Avoiding dust explosions: preventive measures Estellito Rangel Junior Petrobras Rio de Janeiro, Brazil estellito@petrobras.com.br ABSTRACT In recent years it has been noticed about fires and explosions in grain storage installations that resulted in losses of millions of dollars and also with fatal victims. This paper discusses some occurrences of dust explosions, describes the dust characteristics and suggests preventive measures. 1. Introduction The risk of dusts explosions is present during all stages of the grain processing industry, starting from the reception of the raw material, passing through the conveyor belts, until its storage in silos. The main component of this risky formula is the possible high concentration of organic dust in the typically confined spaces of locations such as underground tunnels and elevators. In recent years we heard about fires and explosions in grain storage installations that resulted in losses of millions of dollars. Examples of such occurrences are: De Bruce grain elevator in Wichita, KS, USA, exploded in 1998, killing seven and injuring several others. The ground shook was so hard that people believed that McConnell Air Force Base, close to the facility, was under missile attack. Windows were shattered for blocks in every direction. Flames shot hundreds of feet into the air and the smoke plume shocked city habitants In February 1999, a deadly fire and explosion occurred in Jahn Foundry in Massachusetts, with 3 killed and 9 injured. The Occupational Safety Health Administration (OSHA) and state and local officials conducted a joint investigation of this incident. The joint investigation report indicated that a fire initiated in a shell molding machine from an unknown source and then extended into the ventilation system ducts by feeding on heavy deposits of phenol formaldehyde resin dust. In January 2003, devastating fires and explosions destroyed the North Carolina’s West Pharmaceutical plant that manufactured rubber drug-delivery components. Six employees were killed and 38 people, including two firefighters, were injured. Imperial Sugar refinery, in Port Wentworth, GA, USA, in February 2008 resulted in 14 people died and 38 people injured. The Figure 1 shows the results of this explosion. Figure 1: Explosion at Imperial Sugar, USA, February 2008 2. The dust behavior With the majority of grains the development of a fast combustion process is possible when particles’ size are small enough. Under confinement, this combustion will reach explosive conditions that produce hot gases, which in turn will increase the pressure inside the vessel. As in the case of gas explosions, a dust explosion is caused by the simultaneous presence of a source of ignition and an explosive atmosphere. Sparks produced by electrical equipment (motors, control stations, switches, etc.), are one of the most common sources of ignition found in industrial installations with explosive atmospheres. The amount of dust accumulation necessary to cause an explosive concentration can vary greatly. This is because there are so many variables – the particle size of the dust, the method of dispersion, ventilation system modes, air currents, physical barriers, and the volume of the area in which the dust cloud exists or may exist. As a result, simple rules of thumb regarding accumulation (such as writing in the dust or visibility in a dust cloud) can be subjective and misleading. The hazard analysis should be tailored to the specific circumstances in each facility and the full range of variables affecting the hazard. It is important to note that the behavior of combustible dusts atmospheres are quite different from gas atmospheres. While flammable gases spread out in air seek to reach a homogeneous concentration, dust particles tend to settle and to accumulate in layers. Dust particles can also remain in suspension for a given period of time, depending on their density and the particles' diameters. Dust particles can also travel from the point where they were released to other points farther away. Leakage from one piece of process equipment to another piece of equipment or component, such as into an electrical terminal panel, is therefore possible. Dust can also accumulate on the floor, on piping, on equipment surfaces, on cable trays, and on electrical motors, for example. The Figure 2 shows a dusty environment. Figure 2: An industrial plant with grain transportation The dust particles can come into contact with sources of ignition when accumulated in layers, when forming a cloud, when in suspension, and also during "normal" operation (for example, during cleaning operations using brooms). If a dust explosive cloud comes into contact with a source of ignition of just few millijoules, an initial ignition will be produced. This would be the primary explosion, generally with subsonic speed (also known as “deflagration”), which generates a considerable volume of hot gases that in turn generates a pressure wave. After this, dust that has settled nearby easily becomes suspended, forming a new dust cloud in front of the first flash. The initial flame now becomes a new source of ignition for the newly formed cloud (flammable mixture). The process thus repeats itself, over and over, quickly producing a sequence of new secondary explosions, with increased energies that potentially cause the destruction of the entire plant. 3. Statistic data The Health and Safety Executive in UK, stated that on average there are 70 to 100 incidents each year in the UK that involve explosive atmospheres. Companies affected by potential dust explosions include manufacturers of sugar, coal, cocoa, flour-based products, milk powder, tea, grain, fodder and tobacco, as well as wood and metal processing companies. When it comes to sourcing electrical equipment for areas where there is a risk of dust explosions, many companies in these sectors are not fully aware of the recommendations of latest relevant standards. A combustible dust hazard study conducted by the U.S. Chemical Safety and Hazard Investigation Board (CSB) found that nearly 280 dust fires and explosions have occurred in U.S. industrial facilities over the past 25 years, resulting in 119 fatalities and over 700 injuries. In the late 1970s a series of devastating grain dust explosions in grain elevators in USA left 59 people dead and 49 injured. 4. Characteristics of dust explosions To produce a dust explosion, the following conditions must happen simultaneously: Combustible dust in suspension; Dust concentration in suspension must be above its lower explosive limit (LEL); Dust must have particles of adequate size; Air (oxygen) present; Source of ignition with adequate power. Combustible dust-air mixtures have different ignition temperatures. The surface temperature of the equipment in areas with a risk of dust explosion may reach 2/3 of the minimum ignition temperature of the surrounding dust-air mixture at the maximum and with a 5 mm thick layer of dust must be at least 75 K below the minimum ignition temperature of the dust (glow temperature). It is therefore the owner‘s job to ensure that the cleaning and maintenance intervals of installations with a dust explosion risk are scheduled so that no dust layers thicker than 5 mm are allowed to form. At higher dust deposits the minimum ignition temperature (glow temperature) of the dusts are reduced drastically. Examples for the ignition and glow temperatures can be taken from Table 1. In general, it can be said that it is more difficult to initiate a dust explosion than it is to initiate an explosion of flammable gas or vapor atmosphere, because the necessary energy to ignite dust is higher (magnitude of mJ) than that which is necessary to ignite gases (magnitude of µJ). Electrical equipment to be installed at these areas need to comply with relevant standards. These special electrical equipment are called as “Ex equipment”. Considering that an electrical installation poorly maintained can act as a source of ignition in hazardous atmospheres, an inspection plan is highly recommended as a tool to monitor the integrity of the installation, keeping the safety of goods and people. Table 1 – Ignition temperatures of some dusts Dust type (name of the solid) Minimum ignition temperature of a dust layer (glow temperature) in acc. with IEC 61241-2-1 method A o Cellulose Cotton Grain Sawdust C 370 350 290 300 Minimum ignition temperature of a dust cloud in acc. with IEC 61241-2-1 method B o C 500 560 420 400 5. Preventive measures The following measures are recommended to avoid explosions: Use appropriate electrical equipment and wiring methods; Identify and control static electricity risks; Control smoking, open flames, and sparks; Control mechanical sparks and friction; Use separator devices to remove foreign materials capable of igniting combustibles from process materials; Separate heated surfaces from dusts; An inspection plan is very important to know if the safety in your plant is affected. The following steps are necessary to perform an inspection of the electrical installation in a hazardous location: Keep the area classification documentation updated; Form an inspection team with skilled persons; Get the installed Ex equipment data; List all equipment in inadequate condition; Let’s explain each item in a more detailed way: 1) Area classification documentation An area classification study is required to be developed using the IEC 60079-10-2 standard as basis. Considering its relevancy, all data taken into consideration to define the extent of the classified areas have to be recorded and kept available to the plant employees. 2) The inspection team Adequate training of personnel in topics related to hazardous areas is needed to keep industrial plants safe and to guarantee the integrity of Ex equipment. Many non-conformities' causes are attributed to the low qualification of maintenance professionals. It is worth to say that good workmanship is the result of competent people working within good systems of work. If no trained personnel are available in the facility, it will be necessary to hire a specialized company to perform the inspection. 3) Getting equipment data It is necessary to know the inventory of the electrical Ex equipment installed, including their types, gas groups, T class and categories. The conformity certificates of each electrical and electronic equipment shall be kept available to the maintenance personnel. 4) Listing all defective items All equipment found with non-conformities under the relevant standards, need to be identified and the necessary repairs shall be carried out without delay. It is important to note that if the integrity of the Ex equipment is affected, the safety of the plant is at risk. The repair work on Ex equipment should only be carried out by the manufacturer or authorized repair shops. Maintenance resources shall be directed at eliminating these failures that affect the safety of the plant. When maintaining Ex equipment, is absolutely necessary that the certified components´ characteristics are kept. To keep the conformity certificate valid after a maintenance service, only original spare parts recommended by the manufacturer can be used. The maintenance service quality is one of the factors affecting safety and operational costs. 6. Conclusions Despite their deceptive “harmless appearance”, combustible dusts have a huge destructive power. Design, installation and maintenance on electrical installations at locations where explosive atmospheres can occur, need to be performed strictly under the technical and legal requirements, by skilled personnel. Workers are the "first line of defense" in preventing and mitigating fires and explosions. If the people closest to the source of the hazard are trained to recognize and prevent hazards associated with combustible dust in the plant, they can recognize unsafe conditions in a quick way, and take the appropriate measures. A regular inspection program applied to electrical installations is an important tool to prevent undesirable sources of ignitions that can lead to dust explosions. 7. References 1. Murdoch, Peter - Inspections of installations in hazardous areas adds value to safety and maintenance strategies. In: II Hazardex, Coventry, UK, 2003. 2. Rangel Jr., Estellito, Nägle, Rainer - Dust explosion protection in Brazil. Ex Magazine, Waldenburg, Germany. R. Stahl Schaltgeräte GmbH, August 2006. 3. NFPA 654: Standard for the Prevention of Fire and Dust Explosions from the Manufacturing, Processing, and Handling of Combustible Particulate Solids. NFPA, Quincy, MA, USA. 4. Rangel Jr., Estellito - The importance of inspections in classified areas, Vector Magazine, Johannesburg, South Africa. EE Publishers, October 2005. 5. Eckoff, R.K. - Dust explosions in the process industries. Butterworth Heinemann, 1997. 6. Rangel Jr., Estellito - Handling changes from Divisions to Zones, IEEE IAS Applications Magazine, Piscataway, USA. IEEE, May 2004. 7. Schoeff, R.W. - Case study of dust explosion at DeBruce Grain Co. terminal elevator. In: III Worldwide Seminar on the Explosion Phenomenon and on the Application of Explosion Protection Techniques in Practice. Ghent, Belgium, 1999. 8. IEC 61241-17 - Electrical apparatus for use in the presence of combustible dust Part 17: Inspection and maintenance of electrical installations in hazardous areas (other than mines). IEC, Geneva, Switzerland. 9. Rangel Jr., Estellito - Electrical installations in explosive atmospheres: Inspection and maintenance are basic activities for safety. In: I IEEE ESW Brazil - International Seminar of Electrical Safety in the Workplace. Guararema, Brazil, 2003.