Water and key nutrients (carbon, nitrogen and phosphorus) are recycled within ecosystems. Human activities such as agriculture, industrial activity and energy use disrupt the normal nutrient cycling patterns. They lead to . . . pollution habitat distruction and climate change. Understanding normal and altered nutrient cycles gives us a framework for minimizing the effect of human activities on the environment and solving some of our environmental problems. The Water Cycle Availability of clean, potable water is the major constraint on population growth, health and productivity. All of earth’s water has been present since earth first formed. It is simply recycled from one source to another. That is why water pollution is problematic it gets worse over time as pollutants accumulate. condensation precipitation evaporation & transpiration transpiration & evaporation melting & runoff condensation evaporation runoff water reservoir Pollution Facts ∙ Organic matter (e.g. leftover food, excrement) is bio-degradable. The environment has an assimilative capacity for these materials, and they are recycled over time. ∙ Excess organic material causes pollution because the assimilative capacity of the environment is exceeded. It can also be a source of disease-causing bacteria and viruses (e.g. typhoid, typhus, cholera). ∙ Some man-made chemicals (e.g. PCBs) have no assimilative capacity - they don’t biodegrade and so accumulate. ∙ Other chemicals used in industry (oils, heavy metals) are biodegradable, but cause pollution if released in large amounts into the environment. Water Facts: ∙ 98% of the earth’s water is held in oceans, and they are salty (non-potable). The largest reservoir of fresh water is polar ice caps and glaciers (1%). ∙ Less than 0.5% of the earth’s water is fresh from lakes, streams and reservoirs. The remainder is ground water and in aquifers. ∙ Evaporation from oceans, rivers and lakes is the main source of all the fresh water on earth. It is recycled back in the form of precipitation. ∙ In the U.S., we use ground water and surface fresh water (lakes, rivers, reservoirs) equally for industrial and residential purposes. ∙ Industrial use, particularly for agriculture, is the main commercial use for water. ∙ If toxins from landfills and industrial waste seep into ground water, it poses an immediate problem. ∙ The ocean has a large assimilative capacity for organic waste because of its size, and is a tempting dumping site. However, there are long-term consequences of these practices (toxins build up in aquatic food chains and damage ecosystems over time). Keeping it Clean! Industrialized societies spend a great deal of resources to keep their supply of potable water clean and safe: ∙ Laws minimize industrial pollution. The Clean Water and Clean Air Acts in the U.S. are examples. This type of legislation restricts dumping of chemical waste and mandates proper sewage treatment. ∙ Sewage treatment systems clean and recycle water used in human residences. Organic matter and bacteria are removed, and the water is recycled by evaporation or it is cleaned to the point where it can safely be released into the ocean. NOTE: Sewage treatment does not remove chemical pollutants! ∙ Reservoirs are built to trap seasonal snowmelt and rain water for year-round use. The Hetch-Hetchy system in our area brings snowmelt/rain to reservoirs in San Mateo. These efforts effectively increase the available of surface water. ∙ Local ordinances restrict water use in residences and businesses. There is wide variability in water use across the U.S. The Nitrogen Cycle Nitrogen is a critical limiting nutrient for plants; without it, productivity falls. Plants absorb nitrogen mainly from the soil. The problem: Most of earth’s nitrogen is in the atmosphere in the form of N2 gas (nitrogen reservoir). Plants can only use nitrogen in the form of nitrate (NO3) compounds. Nitrogen must be moved from the atmospheric reservoir into the soil and chemically altered into nitrates. Nitrogen cycling involves four chemical processes that turn atmospheric nitrogen or nitrogen from decomposing organisms into useful nitrates. It is performed by different groups of soil bacteria, including azobacteria and rhizobacteria. The 4 chemical processes are: ammonification, nitrification, nitrogen fixation and denitrification. Ammonification and nitrification recycle nitrogen among living organisms: ∙ Ammonification decomposes organic nitrogen into ammonium: NH2 or NH3 ➔ NH4+. ∙ Nitrification turns ammonia into nitrites, then nitrates: NH4+ ➔ NO2 ➔ NO3. Nitrogen fixation and denitrification recycle nitrogen between living organisms and the atmospheric reservoir. ∙ Nitrogen fixation is performed by bacteria in root nodule of leguminous plants. N2 ➔ NH4+ in the first step. Different bacteria turn NH4+ ➔NO3 in subsequent steps. ∙ Denitrification also occurs, returning excess soil nitrates to the air. NO3 ➔N2. Denitrification is very rare and occurs only in over-fertilized fields. The main processes by which soil gains nitrogen are: ammonification followed by nitrification. Nitrogen fixation plays a small but important role. The main way soil loses nitrogen is via uptake by plants, then ingestion of the plant by animals. Denitrification is rare. Agriculture and energy use disrupt nitrogen cycling in the following ways: Excess nitrogen fertilizers enter waterways and cause algal blooms and premature eutrophication. Burning fossil fuels increases atmospheric nitrogen oxides, enhancing the greenhouse effect and leading to acid rain. Like nitrogen, phosphorus is an important nutrient without which primary productivity falls. Phosphorus is required for nucleic acids, phospholipids, ATP, and animal skeletons. The main phosphorus reservoirs are rocks and minerals, dissolved phosphates and in living organisms. The cycling is relatively simple; phosphates are moved from one group of organisms to another via excretion, decomposition and consumption. Farming disrupts the phosphorus cycle in much the same way as for nitrogen. phosphate detergents add intermittent phosphate doses to waterways, causing destructive algae blooms. ACCELERATED EUTROPHICATION ∙ Eutrophication is a normal process; lakes, ponds, and river banks gradually fill in due to accumulated silt and nutrients. ∙ Agricultural runoff contains excess fertilizers (nitrates and phosphates), which accelerate eutrophication. The ABC’s of eutrophication: A: Runoff enters lakes and rivers, causing a producer growth explosion. You get more O2 production during the day, but high O2 use at night. B: Producers die when the pulse of nutrients from the runoff stops. The decomposition of producers leads to water turbidity, lower sunlight penetration and oxygen depletion. C: Rate of detritus production and accumulated organic matter (from dead organisms) increases and the water body begins to fill in prematurely. The bottom line: In bodies of water that undergo accelerated eutrophication, higher order consumers like fish often decrease because there isn’t enough dissolved oxygen to support them. The Carbon Cycle Most of the available carbon exists in living organisms, sedimentary rocks, atmospheric CO2 and fossil fuels. Carbon is perfectly recycled via the processes of decomposition, photosynthesis and respiration. respiration C6H12O6 + 6 O2 + 6 H2O 6 CO2 + 12 H2O + energy photosynthesis Decomposers liberate stored carbon from decaying plants and animals in the form of CO2. Plants can then utilize the CO2 to form glucose, liberating oxygen. Burning fossil fuels and wood increases atmospheric CO2 without increasing the resources (plants) to recycle the carbon. In the case of wood, plants are removed to use as fuel, creating a further imbalance between fixation of CO2 into sugars and release of CO2 into the atmosphere. As a result, atmospheric CO2 rises. Atmospheric CO2 is a greenhouse gas. It traps heat in earth’s atmosphere, allowing for a moderately warm climate in most latitudes. Excess CO2 causes global warming because it enhances the beneficial greenhouse effect. Intensive farming also disrupts carbon cycling in many ways: 1. Crops grown in one region are shipped to another for consumption. 2. Farming requires automation and uses fossil fuels, the burning of which add atmospheric CO2 . 3. Biomes such as rainforests, tropical grasslands, temperate forests and temperate grasslands are replaced by farms. Crops are of similar productivity (recycled CO2 per acre) to temperate grasslands and forests. However, they are less productive than tropical biomes they replace. This slows carbon recycling and increases atmospheric CO2. 4. When forests are burned to clear farms, atmospheric CO2 also rises due to the wood burning. Until 200 years ago, carbon was effectively recycled by photosynthesis and cellular respiration. The normal carbon cycling pattern resulted in a small amount of CO2 in the atmosphere. Humans disrupt the normal carbon cycling pattern by burning fossil fuels for energy, adding to atmospheric CO2. Humans also burn down productive forest biomes to make room for farms and housing for the burgeoning human population.