treatment of agricultural wastewaters using sand filtration and

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Published as: Healy, M.G., Rodgers, M., Mulqueen, J. 2007. Treatment of dairy wastewater using constructed wetlands and intermittent sand filters. Bioresource Technology 98:

2268-2281.

TREATMENT OF DAIRY WASTEWATER USING CONSTRUCTED WETLANDS

AND INTERMITTENT SAND FILTERS

M.G. Healy

*

, M. Rodgers and J. Mulqueen

10

11 Department of Civil Engineering, National University of Ireland, Galway, Ireland.

12

13 Abstract

14

15 In Ireland, the most common method of disposal of dairy parlour washings is by land

16 spreading. This treatment method has numerous problems, namely high labour

17 requirements and the potential for eutrophication of surface and ground waters.

18 Constructed wetlands are commonly used for treatment of secondary municipal

19 wastewaters and they have been gaining popularity for treatment of agricultural

20 wastewaters in Ireland. Intermittent sand filtration may offer an alternative to traditional

21 treatment methods. As well as providing comparable treatment performance, they also

22 have a smaller footprint, due to the substantially higher organic loading rates that may be

23 applied to their surfaces. This paper discusses the performance and design criteria of

24 constructed wetlands for the treatment of domestic and agricultural wastewater, and sand

* Corresponding author. Tel: +353 91 495364; Fax: +353 91 494507. E-mail: mark.healy@nuigalway.ie

1

25 filters for the treatment of domestic wastewater. It also proposes sand filtration as an

26 alternative treatment mechanism for agricultural wastewater and suggests design

27 guidelines.

28

29 Keywords: dairy parlour washings; domestic wastewater; intermittent sand filtration;

30 constructed wetlands; land spreading; organic loading rate.

31

32 1. Introduction

33

34 Dairy parlour washings, containing urine and manure, as well as detergents, spilled milk,

35 and mucus, can have a significant adverse effect on the environment. In Ireland and

36 elsewhere, dairy parlour washings are treated mainly by land spreading with low rate

37 irrigation systems. This has proven problematic because of the labour requirements for

38 effective management and the potential for eutrophication due to run-off and leaching.

39 Problems of surface run-off are particularly prevalent on slow-draining soils with sloping

40 land at field capacity or wetter. In land spreading on free-draining soils, the main nutrient

41 removal processes are filtration, soil adsorption, microbial decomposition, and plant

42 uptake. The latter two processes are active in reducing nitrate-nitrogen (NO

3

-N)

43 concentrations; however, if NO

3

-N passes beyond the root zone it can be leached to the

44 groundwater. Analyses of five Irish borehole (well) waters underlying light textured soils

45 receiving high nitrogen (N) applications have yielded NO

3

-N concentrations greater than

46 the EU maximum allowable concentration (MAC) of 11.3 mg L -1 for drinking water

47 (Richards et al., 1998). In that study, Richards et al. (1998) found, that in a plot

2

48 comprising a sand loam overlying a sandy silt loam to 106 cm deep receiving a mean

49 wastewater application rate of 677 kg N ha -1 yr -1 , mainly as organic N, soil water NO

3

-N

50 concentration was 23 mg NO

3

-N L

-1

.

51

52 The Nitrate Directive, 91/676/EEC (EEC, 1991) has focused considerable attention on the

53 disposal of agricultural wastewaters in Ireland, where about 25% of the land area is

54 devoted to dairy farming (Carton, 2001). A survey of 1132 rivers and streams from 2001

55 to 2003 (Toner et al., 2005) estimated that the percentage of pollution attributed to

56 agriculture was approximately 32%, 32% and 15% in rivers and streams which were

57 slightly, moderately, and seriously polluted, respectively.

58

59 In farms, volumes of water used for wash-down of yard areas, milk spillage, yard area

60 rainfall, and stormwater run-off lead to a final effluent of variable concentration and

61 volume. The water volumes generated may vary according to the practices applied by the

62 farmers. Factors such as frequency of milking and the number of cows present at the

63 same time affect the volumes generated. Dairy parlour washings have been estimated at

64 50 litres per cow per day (Department of the Environment and Department of

65 Agriculture, Food and Forestry, 1996) but this value can be frequently exceeded

66 especially where there is indifferent management of water usage. Studies have shown that

67 when low-pressure, high-volume spray nozzles are used in yard wash-down, water

68 volumes generated can be significantly reduced (Wrigley, 1994).

69

3

70 Concentrations of contaminants in dairy wastewater are significantly higher than

71 municipal effluent, and tend to vary throughout the year. On a 160 cow dairy farm, Ryan

72 (1990) found that total nitrogen (Tot-N) and biochemical oxygen demand (BOD

5

)

73 concentrations in the washings ranged, respectively, from 88 and 954 mg L

-1

during the

74 winter to 225 and 2974 mg L

-1

, respectively, during the summer. These concentrations

75 also depend on the number of rinses of the milking machine as Ryan (1990) found that

76 the BOD

5

concentration of the washings decreased from 19,200 mg L -1 in the first rinse

77 to 144 mg L

-1

in the final rinse. In the hydraulic design for land spreading, the hydraulic

78 conductivity of the soil, the depth to water table and/or bedrock, and the concentration of

79 the suspended sediment can be defining parameters. Maximum land application rates of 5

80 mm per hour are recommended (Department of the Environment and Department of

81 Agriculture, Food and Forestry, 1996). The quantity of wastewater applied should not

82 exceed 50 m

3

per hectare by single tanker application. In The Netherlands, application

83 rates of up to 15 mm per application are recommended (Hack-ten Broeke, 2001).

84

85 In recent years, the use of constructed wetlands (CWs) for the treatment of dairy parlour

86 washings has been gaining popularity, due to their relatively low capital costs and

87 maintenance requirements. However, intermittent sand filtration (ISF) may have the

88 potential to treat dairy parlour washings effectively and, where denitrification is

89 incorporated, to reduce NO

3

-N to low levels. To date, the use of ISF for the treatment of

90 agricultural wastewater has been limited. They have been used in the dewatering of swine

91 wastewater following addition of organic polymers to increase settlement of suspended

92 solids (SS) and organic compounds (Vanotti et al., 2005; Szögi et al., 2006) and in the

4

93 treatment of detergent and milk fat wastewaters (Liu et al., 1998; Liu et al, 2000; Liu et

94 al., 2003).

95

96 This article aims to review the present state of knowledge regarding CWs and ISF for the

97 treatment of domestic wastewater. The performance of CWs in the treatment of dairy

98 parlour washings is also discussed. As ISF may be a viable alternative to conventional

99 CW treatment, this article suggests design protocols which may be adopted for the ISF of

100 dairy parlour washings, as well as detailing some previous experiences in their use.

101

102 2. Domestic wastewater treatment

103

104 2.1 Constructed wetlands

105

106 There are two types of CW: free water surface constructed wetlands (FWS CWs) and

107 subsurface CWs. In FWS CWs, wastewater flows in a shallow water layer over a soil

108 substrate. Subsurface CWs may be either subsurface horizontal flow CWs (SSHF CWs)

109 or subsurface vertical flow CWs (SSVF CWs). In SSHF CWs, wastewater flows

110 horizontally through the substrate. In SSVF CWs, wastewater is dosed intermittently onto

111 the surface of sand and gravel filters and gradually drains through the filter media before

112 collecting in a drain at the base. CWs may be planted with a mixture of submerged,

113 emergent and, in the case of FWS CWs, floating vegetation.

114

5

115 The large surface area of CWs provides an environment for the physical/physico-

116 chemical retention and biological reduction of organic matter and nutrients (Geary and

117 Moore, 1999; Knight et al., 2000). Depending on the type of CW used, its design, organic

118 loading rate and hydraulic retention time (HRT) (Karpiscak et al., 1999), a CW can have

119 a significant nutrient removal capability. However, due to the effect of changing

120 temperatures, the treatment efficiency of these systems tends to change throughout the

121 year (Bachand and Horne, 2000; Healy and Cawley, 2002).

122

123 Although temperature affects the performance of FWS CWs, SSHF CWs and SSVF

124 CWs, they generally meet relevant effluent discharge criteria in colder climates

125 (Maehlum et al., 1995; Vymazal, 2002; Rousseau et al., 2004). In Europe, effluent BOD

5

126 and SS standards for discharge into surface waters range from 250 mg BOD

5

L -1 in The

127 Netherlands to 25 mg BOD

5

L

-1

in Austria and 70 mg SS L

-1

in The Netherlands to 35 mg

128 SS L

-1

in the Czech Republic, respectively (Rousseau et al., 2004). In Norway, where

129 mean winter temperatures can drop below -10 o

C, Maehlum et al. (1995) used an SSHF

130 CW to treat septic tank wastewater. Under an organic loading rate of approximately 4 g

131 BOD

5

m -2 d -1 , BOD

5

and Tot-N was removed by 93% and 48%, respectively (Table 1).

132

133 N removal in CWs is accomplished primarily by physical settlement, denitrification and

134 plant/microbial uptake. Plant uptake does not represent permanent removal unless plants

135 are routinely harvested.

136

6

137 Phosphorus (P) is removed through short-term or long-term storage. Uptake by bacteria,

138 algae and duckweed (Lemma spp.

), and macrophytes provides an initial removal

139 mechanism (Kadlec, 1997). However, this is only a short-term P storage as 35%-75 % of

140 P stored is eventually released back into the water upon dieback of algae and microbes

141 (Richardson and Craft, 1993; White et al., 2000). Anaerobic conditions which exist at the

142 soil/water interface may also cause the release of P back into the water column (Patrick

143 and Khald, 1974). The only long-term P storage in the wetland is via peat accumulation

144 and substrate fixation. The efficiency of long-term peat storage is a function of the

145 loading rate and also depends on the amount of native iron, calcium, aluminium, and

146 organic matter in the substrate (Shatwell and Cordery, 1999). Lake and reservoir

147 sediments have been shown to act as P sinks (Richardson and Craft, 1993; White et al.,

148 2000). At P loading rates of less than 5g P m -2 yr -1 , wetland sediment can absorb greater

149 than 90% of the total incoming P (Faulkner and Richardson, 1989).

150

151 2.1.1 Pretreatment

152

153 Domestic wastewater must undergo septic tank pre-treatment prior to entering a CW

154 (EPA, 2000). In municipal wastewater treatment, an activated sludge plant provides

155 initial settlement, organic carbon removal and partial nitrification (Healy and Cawley,

156 2002). To protect against groundwater contamination, all FWS CWs, SSHF and SSVF

157 CWs should be lined with an impervious layer e.g., a high density polyethylene liner

158 (HDPL).

159

7

160 2.1.2. Media selection

161

162 For FWS CWs, a substrate rich in iron, calcium and aluminium is recommended. For

163 SSHF CWs, a soil or gravel is recommended (Cooper et al., 1996). In SSVF CWs, an

164 active sand layer with a depth of 1.0 m (effective grain size, d

10

=0.25 – 1.2 mm,

165 coefficient of uniformity, Cu<3.5) is recommended (Brix and Arias, 2005).

166

167 2.1.3 Treatment area and organic loading rates

168

169 FWS CWs and SSHF CWs are normally sized in accordance with (Kadlec and Knight,

170 1996):

171

172 A

0 .

0365 Q k

 ln



C

C e i

C

*

C

*

 (1)

173

174 where A = required wetland area (ha)

175

176

C e

= the outlet concentration (mg L

-1

)

C i

= inlet concentration (mg L

-1

)

177 C* = background concentration (mg L

-1

)

178 k = first-order areal rate constant (m yr -1 )

179 Q = hydraulic loading rate (m d

-1

)

180

181 Depending on the water quality parameter used to size the CW, the constants in the

182 model (C* and k) may be different for FWS CWs and SSHF CWs (Kadlec and Knight,

8

183 1996). For example, if using BOD

5

to size a CW, C*= 3.5 + 0.053C

i

for a FWS CW or a

184 SSHF CW and k would be 34 and 180 m yr -1 for a FWS CW and a SSHF CW,

185 respectively (Kadlec and Knight, 1996).

186

187 In CW design, it is difficult to account for variables such as climate variation, pre-

188 treatment control, and time to maturation. Therefore, design guidelines tend to be

189 conservative. Organic and SS loading rates not exceeding 6 g BOD

5

m -2 d -1 and 5 g SS

190 m

-2

d

-1

, respectively, are recommended for FWS CWs (US EPA, 1992). SSVF CWs may

191 be operated in single-pass mode, intermittently loaded 8-12 times d

-1

, or in recirculation

192 mode, intermittently loaded 16 – 24 times d

-1

(Brix and Arias, 2005). Winter and Goetz

193 (2003) recommend a maximum organic loading rate of 20 g COD m

-2

d

-1

and a maximum

194 SS influent concentration of 100 mg L -1 for SSVF CWs. Even when these loading

195 conditions are satisfied, the performance of CWs may be variable.

196

197 2.1.4 Wetland vegetation

198

199 Ireland has a cool temperate west maritime climate. In these climatic conditions, common

200 reed ( Phragmites australis (Cav.) Trin. ex Steud.) and common cattail ( Typha latifolia

201 L.) are mainly planted in CWs. As the amount of oxygen released by the emergent

202 vegetation into the surrounding soil is small (Armstrong et al., 1990), anaerobic

203 conditions predominate.

204

9

205 Harvesting of the emergent macrophytes has a pronounced effect on the growth and

206 nutrient uptake rates. Although nutrient uptake and growth rates are higher in young

207 vegetation stands (Greenway and Whoolley, 2001), other factors such as nutrient loading

208 and hydraulic retention time (HRT) may significantly affect the uptake rates (Reddy et

209 al., 2001; Hardej and Ozimek, 2002). In cool temperate west maritime climates, shoot re-

210 growth depends on the time of year at which harvesting takes place (M.G. Healy,

211 unpublished data). Harvesting during June/July produces good shoot re-growth, whereas

212 August/September harvesting tends not to produce significant re-growth.

213

214 2.1.5 Treatment efficiency

215

216 SSHF CWs are ideal for cold climates because wastewater treatment occurs below the

217 surface (Werker et al., 2002). They are the most common CW system used in Europe

218 (Vymazal, 2005). SSHF CWs have good organic, SS and faecal coliform removal rates

219 but have poor NH

4

-N removal rates (Neralla et al., 2000; Weaver et al., 2001; Steer et al.,

220 2005, Vymazal, 2005). In Texas, USA, Neralla et al. (2000) monitored 8 SSHF CWs

221 comprising gravel media ranging in size from 0.95 to 1.6 cm and receiving domestic

222 effluent from a septic tank. Under organic loading rates ranging from 2 to 5 g BOD

5

m

-2

223 d

-1

, average effluent BOD

5

and SS removals of 80% and 88%, respectively, were

224 measured (Table 1). An average NH

4

-N removal of 39% was also measured and

225 nitrification did not occur. These results were similar to Steer et al. (2005) who studied

226 the performance of 8 SSHF CWs treating domestic effluent, comprising two 25m 2 SSHF

227 CWs connected in series and preceded by a septic tank. Over a 5 yr. duration, average

10

228 BOD

5

and SS removals of 69-98% and 77-83%, respectively, were measured and NH

4

-N

229 was reduced by approximately 70% (Table 1).

230

231 SSVF CWs are commonly used for domestic wastewater treatment. When the organic

232 loading rate does not exceed a maximum allowable organic loading rate of 20 g COD m

-2

233 d

-1

(Winter and Goetz, 2003), they effectively remove organic matter, SS and nutrients

234 (von Felde and Kunst, 1997). Luederitz et al. (2001) intermittently loaded a SSVF CW,

235 comprising a 0.6 m active sand layer (sand/gravel, 0 – 4 mm) 800 m

2

in area and

236 preceded by an anaerobic digester, at an organic loading rate of 35 g COD m

-2

d

-1

(21 g

237 BOD

5

m

-2

d

-1

) and measured a COD removal of 94% and Tot-N removal of 61% (Table

238 1). With a SSVF CW having the same active sand layer but preceded by two unaerated

239 ponds and receiving an organic loading rate of 20 g COD m -2 d -1 (10 g BOD

5

m -2 d -1 ),

240 COD and Tot-N removals were 99.5% and 93.8%, respectively (Table 1).

241

242 Recently, a modified version of the SSVF CW, the two-stage vertical flow constructed

243 wetland (VFCW), has been gaining popularity in France, where there are currently

244 around 400 VFCWs in operation (Molle et al., 2006). The first stage of this system

245 comprises 3 parallel vertical flow sand filters which are alternately intermittently dosed

246 with raw wastewater at an organic loading rate of 300 g COD m

-2

d

-1

. In this first stage,

247 COD and SS removal takes place. They contain a 30 cm-deep fine gravel layer (2-8 mm

248 in size) which overlies a 10-20 cm-deep transition layer (5 mm in size) and a 10-20 cm-

249 deep drainage layer (20-40 mm in size) (Molle et al., 2005). The second stage comprises

250 two identical vertical flow sand filters which contain a 30 cm-deep fine gravel layer

11

251 (effective grain size, d

10

< 0.40 mm) which overlies a 10-20 cm-deep transition layer (3-

252 10 mm in size) and a 10-20 cm-deep drainage layer (20-40 mm in size) (Molle et al.,

253 2005). Nitrification mainly occurs in the second stage. Results from these systems have

254 been good with COD and SS removals of 90% and 95%, respectively, being measured

255 and nitrification at 85% (Molle et al., 2005).

256

257 FWS CWs are also effective in organic matter, SS, and faecal coliform removal (Ran et

258 al., 2004) but, similar to SSHF CWs, have low N removals (Healy et al., 2002; Ran et al.,

259 2004). Studies have reported settlement as the main N removal pathway (Toet et al.,

260 2005). In a 2-cell FWS CW, planted with duckweed and preceded by a preliminary

261 storage tank and a primary sedimentation tank, Ran et al. (2004) measured average BOD

5

262 and SS removals of 71% and 80%, respectively, when the system was loaded at an

263 organic loading rate of 16 g BOD

5

m

-2

d

-1

. Removal of N within the system seemed to be

264 due mainly to sedimentation and plant uptake, as NH

4

-N removals of 14% were measured

265 (Table 1).

266

267 When FWS CWs are in a marsh - retention pond - marsh formation, low flushing rates

268 and little surface cover means that eutrophication may occur in the retention pond during

269 warmer periods of the year (Healy and Cawley, 2002). In a 2-year study of a 3-cell FWS

270 CW for tertiary treatment of municipal wastewaters in Williamstown, Ireland, Healy and

271 Cawley (2002) measured average BOD

5

and SS removals of 49% and 90%, respectively

272 (Table 1) but noted the occurrence of algal blooms in the retention pond during the

273 summer months.

12

274

275 2.2 Intermittent sand filtration

276

277 ISF has been used for the treatment of domestic wastewater for over a hundred years.

278 Sand filters may be operated either in single-pass or recirculation mode. In single-pass

279 mode, following primary sedimentation, the wastewater is intermittently dosed onto a

280 stratified sand filter (Gross and Mitchell, 1985).

281

282 On a single pass through the system, organic carbon removal, ammonification and

283 nitrification occurs. Factors affecting the retention of bacteria in porous media include

284 straining, the grain size of the filter media, and the hydraulic loading rate (Stevik et al.,

285 2004). Removals of greater than 99.9% have been recorded for faecal coliforms

286 (Vanlandingham and Gross, 1998). A study comparing single-pass sand filters (33.5 m

2

),

287 FWS CWs (53 m

2

), and peat biofiltration systems (28 m

2

) for the treatment of septic tank

288 effluent (Puraflo

TM

, Bord na Mona, Ireland) has shown that single-pass sand filters have

289 the greatest organic and nutrient removal efficiency, although the difference in

290 performance between the sand filtration and peat biofiltration systems is small (White,

291 1995). White (1995) measured organic carbon removals of 92% and nitrification of 91%

292 for sand filters. Organic carbon removals of 87 and 82% were measured for the peat

293 biofiltration and constructed wetland systems, respectively. No nitrification occurred in

294 the constructed wetlands, and the percentage nitrification in the peat biofiltration systems

295 was 90%.

296

13

297 Virus removal has also been estimated to occur in the first 30 cm of a stratified sand filter

298 sand (Gross and Mitchell, 1985; Gross, 1990), although removal is dependent on the

299 hydraulic loading rate and degree of saturation of the filter (Reneau et al., 1989). In a

300 series of columns containing medium concrete sand (d

10

= 0.32 mm) and loaded with

301 dechlorinated tap water containing MS2 bacteriophage at hydraulic loading rates of 51,

302 81, 12.2, and 16.3 L m

-2

d

-1

, Vanlandingham and Gross (1998) found average MS2 phage

303 removal efficiencies of 99.6%, 98.6%, 99.9%, and 97.2%, respectively.

304

305 In a normal single-pass filter operation, denitrification is limited by the absence of

306 reducing conditions following nitrification and the lack of an available carbon source.

307 This leads to poor Tot-N reduction and an effluent that is high in NO

3

-N. In order that

308 ISF offers a viable treatment alternative to conventional treatment methods, NO

3

-N in the

309 effluent needs to be denitrified. Recirculation of a major portion of the nitrified effluent

310 from the sand filter through a denitrifying anoxic zone receiving the influent wastewater,

311 located before the filter, offers a solution to this problem (USEPA, 1980). The

312 recirculation ratio is defined by:

313

314

 

Q r

Q

(2)

315

316 where

is the recirculation ratio, Q r is the return flow from the filter to the anoxic

317 recirculation tank, and Q is the influent wastewater. Alternatively, external carbon

318 sources can also be used in an anoxic reactor positioned after the nitrification reactor.

319 Researchers have utilised methanol, ethanol, glucose, and acetate in denitrification (Lamb

14

320 et al., 1990; Carley and Mavinic, 1991). However, the widespread use of these chemicals

321 has been hampered by the possibility of environmental hazards due to the toxicity of

322 substances such as methanol (Lamb et al., 1990). In attempts to reduce the hazards

323 associated with such systems, researchers began to consider septic tank effluent as a

324 source of carbon. However, the success of such a system depends largely on system

325 design. Short contact times, a low carbon to nitrogen ratio (C:N) in the recirculation tank

326 and high recirculation rates all result in poor denitrification rates in the system (Tebbutt,

327 1998; van Buuren et al., 1999).

328

329 To date, a number of variations on recirculating sand filters have been explored. At a

330 hydraulic loading rate of 155–195 L m

-2

d

-1

, Lamb et al. (1990) found that denitrification

331 was achieved when the sand filter effluent was mixed with three different carbon sources

332 (methanol, ethanol and septic tank effluent) prior to entering a buried rock tank. With

333 septic tank effluent as the carbon source, only 25% denitrification occurred, whereas

334 methanol and ethanol produced a mean denitrification of 99%. This poor performance for

335 the septic tank effluent was due to a C:NO

3

-N ratio of 0.7:1 in the rock tank. Ethanol and

336 methanol resulted in C:NO

3

-N ratios of 2:1 and 4:1, respectively. Gold et al. (1992)

337

338 encountered similar poor denitrification performance of a sand filter when the nitrified effluent was recirculated through a recirculation tank with an

ratio of 4:1 to 5:1. Tot-N

339 removal increased from 8.4% (on a single pass through the sand filter) to 20% for

340 recirculation. Again a low BOD

5

:NO

3

-N of approximately 1:1 in the recirculation tank

341 limited denitrification. Optimal conditions for maximum denitrification occur at a COD:

15

342 Tot-N ratio in the range of 4:1 to 5:1 for organic sludge (Henze et al., 1997, Martinez,

343 1997; van Buuren et al., 1999).

344

345 2.2.1 Biological clogging of filter media

346

347 Biological clogging of the filter media is often problematic (Siegrist, 1987). Clogging of

348 the upper layers of the sand filter increases the average water retention time in the filter

349 and reduces the effective area available for water infiltration to a point where ponding

350 occurs.

351

352 Surface clogging may be due to a number of causes. Accumulation of microorganisms on

353 surfaces as biofilms is believed to be the cause of surface sealing (Siegrist and Boyle,

354 1987; Vandevivere and Baveye, 1992; Schwager and Boller, 1997; Bouwer et al., 2000).

355 In this process, hydrated extracellular polymers (exopolymers) as well as cells

356 accumulate on the upper layers of the sand media and give rise to a reduction in

357 permeability (Schwager and Boller, 1997). Siegrist and Boyle (1987) found an

358 accumulation of organic matter in the upper sand layer, and hypothesised that it may have

359 undergone humification, and gradually filled the pore space, reducing the permeability.

360 The type of filter media (Jowett and McMaster, 1995) and the deposition of organic and

361 inorganic solids on the surface layer (Platzer and Mauch, 1997; Rodgers et al., 2004)

362 have also been considered to cause surface sealing.

363

16

364 Siegrist (1987) used gravimetric water content profiles to measure pore size reduction in

365 an aggregate loaded with domestic septic tank effluent, greywater septic tank effluent,

366 and tapwater. The most significant increases in water content near the infiltrative surface

367 were attributed to the pore size reduction due to biomass build-up and, after 62 months of

368 operation, the water contents in the upper 4 cm layer for treating tapwater and domestic

369 septic tank effluent were 0.26 and 0.36, respectively.

370

371 Conservative tracers such as sodium bromide (NaBr) can also be used to illustrate this

372 effect (Schudel and Boller, 1990). Schwager and Boller (1997) used an F-curve

373 (Levenspiel, 1999) in a ‘clean’ and ‘used’ filter to show the effect of biomass growth in

374 the top filter layer on the prolongation of the retention time of a liquid.

375

376 2.2.2 Effect of dosing frequency on treatment performance.

377

378 An increase in dosing frequency will have a beneficial effect on the treatment

379 performance of a single-pass sand filter (Anderson et al., 1985). In a study of 12 shallow

380 sand filters (0.38 m deep), with four sets having the same d

10

(0.29 mm) and uniformity

381 coefficient (Cu=4.5), Darby et al. (1996) found that for the same daily hydraulic loading

382 rate, increasing the application frequency from 4 to 24 times per day resulted in a slight

383 but statistically significant increase in the removal of turbidity, COD and organic-N

384 (Table 2). In a field-scale experiment, Boller et al. (1993) showed that in a sand filter

385 containing coarse sand (d

50

=1.4; Cu=4) dosed daily with septic tank effluent, the filter

386 performed better when loaded with 4 flushes of 10 L m

-2

than when loaded with 1 flush

17

387 of 40 L m

-2

or 2 flushes of 20 L m

-2

. Average sand filter effluent NH

4

-N concentrations

388 were 21.0, 17.2 and 3.8 mg NH

4

-N L -1 at 1, 2, and 4 daily flushes, respectively. The

389 results from a pilot-scale sand filter unit (Boller et al., 1993), loaded at 6 times per day,

390 are tabulated in Table 2.

391

392 2.2.3 Effect of media size and uniformity coefficient on treatment performance.

393

394 The uniformity coefficient (Cu) is defined as (Craig, 1997):

395

396 Cu

 d

60 (3) d

10

397

398 where d

60

and d

10

denote the largest possible sizes of the 60% and 10% fractions,

399 respectively. The higher the uniformity coefficient, the larger the range of particle sizes in

400 the sand. This may affect filter performance at higher hydraulic loading rates, as a well-

401 graded sand means that small particles may fill interstices between large particles, leading

402 to a reduction in the hydraulic conductivity, and possible blocking of the filter media.

403

404 Design specifications recommend that the sizing of the filter media should be in

405 accordance with its use (USEPA, 1980; Ball and Denn, 1997; Loomis and Dow, 1999).

406 For single-pass operation with a filter depth of 0.61 – 0.91 m, a d

10

of 0.33 mm and Cu<3

407 are recommended, whereas in recirculation mode, a d

10

of 1.5-3.0 mm and Cu of 1.3-2.5

408 are recommended. Although increased nitrification has been attributed to a coarse grain

409 size (Nielsen et al., 1993), performance effects appear to be mostly related to hydraulic

18

410 and organic loading rate and dosing frequency (Darby et al., 1996). Nichols and Abboud

411 (1995) found that complete organic carbon removal and good Tot-N removals (68-74%)

412 were still attained when a chip stone (d

10

=1.85 mm; Cu=1.9) and a pea gravel (d

10

=2.05

413 mm; Cu=2.7) were used in a single-layer recirculating sand filter treating effluent from a

414 restaurant.

415

416 2.2.4 Effect of organic and SS loading rates on performance.

417

418 The organic and SS loading rates have a significant effect on the clogging and

419 performance of a filter. The US EPA (1980) recommend that, in single-pass sand filters,

420 the organic loading rate should not exceed 22 g BOD

5

m

-2

d

-1

at a hydraulic loading rate

421 of 40-80 L m -2 d -1 , whereas in recirculating sand filters the organic loading rate should not

422 exceed 22 g BOD

5

m

-2

d

-1

at a hydraulic loading rate of 120 – 200 L m

-2

d

-1

. Results from

423 single-pass and recirculating sand filters are given in Tables 2 and 3, respectively.

424

425 A number of studies have investigated the filter performance under varying loading rates

426 in an attempt to quantify the maximum organic and SS loading rates that can be safely

427 applied to a filter (Darby et al., 1996; Nichols et al., 1997). Nichols et al. (1997) found

428 that, when the COD and SS loading rates on a 1 m-deep, 3-layer stratified sand filter were

429 increased to 15 and 1.0 g m

-2 d

-1

, respectively, reduced rates of nitrification occurred.

430

431 Effert et al. (1985) applied domestic effluent onto a sand filter 76 cm deep (d

10

= 0.4mm;

432 Cu = 2.5) at an organic loading rate of 20 g BOD

5

m

-2

d

-1

and found that almost complete

19

433 organic removal occurred, but in the absence of denitrifying conditions, Tot-N was

434 reduced by only 1-11%, with the effluent Tot-N mainly present as NO

3

-N. In an analysis

435 of 50 sand filters, with an effective size (d

10

) of 0.2-0.3 mm, treating domestic effluent,

436 Nielsen et al. (1993) showed that at an average organic loading rate of approximately 10

437 g BOD

5

m

-2

d

-1

, 90-95% of the BOD

5

and 30-45% of the Tot-N were removed.

438

439 The organic and SS loading rates can have a significant effect on the clogging and

440 performance of a filter. A number of studies have investigated the filter performance

441 under varying loading rates in an attempt to quantify the maximum organic and SS

442 loading rate which can safely be applied to a filter (Nichols and Abboud, 1995; Darby et

443 al., 1996).

444

445 2.3 Alternative single-pass filter designs.

446

447 A number of alternative filter designs have been proposed. Latvala (1993) proposed the

448 use of a multilayer intermittent sand filter, wherein wastewater is loaded through three

449 gravel layers at incremental depths in the layered filter column. Varying the organic

450 loading rate between 83 and 166 g COD m

-2

d

-1

, only 54% of the organic matter was

451 removed in the filter.

452

453 Jowett and McMaster (1995) experimented with a set-up similar to that used later by

454 Leverenz et al. (2000). They used a single-pass unsaturated biofilter, composed of foam,

455 to treat synthetic domestic effluent at a hydraulic loading rate of 800 L m

-2

d

-1

. They

20

456 found that the system only performed well under conditions of forced ventilation, giving

457 complete nitrification and over 98% organic matter removal. Using natural air

458 convection, nitrification was incomplete (effluent NH

4

-N concentration was 10.2 mg L

-1

),

459 and organic matter removal was at 93%.

460

461 The multi-soil-layering (MSL) method has also been used to purify domestic effluents

462 (Wakatsuki et al., 1993; Luanmanee et al., 2001). It consists of 1.2 m-deep soil-mixture

463 blocks (containing metal iron and pelletised jute; the jute is used as a carbon-source for

464 denitrification) in a brick-like pattern with zeolite interlayers. They are capable of

465 operating under an organic and hydraulic loading rate of 4-15 g BOD

5

m

-2

d

-1

and 100-

466 850 L m

-2

d

-1

, respectively, without significant clogging. Over a 1-year study period, the

467 BOD

5

and Tot-N was reduced by 80-95% and 80-91%, respectively (Wakatsuki et al.,

468 1993). The Tot-N reduction may be due to NH

4

-N absorption onto the zeolite. The MSL

469 system is, however, a mechanical aeration system. It is highly sensitive to aeration

470 (Luanmanee et al., 2001) and excessive dosing can lead to reduced denitrification rates.

471

472 In a study using non-woven textile fabrics (NWTF) as filter media, Leverenz et al. (2000)

473 used 3 filter configurations (hanging sheets of textile fabric, single layer textile fabric

474 chips (approximately 30mm x 20mm in size), and 3 independent layers of textile fabric

475 chips (size not quoted)) to treat domestic-strength wastewater over a period of 7 months.

476 Due to the random stacking arrangement of the textile fabrics, the filter media had a high

477 porosity and hydraulic conductivity. The filters were operated in recirculation mode with

478 recirculation ratios of 9:1 and 3:1 for two hydraulic loading rates of 410 and 1220 L m

-2

21

479 d

-1

, respectively, on the plan surface area of the filter. Using mechanical aeration, the

480 filters produced an effluent that was low in nutrients and organic matter under maximum

481 COD and SS loading rates of 141 and 76 g m

-2

d

-1

, respectively.

482

483 2.4 SSVF CWs and ISF.

484

485 SSVF CWs remove organic matter, SS and nitrify N (Brix et al., 2002; Weedon, 2003)

486 but, similar to ISF, have poor long-term P removal rates (Brix and Arias, 2005). Both

487 systems are limited by the maximum organic loading rate that may be applied to their

488 surfaces. Depending on the strength of the influent wastewater, a maximum organic

489 loading rate of approximately 24 g COD m

-2 d

-1

may be applied in ISF (Rodgers et al.,

490 2005), whereas a maximum organic loading rate of 20 g COD m -2 d -1 is recommended for

491 SSVF CWs (Winter and Goetz, 2003). SSVF CWs are differentiated from ISF by their

492 surface covering of emergent vegetation which affects the infiltration of wastewater into

493 the filter media (Molle et al., 2006).

494

495 3. Treatment of dairy parlour wastewater

496

497 3.1 Constructed wetlands

498

499 To date, FWS CWs are the most widely used, low-cost and low-maintenance alternatives

500 to land spreading of dairy wastewaters in Ireland. Presently, over 13 farms in the Anne

22

501 Valley catchment, Ireland, use FWS CWs for the treatment of agricultural wastewater

502 (Dunne et al., 2005).

503

504 American guidelines for the design loading of SSHF CWs treating agricultural

505 wastewater (NRCS, 1991) recommend an areal loading rate of 7.3 g BOD

5

m

-2 d

-1

;

506 similar rates are used in wetland design for cool temperate climates (Cooper et al., 1996;

507 Dunne et al., 2005). New Zealand guidelines for the disposal of farm dairy wastewaters

508 (Tanner and Kloosterman, 1997) recommended that an FWS CW should only succeed

509 two waste stabilization ponds (an anaerobic and an aerobic pond, respectively) before

510 entering the wetland with an organic loading rate not exceeding 3 g BOD

5

m

-2

d

-1

. The

511 anaerobic pond reduces the BOD

5

and SS, and the aerobic pond carries out further

512 biological reductions. In a study of a FWS CW treating milkroom parlour wastewater in

513 Connecticut, USA, Newman et al. (2000) did not utilize a stabilization pond and found

514 that, under an organic loading rate of approximately 52 g BOD

5

m

-2 d

-1

, 76% of BOD

5

515 was removed and no nitrification occurred. One study (Mantovi et al., 2003) suggests that

516 the milking parlour should be designed to allow parlour washings and washings from the

517 holding room to be separated, so as the wetland only treats the effluent of lower organic

518 and nutrient content.

519

520 Results from these systems have been variable (Table 4). In a study of planted and

521 unplanted SSHF CWs, where the unplanted SSHF CWs acted as an experimental control,

522 Tanner (1995a,b) found that under 5-day carbonaceous biochemical oxygen demand

523 (CBOD

5

) loading rates ranging from 0.9 to 3.4 g CBOD

5

m

-2

d

-1

(unplanted) and 0.9 to

23

524 4.1 g CBOD

5

m

-2

d

-1

(planted), maximum CBOD

5

removals of 85% and 92%,

525 respectively, were measured. Ammonification was more pronounced with increasing

526 retention time, and Tot-N removal varied between 48 and 80 % for planted CWs. Similar

527 organic loading rates were used in a study on a 3-cell integrated FWS CW in Co.

528 Wexford, Ireland (Dunne et al., 2005) where, under organic loading rates varying from

529 2.7 to 3.5 g BOD

5

m

-2 d

-1

, good organic removal was measured but nitrification was not

530 complete during winter.

531

532 Cronk et al. (1994) also found that under reduced retention times (with loading rates of

533 60 g BOD

5

m

-2

d

-1

) BOD

5

and SS concentrations were not reduced to acceptable levels

534 after treatment in a 1-cell FWS CW, and that no significant reduction of TKN occurred

535 (Table 4). In a study on a dairy farm in Drointon in the UK (Cooper et al., 1996), a SSHF

536 CW was used to treat influent with an average BOD

5

concentration of 1192 mg L

-1

. The

537 system initially utilized only the wetland alone and performed poorly under an organic

538 loading rate of approximately 26 g BOD

5

m

-2

d

-1

. However, when two SSVF CWs and a

539 lagoon were installed in front of the SSHF CW, the system had an organic loading rate of

540 approximately 4 g BOD

5

m -2 d -1 and had good organic and SS removal rates but had

541 limited nitrification due to large fluctuations in the inlet wastewater strength (Table 4).

542 Utilizing a similar set-up (2-stage SSVF CW and a SSHF CW), Job (1992) obtained

543 BOD

5

and SS removals of approximately 65% and 90%, respectively, but nitrification

544 was limited (Table 4).

545

24

546 Even under significantly reduced organic loadings, SSHF and FWS CWs have under-

547 performed. In Italy, a study on a 2-cell FWS CW operated in series and monitored over a

548 26 month period, treating a mixture of domestic and dairy parlour washings at an average

549 influent organic loading rate under 2 g BOD

5

m

-2

d

-1

, showed that anoxic zones which

550 developed in the wetland inlet meant that nitrification was inhibited, producing an

551 effluent Tot-N which was mainly composed of NH

4

-N (Mantovi et al., 2003, Table 4).

552

553 3.2. Sand filtration

554

555 ISF treatment systems may be an efficient treatment alternative to conventional land-

556 spreading/reed bed treatment currently carried out in Ireland. To date, sand filters have

557 been used as a cost effective alternative to conventional septic tank/soil adsorption

558 systems for domestic wastewater (Rich, 1996; Loomis and Dow, 1999). However, they

559 are largely untested for the treatment of dairy parlour washings with high BOD

5

.

560

561 Soil filters have been used as an alternative treatment method for agricultural wastewaters

562 (Martinez, 1997); however they are limited by their hydraulic loading capacity. The

563

564 deposition of dispersed clay particles in the pore spaces of soils reduces the hydraulic conductivity and causes clogging to occur. Martinez (1997) developed the ‘Solepur’

565 process wherein an isolated field treatment plant was used to treat pig slurry. However,

566 the practical application of the process is limited by the low hydraulic loading rate of

567 approximately 1.3 L m -2 d -1 .

568

25

569 In ISF of dairy parlour wastewaters, best performance is achieved when the filter is

570 operated in recirculation mode. In a laboratory study, Healy et al. (2004) used a 0.9 m

571 deep sand filter with a recirculation ratio of 3:1; to treat high strength synthetic

572 wastewater (Table 3), the filter comprised stratified layers of coarse (d

10

= 0.45 mm) and

573 fine sand (d

10

= 0.11 mm). They found that it was able to treat synthetic agricultural

574 wastewater with an organic loading rate of 23.4 g COD m

-2

d

-1

and a system hydraulic

575 loading rate of 6.7 L m -2 d -1 . A maximum system hydraulic and organic loading rate of 10

576 L m

-2

d

-1

and 30 g COD m

-2

d

-1

, respectively, produced organic and Tot-N removals of

577 99% and 86%, respectively. Using the same filter operated in single-pass mode, Rodgers

578 et al. (2005) found that at a BOD

5

loading rate of 22 g m

-2

d

-1

, 37% of Tot-N occurred

579 (Table 2).

580

581 In this section, based on laboratory studies using intermittent sand filters for the treatment

582 of synthetic dairy parlour washings (Healy et al., 2004; Rodgers et al., 2004; Rodgers et

583 al., 2005; Healy et al., 2006), the design rationale for a pilot-scale sand filter is discussed

584 (Figure 1 and Table 5). Possible differences that may exist between laboratory synthetic

585 dairy parlour washings and farm dairy parlour washings are acknowledged and

586 conservative design is recommended.

587

588 3.2.1 Farmyard management: house-keeping and water usage

589

590 In farms, volumes of water used for wash-down of yard areas, pipeline cleaning and

591 rinsing and stormwater run-off from soiled yards lead to a final effluent of variable

26

592 volume and concentration. The water volumes generated may vary according to the

593 practices applied on the farms. Factors such as hosing down practices and the number of

594 cows milked affect the volumes generated. The design specification detailed below

595 applies to farms with a water usage not greater than 50 L cow

-1

day

-1

(Department of the

596 Environment and Department of Agriculture, Food and Forestry, 1996). Prior to the

597 installation of a recirculating sand filtration system, water usage should be monitored by

598 the installation of a water meter on the rising main and cleaning practices revised to

599 minimise volumes.

600

601 3.2.2 Organic and SS loading rates

602

603 The operation and performance of sand filters are determined by the organic and

604 suspended solids loading applied to them. A design specification similar to that illustrated

605 in Figure 1 is proposed. This design proposes a holding tank comprising two

606 compartments, a settlement chamber with a retention time of 1 day, into which the dairy

607 parlour and yard washings and three-quarters of the volume of effluent from the sand

608 filter flow and a pumping chamber with a pump assembly and screen. Settled wastewater

609 flows from the settlement chamber through a baffled pipe into the pumping chamber. The

610 contents of the pumping chamber are pumped a minimum of 4 times a day onto the sand

611 filter to give a hydraulic loading of 10 L m

-2

dose

-1

at each pumping (40 L m

-2

d

-1

).

612

613 3.2.3 Sand filter media, type and depth

614

27

615 Design specifications recommend that the sizing of the filter media should be in

616 accordance with its use (USEPA, 1980; Ball and Denn, 1997; Loomis and Dow, 1999).

617 For a recirculating sand filter, sands with a d

10

of 1.5-3.0 mm and a coefficient of

618 uniformity of 1.3-2.5 are recommended. A sand media depth of not less than 0.9 m is

619 recommended. The sand filter must be regularly checked for ponding and ideally the

620 column could be instrumented with tubes for time domain reflectrometry (TDR) probes

621 to monitor the build-up of biomass within the column (Healy et al., 2004; Rodgers et al.,

622 2005).

623

624 3.2.4

Wastewater application to the sand filter, including the loading rate and

625 frequency

626

627 The wastewater is applied to the sand filter via a distribution manifold (Figure 1) at 4

628 times the influent hydraulic flow rate. The distribution manifold should be designed so

629 that the water flow from each orifice should be approximately the same (US EPA, 1982).

630

631 A maximum filter loading rate of 40 L m -2 d -1 of a 3000 mg L -1 COD and 300 mg L -1 Tot-

632 N wastewater was successfully treated in the laboratory (Healy et al., 2006). It is

633 proposed that this design loading be used in the full-scale plant. In laboratory studies,

634 good results were achieved with the application of wastewater in four daily doses to a

635 sand filter (Healy et al., 2004; Rodgers et al., 2005). The pumps were sized to operate for

636 a period of 5 minutes per dose.

637

28

638 3.2.5

Wastewater treatment-post sand filtration

639

640 After passing through the sand filter, the remaining quarter of the effluent from the sand

641 filter flows by gravity onto a woodchippings/sand tank where further denitrification

642 occurs. Healy et al. (2005) found that when a loading rate of 2.9 mg NO

3

-N kg

-1

d

-1

was

643 applied to a woodchippings/sand horizontal flow filter, a 97% reduction in NO

3

-N

644 occurred.

645

646 The outflow from the woodchippings/sand horizontal flow filter can lead to a percolation

647 area in permeable soil or to a suitable watercourse in slow-draining soils. The settlement

648 and pumping chambers must be regularly checked and desludged.

649

650 3.2.6

Actions to be taken in the event of clogging of the sand filter

651

652 If excess organic and suspended solids loading rates are applied to the sand filter,

653 clogging of the surface layer will occur. In a study of a laboratory intermittently loaded

654 stratified sand filter treating synthetic agricultural wastewater, Rodgers et al. (2004)

655 investigated the characteristics of the clogging layer, following the occurrence of surface

656 ponding. Measurements of field-saturated hydraulic conductivity within the upper layer

657 of the sand filter indicated that the effects of the build-up of organic and inert matter may

658 have extended to a depth of 0.165 m into the layer. If clogging occurs, it would be

659 necessary to replace the surface layer of sand.

660

29

661 4. Conclusions and recommendations

662

663 This article reviewed the currently used practices of constructed wetlands, single-pass

664 and recirculating sand filters for the treatment of dairy parlour wastewaters. To date, ISF

665 of high strength wastewaters is an emerging technology; therefore, there is not strong

666 research antecedence in their use in an agricultural setting. While FWS CWs, SSHF and

667 SSVF CWs are regularly used for the treatment of agricultural wastewaters, they appear

668 to be limited by the organic loading rate that may be applied to them. In comparison, ISF,

669 though possibly requiring greater monitoring and maintenance can accept a higher

670 organic loading rate and has a much smaller footprint. Research should be prioritised in

671 the following areas:

672 (1) Pilot-scale studies examining ISF for the treatment of dairy parlour wastewaters should be completed. 673

674 (2) Work needs to be done to optimise the design of CWs – particularly under Irish climatic conditions – to reduce the areal requirement and/or increase the organic 675

676 loading application rate.

677

678 Acknowledgements

679

680 The authors are grateful to Teagasc for the award of a Walsh fellowship to the first author

681 and for financial support for the work. The authors acknowledge the technical help of M.

682 Rathaille, M. O’Brien and G. Hynes (NUI, Galway).

683

30

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1059

1060

47

1069

1070

1071

1072

1073

1074

1075

1076

1077

1078

1079

1061

1062

List of figures.

1063 Figure 1. Illustrated layout of a proposed recirculation sand filter system for treating dairy

1064 wastewaters.

1065

1066

1067

1068

1080

1081

1082

1083

48

Table 1. Data from wetlands treating domestic wastewaters.

____________________________________________________________________________________________________________________________________________________________________________

Reference Location Wetland type

Organic loading Pre-treatment Influent Quality Effluent Quality rate (mg L -1 ) (mg L -1 )

______________________________________________________________________________________

BOD

5

COD SS Tot-N NH

4

-N BOD

5

COD SS Tot-N NH

4

-N

____________________________________________________________________________________________________________________________________________________________________________

Healy and Cawley, 2002

Luederitz et al., 2001

Maehlum et al., 1995.

Neralla et al., 2000

Ran et al., 2004

Steer et al., 2005

Ireland FWS

Germany SSVF

Germany SSVF

Norway

USA

Israel

USA

SSHF

SSHF

SSHF

FWS

SSHF

1 g BOD

5

m -2 d -1 Aerator/clarifier 18

21 g BOD

5

m -2 d -1 Anaerobic digester 490

10 g BOD

5

m -2 d -1 2 unaerated ponds 335

4 g BOD

5

m -2 d -1 Septic tank

2 g BOD

5

m -2 d -1 Septic tank

5 g BOD

5

m -2 d -1 Septic tank

16 g BOD

5

m -2 d -1 Storage tank and

200

69

177

142

- sedimentation tank

Septic tank 131

-

816

691

420

-

-

298

-

52

-

-

-

39

26

65

25

29

126

100

91

-

-

-

-

2.2

-

-

-

49

24

51

31

9

24

3

10

10

17

40

23

-

44

12

195

-

-

93

-

5

-

-

-

16

7

13

3

15

66

6

48

-

-

-

-

0.8

-

-

-

32

18

44

2

SSHF - Septic tank 173 - 45 - 41 53 - 8 - 23

____________________________________________________________________________________________________________________________________________________________________________

SSHF = subsurface horizontal flow constructed wetland; SSVF = subsurface vertical flow constructed wetland; FWS = free-water surface constructed wetland.

The first wetland has a population equivalent (P.E.) of 1. The second wetland has a P.E. of 6.

49

Table 2.

Filter design and loading rates from previous studies on single – pass sand filters.

__________________________________________________________________________________________________________________________________________________________________

Reference Hydraulic loading rate Wastewater type Frequency

(L m

-2

d

-1

) (times d

-1

)

Filter loading rates Filter depth Filter media

COD SS

__ g m

-2

d

-1

__ (m)

COD

% removals

Tot-N NH

4

-N PO

4

-P SS

__________________________________________________________________________________________________________________________________________________________________

Darby et al. (1996) 81 Domestic 24 11.5 2.3 0.38 Single-layer filter 94.9 - 99.5 - 98.1

326

41

163

24

4

4

47

5.8

23

9.4

1.2

4.7 d

10

= 0.29 mm

Cu= 4.5

71.6

96.3

92.1

-

-

-

95.7

99.7

-

-

90.7

98.2

99.2 - 94.7

98.6 26.1 93.8 Boller et al. (1993) 30

Nichols et al. (1997) 12.5

50

Rodgers et al. (2005) 20

6.7

EPA guidelines

<40

Domestic

Domestic

Agricultural

Agricultural

Domestic

6

-

-

4

4

>2

8.0 1.7

3.8 0.2

15 1.0

26

24

9.3

5.3

5.0

3.9

1.0

1.0

0.9 m

0.9 m

0.61-0.91

Single-layer filter 90.5 -

Cu = 4.4

Stratified sand - filter -

-

-

Stratifed sand filter 96

Single-layer filter d

10

= 0.4 - 1 mm

Cu< 4

99

27

37

99

85

37

36

89

-

88 94 100

100 83 100

__________________________________________________________________________________________________________________________________________________________________

US EPA (1980), Calculations based on a typical flow of 24 L m

-2

d

-1

with a septic tank effluent COD and SS concentration of 389 and 163 mg L

-1

, respectively (EPA, 1999)

50

Table 3. Filter design and loading rates from previous studies on recirculating sand filters (adapted from Healy et al., 2006).

________________________________________________________________________________________________________________________________________

Reference Forward flow

Recirculation Filter loading rates Filter media Filter depth Comments ratio COD SS

L m -2 d -1 g m -2 d -1 m

________________________________________________________________________________________________________________________________________

Crites et al. (1997) 9.6 5:1 ~2 <1 Single-layer filter 1.0 Domestic wastewater. Effluent d

10

= 3 mm; C u

<2 treated to discharge standards.

Loudon et al. (1985) 42 4:1 ~7 2 Single-layer filter 1.0 Domestic effluent. Nitrification d

10

= 0.3mm; C u

=4 incomplete in filter.

Healy et al. (2004) 6.67 4:1 23.4 3.2 Stratified sand filter 1.0 Synthetic agricultural-strength

Top layer: d

10

= 0.45mm; effluent.

Cu: 3

EPA guidelines

120-200 3:1-5:1 34 5.8 Single-layer filter 0.61-0.91 d

10

= 1.0-1.5 mm; C u

<4

________________________________________________________________________________________________________________________________________

The forward flow is the hydraulic loading rate on the sand filtration system.

US EPA (1980). Calculations based on a forward flow of 160 L m -2 d -1 at a recirculation ratio of 5:1, and with COD, SS, and TKN concentrations of 35, 6 and 8 mg L -1 in the recirculation tank (using data from Leverenz et al., 2000)

51

Table 4. Data from wetlands treating agricultural wastewaters.

____________________________________________________________________________________________________________________________________________________________________________

Reference Location Wetland type

Organic loading Pre-treatment Influent Quality Effluent Quality

rate (mg L -1 ) (mg L -1 )

________________________________________________________________________

BOD

5

SS Tot-N NH

4

-N BOD SS Tot-N NH

4

-N

____________________________________________________________________________________________________________________________________________________________________________

Cooper et al., 1996 Drointon, UK SSHF 4 g BOD

5

m -2 d -1 Anaerobic lagoon + 2 vertical

350 400 - 200 61 100 - 180

Cronk et al., 1994 Maryland, US FWS

Geary and

Moore, 1999

Job, 1992 Rugeley, UK

Karpiscak et al., 1999 Arazona, US

Knight et al., 2000 US

Mantovi et al., 2003 Casina, Italy

Australia FWS

SSHF

FWS

FWS

~60 g BOD

5

m -2 d -1

5.6 g BOD

5

m -2 d -1

- flow reed beds

Settling tank

+ anaerobic pond

Anaerobic lagoon + 2 vertical

Solids separator

7130

220

400

5540 -

- -

150

126

400 - 350 flow reed beds

~12 g BOD

5

m -2 d -1

22 g BOD

5

m -2 d -1

4 anaerobic lagoons

Settling basin

~1.9 g BOD

5

m -2 d -1 Septic tank +

Solids separator

242 911 - 188

442 1111 103 105

451 680 64 22

2730 990

90

150 50

246

28

-

641

141 592

60

-

-

-

- 112

51 42

33

120

105

300

25

___________________________________________________________________________________________________________________________________________________________________________

SSHF = subsurface horizontal flow constructed wetland; FWS = free-water surface constructed wetland.

52

Table 5. Sizing a full-scale recirculation sand filter system for treating dairy parlour wastewater based on a laboratory study.

________________________________________________________________________________________________________________________________________________

Herd size Daily wastewater g COD to Min. holding tank Recirculation Sand filter Woodchipping/ Volume flow

† be treated

‡ volume flow

¶ area

¥ sand mass reqd.

§ reqd.

# m 3 d -1 g COD d -1 m 3 m 3 m 2 kg m 3

Q 3Q

________________________________________________________________________________________________________________________________________________

50 2.5 7500 10 7.5 247 5 x 10 4 64

100 5.0 15000 20 15.0 493 1 x 10 5 128

150 7.5 22500 30 22.5 740 1.6 x 10 5 205

200 10 30000 40 30.0 987 2 x 10 5 256

§

#

________________________________________________________________________________________________________________________________________________

With each cow producing 50 L d -1 (0.05 m 3 d -1 ) (Department of the Environment and Department of Agriculture, Food and Forestry, 1996)

Assuming a yearly average COD concentration of 3000 mg L -1 .

¥

In laboratory conditions, optimum COD loading rate applied to recirculating sand filter was 30.4 g COD m -2 d -1 under a system hydraulic loading rate of

10 L m -2 d -1 and an average organic carbon concentration of 3045 mg COD L -1 .

Assuming a final effluent from the recirculating sand filter has a NO

3

-N concentration of 60 mg L -1 with each cow producing 50 L d

In the laboratory experiment, a NO

3

-N loading rate of 2.9 x 10 -6 g NO

3

-N g -1 woodchippings/sand mixture produced 98% NO

In the laboratory study the woodchippings/sand mixture had a bulk density of 0.78 g cm -3 , which is applied here.

-1 .

3

-N reduction .

53

Figure 1.

4Q

From dairy farm

Q 3Q

Settlement chamber

Screened pump

Intermittent sand filter

Q Q

Woodchippings/ sand tank

To percolation

54

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