Summer School 4 Energy Weeks Air Pollution, Waste Water, and Solid Wastes Management BMEGEÁTAG04 (3 ECTS credits) 1st week Treatment of Gaseous Substances or Vapours (M. PARTI, Full Professor) A general overview of the air pollution control methods to remove or to convert gaseous substances or vapours in waste gases. Methods with and without recovery of substances. Absorption: absorption phenomena, notations of absorption, types of absorption. Absorption equilibrium, equilibrium curve, dependence on temperature and total pressure. Henry’s law and the role of Henry’s law coefficient. Chemical equilibrium conditions. Selection of solvent for absorption. Material balance for counter-current flow, the operating line, the driving force for mass transfer. Minimum liquid-gas ratio for absorption. Equipment for absorption, general characteristics of tray and packed absorbers (towers). Absorption plant. technical applications. Technical applications of absorption. Advantages and disadvantages of absorption systems. Adsorption: adsorption phenomena, notations of adsorption, types of adsorption. Adsorption equilibria for gases and vapours, effect of temperature. Adsorbents, selection of adsorbents. General overview of an adsorption plant. Unsteady-state adsorption, the adsorption wave. Steady-state adsorption, technical applications. Adsorption of vapours, technical applications. Advantages and disadvantages of adsorption systems. Chemical Waste Gas Treatment (combustion): General overview of combustion systems. Types of the oxidation process. Combustion-control equipment (flares, thermal incinerators, catalytic incinerators). Design and performance of incinerators (heat balance, heat recovery, catalyst). Advantages and disadvantages of combustion systems. Biological Waste Gas Treatment: General process description. Microorganisms used in biological degradation. Efficiency of the processes. Bioabsorption plants, technical applications of the processes. Advantages and disadvantages of biofiltration. Reduction of Nitrogen Oxides: Selective non-catalytic and catalytic reduction. Advantages and disadvantages of the reduction processes. 1/5 Summer School 4 Energy Weeks 2nd week Particle Removal from Gases (J.M. SUDA, Assistant Professor) Introduction. Aerosols. Definition of aerosols. Types and size ranges: Dust, smoke, mist. Various parameters of particulate phases. Behaviour in human body. PM regulations. Characterisation of particle assembly, mono-, polydispersed particulate phase, particle size distribution curves. Characterisation of particle - laden mixtures. Parameters of particles, shape & size, equivalent diameter, geometrical, aerodynamic, optical, electrical equivalency. Relative average distance between neighbouring particles. Dense / dilute suspensions, volume ratio, mass loading ratio, concentration. Particle dynamics. Equation of motion of carrier gas phase, of particles. Aerodynamic drag of single particle. Settling velocity. Cunningham correction factor. Dimensionless formulation of equation of motion for particles. Conditions for neglection of the effect of particles on the gas flow. Turbulence modification by particles in particle-laden flow, time scales, length scales, particle Stokes number, inertia number. Evaluation of particle movement based on particle inertia number: particle pathline relative to carrier gas flow streamline. Theory and practice of particle concentration measurement. Mean concentration. Direct / indirect methods for particle concentration measurements. Iso-kinetic sampling with sampling rig. Various sampling probe design. Error / uncertainty of concentration measurement. Mass balance of a separator. Overall & fractional efficiency. Inlet and outlet particle size distribution curves of a separator in idealistic & real case. Basic steps of particle separation process. Main forces and effects influencing on the particle removal. Various equipments of gas cleaning and particle separators. General description, basic outline, operating method: settling chamber, pre-separator louver, washing tower, Venturi-scrubber, cyclone, electrostatic precipitator, surface & depth filters. 2/5 Summer School 4 Energy Weeks 3rd week Wastewater Treatment (L. TÖMÖSY, Associate Professor) Sources of wastewater. Most important pollutants: Solid and non-water dissolvable components. Dissolvable and suspended organic pollutants and inorganic pollutants. Flow sheet of wastewater treatment. Primary or physical treatment processes. Sedimentation. Design and function of devices: stone catch, fine screen, sand trap or grit chamber, sedimentation (clarifier) tanks. Secondary treatment: biological and chemical processes. Basic knowledge of biological treatment. Activated sludge process, attached growth processes. Function and design of devices. Removal of phosphorous contaminations. Tertiary treatment: nitrification (if necessary), de-nitrification. Disinfection, and disposal of treated wastewater. Wastewater sludge treatment techniques: thickening, conditioning, dewatering, sludge disinfection. Construction and function of gravity thickener, decanter, imperforated basket centrifuge. Physical and chemical conditioning. Organic and inorganic chemicals. Biological conditioning. Aerobic and anaerobic treatment techniques. Devices. Sludge dewatering. Centrifuges. Belt filter press, pressure filter. Sludge-drying beds. 3/5 Summer School 4 Energy Weeks 4th week Solid Wastes Management (P. LÁNG, Full Professor) Introduction, notions. Definition of waste and waste management. Sustainable development. Material cycle producing waste. Diagram of waste management hierarchy. Fractional elements of waste management: reduction, generation, reuse, on-site handling, storage and processing, collection, transfer and transport, processing and recovery, disposal. Municipal waste, quantity and composition. Waste generation and reduction. Reasons of the generation of industrial wastes. Methods for reducing the quantity of industrial wastes. Hazardous wastes, Basel Convention. Processing and resource recovery. Thermal processes. Incineration with heat recovery. Combustion. Types of incinerator plant design: moving grate, rotary kiln, Westinghouse-O’ Connors, combustion chambers, multistoried kiln, fluidised bed, combination of multistoried and fluidised bed kilns. Salt melt kiln. Heat recovery, waste to energy systems. Emissions. Dioxins and furans. Flue gas cleaning (wet, semi-dry, dry methods). Combustion of wastes in high temperature industrial technologies (cement kiln). Pyrolisis (Schwel-Brenn, Babcock) and gasification (Thermoselect). Ultimate disposal. Landfilling of municipal solid wastes. 4/5 Summer School 4 Energy Weeks Course Requirements: Participation in all of the classes, laboratory sessions, presentations, and field trips. Mid-term/s Dates of mid-terms: No.1 - 19 June 2014 No.2 – 26 June 2014 No.3 – 3 July 2014 Final Date of final: Second half of the last week. Compulsory literature: Hand-outs given by the lecturers for the different parts of the curriculum Optional literature: Bailey, J.E., Ollis, D.F.: Biochemical Engineering Fundamentals. McGraw-Hill Book Co., New York, 1977. Brauer, H., Varma, Y.B.G.: Air Pollution Control Equipment. Springer-Verlag, Berlin, 1981. Gray, N.F.: Biology of Wastewater Treatment. Oxford University Press, Oxford, 1989. Green, D.W., Perry, R.H.: Perry’s Chemical Engineers’ Handbook. McGraw-Hill Book Co., New York, 2008. Treybal, R.E.: Mass Transfer Operations. McGraw-Hill Book Co., New York, 1968. 5/5