Honors Physical Science S2 Review Name: ____________________ Pd: ____ Date: __________ Conservation of Mass 1.) A student decides to dissolve granulated sugar in water to see if the mass changes. a.) When sugar dissolves in water, do you predict a change in mass? Explain why or why not. No, because mass never is created or destroyed—Law of Conservation of Mass b.) When the sugar dissolves and “disappears”, is the sugar still there? List at least two possible ways to prove whether or not the sugar is still in the water. Yes. You can boil away the water and be left with sugar. You could also taste the water. c.) The student adds 4.0 grams of sugar to 18.0 grams of water. Make a prediction of the combined mass of the two substances. Explain the reasoning behind your prediction. 22.0 grams; because mass never is created or destroyed—Law of Conservation of Mass d.) Predict: The volume of dissolved sugar is ( more / less ) than solid sugar. Explain your prediction. Less; because the air spaces in between each sugar crystal are now taken up by water so the volume of the sugar appears to decrease. e.) The volume of the sugar was 5.0 mL and the volume of the water 18.0 mL. Between what two numbers can we be absolutely certain the combined volume of the two substances will be? Explain why you chose these two numbers. 18.0 ml – 23.0 ml. The combined volume of the sugar and the water cannot be less than the water alone nor more than the total combined of the sugar and water. f.) The student does the lab and obtains the following results. mass before mixing: 22.00 grams Calculate: ∆m = -0.02 grams mass after mixing: 21.98 grams g.) From the above data and calculations, the student draws the conclusion that when sugar dissolves, mass must change because there was a measured change. Think of two reasons why this is not a valid conclusion to make. Reason #1: Loss of sugar crystals or water when mixed. Reason #2: Error within the balance itself. 2.) Provide an explanation in your own words of what it means to say that “Mass is Conserved”. 3.) Is mass ever created or destroyed when a substance: a.) dissolves? b.) melts? NO c.) precipitates? NO d.) produces a gas? NO NO 4.) What is a closed system? When trying to find the change in mass during various processes, why is it important to do so in a closed system? When the system is not open to the environment. So that no mass is lost to the environment. Characteristic Properties 5.) Ethanol has a density of 0.789 g cm 3 6.) All pure gold has a density of 19.4 . What is the mass of 225 cm3 of ethanol? 225 x 0.789 = 177.525 grams. g 1 cm 3 . A particular cube of gold measures 4.23 cm on each edge. What is the volume of the cube? What is its mass? V = 4.23 x 4.23 x 4.23 = 75.69 cm3 Mass = 75.69 x 19.4 = 1468.33 g 7.) While in the lab your group collects 180cm3 of CO2 from the combination of water and Alka-Seltzer. You calculate the mass difference before and after the test to be 0.36 grams. What is the density of the CO2 gas? How much space would 10 grams of the CO2 gas fill? D = 0.36 g/180 cm3 = 0.002 g/cm3 0.002 g/1 cm3 = 10 g/ ??? cross-multiply and divide = 5000 cm3 D. Parent 2009 1 687320421 8.) A substance was placed in an oven at 125 ˚C. According to the graph at right that shows the relationship between time and temperature for the heating of a single substance, at what temperature does the substance: a.) freeze and melt? -5 Sample Temp. vs Time 125 105 85 Temperature (ÞC) b.) boil and condense? 106 c.) At what temperature is the substance both a solid and a liquid? -5 d.) At what temperature is the substance both a liquid and a gas? 106 e.) Between what temperatures is the substance completely a: i.) solid? ii.) liquid? iii.) gas? -15 to -5 -5 to 106 106 to 125 65 45 25 5 -15 0 5 10 15 20 Time (30 sec intervals) 9.) In Lab 3.11, you found the density of the gas produced when Alka-Seltzer reacts with water. How would your measured density be different if you had used: a.) twice as much Alka-Seltzer? Why? It would be the same because density is a characteristic property and does not change. b.) half as much Alka-Seltzer? Why? It would be the same because density is a characteristic property and does not change 10.) What could be a typical density for a: a.) solid? Around 2.0 11.) The density of liquid A is b.) liquid? About 1.0 c.) gas? Much less than 1.0 2.0 g 1.5 g and the density of liquid B is . If you had 100 cm3 of liquid A, how 3 3 1 cm 1 cm many cm3 of liquid B would you need in order to have an equivalent amount of mass? 133.33 cm3 Solubility 12.) What is concentration? What is a saturated solution? What is solubility? Concentration is the measurement of the amount of solid dissolved in a specific amount of liquid at a specific temperature. A saturated solution is where no more solid will dissolve in a liquid at a specific temperature. Solubility is the range of amount of solid that will dissolve in a certain amount of liquid over a range of temperatures. 13.) A student adds 8.0 g of a solid and 15.0 g of water to a test tube and shakes the tube for 5 minutes. Not all of the solid dissolves. The student then pours the resulting solution (only the liquid) into a massed evaporating dish. The combined mass of the evaporating dish and the solution now in the dish is measured. After the water has been evaporated away, the mass of the dish and the remaining solid is found. a.) Was the solution that was poured into the evaporating dish saturated? How do you know? b.) Using this data: Mass of evaporating dish: Mass of dish and solution: Mass of dish and remaining solid: 23.98 g 29.72 g 25.22 g i.) What was the mass of the remaining solid (the solid dissolved in the solution, the solute)? 25.22-23.98=1.24g ii.) What was the mass of the water (the solvent)? 29.72 – 25.22 = 4.50g iii.) What is the density of water? 1.0 g/cm3 iv.) What was the volume of the water (the solvent)? 4.50 cm3 (same as mass) v.) What was the concentration of the solution in g / 1 cm3? .28 D. Parent 2009 2 …in g / 100cm3? 28 687320421 14.) How does temperature affect the solubility of a gas in a liquid? Compare this to how temperature affects the solubility of a solid in a liquid. Increased temperature causes gas to be less soluble in liquid. Increased temperature causes a solid to be more soluble in a liquid. 15.) Using the graph on p.71 of your text, what is the maximum amount of potassium nitrate that could dissolve in: a.) 100 cm3 of water at 65ºC? b.) 200 cm3 of water at 65ºC? c.) 200 cm3 at 85ºC? 130g 260g ~364g 16.) Using the graph on p.71 of your text, suppose you place 150 g of potassium nitrate and 100 g of sodium nitrate in a beaker that contains 100 cm3 of water. Assume they have no affect on how each other dissolve. What is the lowest temperature at which all the potassium nitrate and sodium nitrate will dissolve? 74ºC Atomic Structure 17.) Complete the following table. Element Protons Neutrons Electrons Nitrogen 7 7 7 Atomic Weight 14 Sodium 11 21 11 23 Neon 10 10 10 20 18.) Fro each atom, draw the electrons for each shell and fill in the missing data. Atomic Number: Li C O _3_ _ _6_ _ _8_ _ Total e-: 19.) a.) For each element in the below table, fill in the cation that the atom forms. b.) Provide one example of a monatomic ion (e.g.: F1-, Cl1-, O2-, N3-, etc.) with which the cation could react in order to form an ionic compound. Name the compound. . Element Cation Sodium Na1+ _3_ _8_ _6_ _ _ _ Valence e-: _1_ _6_ _4_ _ _ _ Electron 2 1 2 2 4 2 2 2 Config.: _1s 2s __ _1s 2s 2p _ __1s 2s 2p _ _____ ______ _____ Ionic charge: _+1__ F1- Ionic Compounds (Formula) NaF CO32- Na2CO3 Anions _+/-4__ _-2__ Magnesium Potassium Copper (I) (cuprous) we will do this in Silver Class. Zinc D. Parent 2009 3 687320421 20.) Complete the following table. Compound Name Formula Molar Mass Mass Moles Molarity .336/.05L Calcium chloride CaCl2 110.98g/mol 37.3g .336 mol Copper (II) nitrate Cu(NO2)2 155.556g/mol 1240 g 7.971 mol 6.72 M 7.971/.900 8.86 M 250 ml Copper (II) acetate Cu(C2H3O2)2 181.633g/mol 18.16g 0.100 mol 0.40 M Compound Synthesis and Decomposition 21. What is a compound? Also, explain how it differs from an element. A compound results when two, or more, elements combine together (bond), forming a new pure substance. 22. What is a pure substance? Also, explain how it differs from a mixture. All the particles of a pure substance have identical characteristic properties whereas particles in mixt. differ. 23.) What is the Law of Constant Proportions? It states that when compounds are either synthesized or decomposed, they always do so in specific ratios. 24.) If a student collected 30 cm3 of hydrogen during the decomposition of water: a.) How many cm3 of oxygen would be collected? 15 b.) Does the volume of the water equal the volume of the two gases? Why/why not? No- diff densities. c.) If the H were recombined with the O, would there be more mass, same amount of mass or less mass than the mass of the original H2O would result? Explain your answer. Same! Conservation of mass. 25.) What are three ways that radioactive elements are the same as ordinary elements? i.) compounds form with constant proportions ii.) characteristic densities, melting & boiling points, etc. iii.) cannot be decomposed by heating, electricity, or by reacting with acid 26.) How is the decomposition of a compound different than radioactive decay? Provide two examples. Compound decomp., the elements stay the same and don’t emit particles. NaClO 3NaCl+O2 & H2OH2+O2 27.) What is an α-decay? What is a β-decay? What causes a γ-ray to be emitted? α-decay: 2 protons&2 neutrons (α-particle) emitted; β-decay: proton becomes neutron and emits electron (β-particle); γ-ray emitted b/c high energy nucleus “drops” to lower energy level, high energy photon emitted 28.) What is half-life? What does it tell you? Is it a characteristic property? Explain. The time it takes ½ the sample to decay and it is a char. prop., each radioactive element takes a different amount of time to decay. Bonding 25. Why do atoms combine to form molecules? To complete their valence shells by either sharing or transferring electrons 26. What is a chemical bond? The attraction between atoms resulting from electron interactions. D. Parent 2009 4 687320421 27. What’s the difference between a covalent bond and an ionic bond? Covalent- Sharing electrons Ionic- complete transfer of electrons. 28. Why does one oxygen atom combine with two hydrogen atoms to form water? Oxygen needs 2 more electrons to complete valence shell. 2 hydrogen atoms each have one to share. 29. 30. 31. What are typical traits of ionic compounds? What are ionic compounds often called? High melting points, crystalline structure, etc. “Salts” Explain electronegativity and why it determines if a bond is nonpolar covalent, polar covalent, or ionic. Electronegativity is the relative affinity an element’s atom has for electrons. If difference is less than .4 = nonpolar covalent ; between .4 & 1.7 = polar covalent ; over 1.7 = ionic Complete the following table. Molecule O2 H2 O BeCl2 NH3 KF N2 CO2 C4H10 Ionic or Covalent? Covalent Covalent Ionic Covalent Ionic Covalent Covalent Covalent Total Valence Electrons 12 8 16 8 8 10 16 24 Lewis dot structure See Your Teacher When You Get To Class Acids & Bases 32. What makes an acid, an acid? What makes a base, a base? Acids add extra Hydrogen Ions to water solution, bases add extra hydroxides. 33. While doing a lab, you are able to determine that there is 10-5 moles of H+ in one liter of the solution. What is the pH of this solution? Would you consider this solution an acid or a base? Why? 5 Acid- pH is less than 7 34. While doing another lab, you measure the pH of solution A to be 3. You measure the pH of solution B to be 6. How many times more acidic is solution A from solution B? 1000x D. Parent 2009 5 687320421