the simple treatment of particulate matter. While these numbers may seem low, their economic value to the treatment of stormwater runoff cannot be overlooked. The mean cost to remove phosphorus from runoff using BMPs in FL is about $14,700/lb/yr and the mean cost to remove nitrogen from runoff using BMPs in FL is about $3,700/lb/yr (Kertesz et al. 2009). Therefore, even removing a small portion of nutrients from a runoff stream can save a large portion of money, even in the short term. The STC900 does an excellent job at balancing the removal of particulate matter from runoff and minimizing the amount of extracurricular maintenance needed on the UOP. It maintains a good amount of nutrient removal as well but, lacks in efficiency when it comes to dissolved constituent removal. As the importance of stormwater runoff comes to the forefront, more stringent technologies must be perfected that focus more on the dissolved portion of pollutants. Various filter designs, ionic ad mixtures and denitrification can help enhance the removal of nutrients. These advanced technologies push the idea of a treatment train and the perfect 7