ATOMIC & MOLECULAR STRUCTURE PHYSICS 471/550 W/'01 INSTRUCTOR: Jacob J. Leventhal Department of Physics University of MO - St. Louis St. Louis, MO 63121 Office: (314) 516-5934 Fax: (314) 516-6152 E-mail: jake@umsl.edu Homepage: http://newton.umsl.edu/~jake/P471/ COURSE DESCRIPTION: Prerequisite: Quantum mechanics. Applications of quantum mechanics to the structure of atoms and molecules; perturbation and variational calculations, self-consistent fields, multiplets, angular momenta, Thomas-Fermi model, diatomic molecules, spectral intensities. PROBLEM SETS: There are problem sets on the course web page. Your solutions will not be collected, but you should have solved or know how to solve each assigned problem prior to the exams. You are encouraged to work on these problems in groups. EXAMS: There will be two exams through the course of the semester. Because the four universities have different calanders the exam dates will be set during the semester. These exam dates will be announced well in advance. Each exam will cover roughly half of the course material. There will be no comprehensive exam. TEXT: There is no formal textbook for this course although the "notes" can be downloaded from the course web page. Also, much of the material is in standard quantum mechanics texts, although more specialized books should also be consulted. Therefore, in addition to the class notes, you should consider the texts that you used for all quantum mechanics courses as texts for this course too. A few books that might be useful are listed below. There are many others. Some standard QM texts Park: Introduction to Quantum Theory Sakurai: Modern Quantum Mechanics Saxon: Elementary Quantum Mechanics Schiff: Quantum Mechanics A few specialty books Atkins: Molecular Quantum Mechanics Bransden & Joachain: Physics of Atoms and Molecules 1 Morrison, Estle & Lane: Quantum States of Atoms, Molecules & Solids Weissbluth: Atoms & Molecules REFERENCES: Some of these references below can be downloaded from: http://newton.umsl.edu/~atomic/ R. R. Freeman and D. Kleppner, "Core Polarization and Quantum Defects in HighAngular Momentum States of Alkali Atoms", Phys. Rev. A 14, 1614-1619 (1976). T. P. Hezel, C. E. Burkhardt, M. Ciocca and J. J. Leventhal, "Classical View of the Stark Effect in Hydrogen Atoms", Am. J. Phys. 60, 324 (1992). T. P. Hezel, C. E. Burkhardt, M. Ciocca, L-W He and J. J. Leventhal, "Classical View of the Properties of Rydberg Atoms: Application of the Correspondence Principle", Am. J. Phys. 60, 329 (1992). J. F. Baugh, M. Ciocca, D. A. Edmonds, P. T. Nellesen, C. E. Burkhardt and J. J. Leventhal, "Polarizability of a Hydrogenic State", Phys. Rev. A 54, R4645-R4648 (1996). J. F. Baugh, D. A. Edmonds, P. T. Nellesen, C. E. Burkhardt and J. J. Leventhal, "Atomic Polarizabilities: Quantal and Classical Perspectives" Am. J. Phys. 65, 602-605 (1997). J. F. Baugh, W. P. Garver, C. E. Burkhardt and J. J. Leventhal, "Population of Stark wave-packet states by cw laser excitation", Phys. Rev. A 58, R785-R788 (1998). J. F. Baugh, D. A. Edmonds, P. T. Nellesen, C. E. Burkhardt and J. J. Leventhal, "Coherent States Composed of Stark Eigenfunctions of the Hydrogen Atom", Am. J. Phys. 65, 1097-1102 (1997). 2