PHYTOREMEDIATION OF SITES CONTAMINATED WITH INDUSTRIAL AND MINING BY-PRODUCTS CONTAINING HEAVY METALS Contract number: OMFB-02453/2000 (BIO-055/2000) Starting date: May 2000. Duration: 3 years Total cost: 28,6 M HUF OM contribution: 13 M HUF Acronym: Phytoremediation BACKGROUND The aim of our research is to develop a phytoremediation-phytostabilization technology applicable on sites contaminated with mining and industrial by-products containing heavy metals. As a representative experimental site an area contaminated with heavy metals located in Gyöngyösoroszi has been chosen since by-products resulted from different mining technologies and the soil, topographical, hydrological and botanical characteristics of the site are inhomogeneous. Realisation of the aims is even more complicated due to the absence of special examination protocol, the extent of the area as well as quantitative questions regarding to the contamination. The developed technology can be adapted for other sites to reduce the environmental risk resulting from mining spoils and industrial sludge, because numerous sites contaminated with heavy metals similar to that of Gyöngyösoroszi are in Hungary the cleanup of which has not been solved. OBJECTIVES To identify phyto-associations having ability to stand extreme heavy metal concentrations and being hyperaccumulators as a result of species selection on the experimental area; To measure the parameters referring to stress toleration and to develop a phytotoxic scale; To develop a terrain model with GIS technique to represent the relationship between plant associations as potential environmental indicators and contaminants; To work out a soil conditioning process to support optimal soil physical and water management conditions with the application of which the ecosystems applicable for phytostabilisation and phytoextraction can be self-supporting; To give technical alternatives (earth works, bench stabilisation, hindrance of infiltration and runoff) taking into consideration the topographical, hydrological and geological conditions, on which the successful application of phytostabilisation is based. To propose a complex phytostabilisation technology on the base of results referring to the experimental area with optimised technical and soil melioration solution and optimised plant associations as well as monitoring system. DESCRIPTION Environmental status assessment method will be developed using GPS/GIS technique and geo-statistical methods for qualitative and quantitative characterisation of sites having inhomogeneous contamination. Measuring the heavy metal content of the soil and plant samples contamination, soil and plant models will be developed and the correlation between contamination and vegetation will be examined. The method allows the identification and selection of phyto-associations having ability to stand extreme heavy metal concentrations and that of potential hyperaccumulators, indicators and excluders, with the help of which phytoextraction and phytostabilisation can be carried out. Heavy metal mobilisation, bioavailability and up-take by plants will be examined with soil columns and lysimeters under different physical and chemical interventions. As a result, the efficiency and applicability of the technology will be examined using plant associations adapted to the experimental area with adequate soil modifications. CURRENT SITUATION/RESULTS The extent and distribution of the contamination has been estimated at the experimental area contaminated with heavy metals. Instead of general soil sampling strategy referring to contaminated soils geo-statistical method adapted to the site and precision measuring technique with DGPS have been used to reveal the spatial inhomogenity. The spatial impoundment of heavy metal contamination has been carried out at the site on the base of which contaminants exceed the limit values according to directive 10/2000. (VI. 2.) referring to total acceptable metal contents of soils. On the experimental site as model area environmental status assessment protocol has been worked out on the base of results gained using GPS, which is generally suitable for qualitative and quantitative characterisation of heavy metal contamination of soils or by-products of mining and industrial activities. In addition, the potentially bio-available contents of heavy metals for plants and their spatial distribution have been measured. Ceonological survey and qualification of associations have also been carried out on the sampling area. The soil column and lysimeter experiments for the examination of stress tolerance of plants has been started. COORDINATOR Pál Draskovits Envirokomplex Environmental and Water Management Ltd. H-1145 Budapest, Kolumbusz u. 17-23. Tel.: 1 3637 231 Fax: 1 4670 188 PARTNERS Dr. habil János Tamás University of Debrecen, Centre of Agricultural Sciences, Dept. of Water and Environmental Management H-4032 Debrecen, Böszörményi út 138. Tel./fax: 52 508 456 tamas@gisserver1.date.hu Prof. Dr. Zoltán Győri University of Debrecen, Centre of Agricultural Sciences, Central Chemical Laboratory H-4032 Debrecen, Böszörményi út 138. Tel.: 52 486 288 / 8067 Fax: 52 413 385 Dr. Gyula Lakatos University of Debrecen, Faculty of Natural Sciences, Dept. of Applied Ecology H-4032 Debrecen, Egyetem tér 1. Tel.: 52 316 666 / 2618 Fax: 52 310 936