H CH 1 HOMEWORK: Misc: 1. Identify the SI unit and prefix that would be most appropriate for measuring the following: a) the length of a pencil. mm, cm, m b) The width of the classroom m c) The diameter of the graphite in a pencil mm d) The distance from here to Meyersdale km e) The mass of a person kg f) The mass of a grape g g) The volume of a glass of water mL, cL, L h) The volume of a dump truck load of sand. m3 2. Determine the number of significant digits in each of the following: a) b) c) d) e) f) g) 65.42 4 385 3 .014 2 709.2 4 5006.12 6 400 1 260. 3 h) 0.47 i) 0.0068 j) 7.0 k) 36.00 l) .0070 m) 100.6040 n) 340.00 2 2 2 4 2 7 5 3. Round off the following measurements to the indicated amount of significant digits: a) b) c) d) e) 2.68 to 2 sig figs 457.26 to 3 sig figs .00254 to 1 sig fig 27 to 1 sig figs .112504 to 5 sig figs 2.7 457 .003 30 .11250 SCIENTIFIC NOTATION Write the following numbers in scientific notation. Round to 2 numbers after the decimal. 1. 100 1.0 x 102 6. .024 2.4 x 10-2 2. 10500 1.05 x 104 7. .00000458 4.58 x 10-6 3. –800 -8.00 x 102 8. -.6 -6 x 10-1 4. 6 6 x 100 9. -.00054 –5.4 x 10-4 5. –216000 -2.16 x 105 10. .00110 1.10 x 10-3 Rewrite the following in expanded notation. 11. 4.2 x 102 420 16. 4.82 x 10-1 .482 12. –8.43 x 106 -8 430 000 21. 14.86 1.49 x 101 24. 1486.2 x 106 1.49 x 109 22. 128.4 1.28 x 102 25. 1486.2 x 10-6 1.49 x 10-3 23. 13.0 1.3 x 101 17. –9.02 x 10-6 -.000 009 02 13. 4.8 x 103 4800 18. 5.77 x 10-4 .000 577 14. –1.97 x 1012 -1 970 000 000 000 19. 8.4 x 10-10 .000 000 000 84 15. 7.14 x 105 714 000 20. 3.00 x 10 –2 .03 Write the following numbers in scientific notation. Round to 2 numbers after the decimal. List of numbers (comparison)…planets PERFORM THE FOLLOWING CALCULATIONS USING SIG FIGS. 1. 112.34 + 23.3 = 135.6 2. 1320 – 212 = 1110 3. 14.55423 + 112.232 + 1.01 = 127.80 4. 10000 – 8 = 10000 5. 110. + .0987 = 110. 6. 23.1 x 1.8 = 42 7. 112.0 x 10 = 1000 8. 1129.10 / 2.000 = 564.6 9. 100 x 23 = 2000 10. 76.54 x 1.82 x 12.552427 = 1750 11. (34.98 + 2.3) / 2.86 = 13.0 12. 9.10 x 2.7762 + 1.23 = 26.5 13. (6.78 + 2.4333 – 3.7) = 2.0 2.8 14. (.0098 + 1.009) x (2.978 + .00725) = 3.042 15. 1/3 = .3 600./3.0 = DENSITY Show all work and round to the correct number of sig figs. Consider the following list of elements: Barium Copper Germanium Platinum Gold Aluminum Sulfur Calcium Nickel Magnesium 1. List the elements in order of increasing density.Ca, Mg, S, Al, Ba, Ge, Ni, Cu, Au, Pt 2. Which of the above elements would float in Bromine? Ca, Mg, S, Al 3. How many cm3 is 6.2 x 103 g of lithium? 12000 cm3 4. How many cm3 is 841 g of silver? 80.1 cm3 5. What mass of Uranium is 95 cm3 of Uranium? 1800 g 6. How many grams would be in 1280 cm3 of Mercury? 17300 g 7. A student determines the volume of a sample of iron to be 11.0 cm3. Its mass is 93.21 g. a. Calculate the experimental density of Iron. 8.47 g/cm3 b. Calculate the experimental error. (No sig figs) .6 g/cm3 c. Calculate the percent error. (No sig figs) 7.62 % 8. A glass of wine is mainly water and ethanol (about 10% by volume). If a cup of wine is poured, what is the mass of the wine? The density of ethanol is .79 g/mL 231.53g review….. 9. What are the dimensions of a cube holding 250g of water? No sig figs 6.3 cm 10. If the specific gravity of carbon tetrachloride is 1.6, what is the mass of 25 ml of carbon tetrachloride? No sig figs 40 g WATER VAPOR PRESSURE: TEMP (C) PRESSURE (mmHg) 0.0 5.0 10.0 12.5 15.0 17.0 20.0 Find the slope What is the pressure at 8 C? What is the pressure at 25 C? 4.6 6.5 9.2 10.9 12.8 14.7 17.5 .64 mmHg/C 8.73 mmHg 19.62 mmHg DENSITY OF WATER: TEMP (C) DENSITY (g/ml) 4 6 8 10 20 30 40 .99997 .99994 .99985 .99970 .99820 .99565 .99222 Find the slope -.0002 g/mL/C Find the density at 25 C .99621 g/mL What information does the slope provide? How are the variables related? Inversely DIMENSIONAL ANALYSIS: English – English: 1. How many ounces are in 2 pounds? 32 oz 2. Change 13 inches to feet. 1.08 ft 3. 32 inches would be how many yards? .89 yds 4. If there are 2 pints in a quart and 4 quarts in a gallon, how many pints are in 2.2 gallons? 17.6 pints Metric – Metric: 5. How many meters are in 1500 mm? 6. Change 740 cL to hL. 1.5 m .074 hL 7. 1.4 x 104 g would be how many Mg? .014 Mg 8. 1100 nm would be how many pm? 1.1 x 106 pm Metric – English/English – Metric: 9. A 3 mile walk is how many km? 4.83 km 10. 254 mm is how many inches? 10 in 11. 10 gallons would be how many L? 37.84 L 12. 635 pounds would be how many kg? 288.29 kg Dimensional Analysis II: 1. An average car has a fuel efficiency of about 25 miles/gal. If we are selling the car in Europe, what would be the efficiency in km/L? 10.6 km/L 2. 87 cm2 would be how many in2? 13.49 in2 3. A typical home faucet has a volumetric flow rate of about 3.2 gal/min. What would that rate be in L/s? Watch sig figs. .20 L/s 4. A 1 gallon container is how many ft3? .13 ft3 5. 470 cL would be how many quarts? Watch sig figs. 5.0 qts 6. A typical mass flow rate for production of polystyrene from a single plant is about 2.12 tons/day. How many Mg is that in a year? 702.6 Mg/yr 7. If you need 27 square yards of carpeting for a room that is square, what would be the dimensions of the room in meters? 4.75 m 8. 6101 in3 would be how many m3? Watch sig figs. .100 m3 9. A large river flows at 2.6 x 105 gal/s into a loch that is 75 m x 30 m x 18 m. How long will it take to fill the loch? 41.16 s 10. A city uses 7 million gallons of water in a day. How many tons of water is that in a year? 1.06 x 107 tons/yr go back and do #8 from Density HW HEAT AND TEMPERATURE: 1. Perform the following conversions: 12.4C = 54.3 F 76.4F = 24.7 C 246 K = -27 C 220F = 377.5 K 2500 J = 6.0 x 102 cal (SF) 56 kcal = 234 kJ 2. A heating coil is placed into 300 g of water at 25C. After 3 minutes the temperature of the water is 50.C. The specific heat of water is 4.184 J/g • C. How much heat did the water absorb? 31380 j 3. 2 oz of gold are to be melted down for use in making jewelry. How much heat would be required to heat this gold from 30 C to its melting point of 1064 C? 7569.7 j 4. It takes 75000 J of energy to change 500.00 g of an unknown substance from 25.0C to 90.0C. What is the specific heat of the substance? (SF) 2.3 j/g C 5. A mass of 1200 g of water has a temperature of 22.0C. What will the new temperature of the water be if 10000 J of energy is absorbed by the water? (SF) 24 C 6. What mass of copper can be increased in temperature by 80 C with 3000 cal of energy? 407.53 g 7. If a piece of aluminum with a mass of 3.90 g and a temperature of 99.3 C is dropped into 10 cm3 of water at 22.6 C, what will the final temperature of the system be? 28.54 C 8. If a piece of cadmium with a mass of 65.6 g and a temperature of 100.0 C is dropped into 25.0 cm3 of water at 23.0 C, what will be the final temperature of the system? 32.8 C 9. A piece of unknown metal with a mass of 23.8 g is heated to 100.0 C and dropped into 50 ml of water at 24.0 C. The final temperature of the system is 32.5 C. What is the specific heat of the metal? 1.106 j/g C 10. A typical hot water heater can hold 40 gallons of water. a) If the height of the heater can be no more than 2 m, then what would be the smallest possible diameter of the heater? (assume it is cylindrical) .31 m b) If the mass of the empty heater is 110 kg, what would the mass of the full heater be? 261.36 kg c) If the incoming water has an initial temperature of 60 F, how much heat would be required to heat the full tank of water to 115 F? 1.93 x 107 j CH 1 Review: 1. What would the SI unit for area be? List several possible units for volume. m2 L, mL, cm3 2. What is the relationship between cm3 and ml? Same value, equivalent 3. What is meant by the density of a material? The ratio of mass to volume 4. What is the rule governing the number of sig figs in calculations involving addition and subtraction? Multiplication and division? Column rule Least amount rule 5. What is meant by an exact conversion factor? Give two examples. 2 values that are defined as being equivalent. Eg; 1 ft = 12 in, 100 cL = 1 L 6. How many sig figs are in each of the following: 34.110 5 .0098 2 1009 4 1200 2 7. Convert the following: a) 12 C to F 53.6 F b) 123 F to K 323.6 K 8. a) 25 cal would be how many j? 104.6 j b) 6.5 kj would be how many cal? 1553 cal 9. Determine the specific heat of a substance if a 25 g sample absorbed 34 j as it was heated from 21 C to 33 C. .113 j/g C 10. Convert the following: a) 24.89 kg to pg 2.49 x 1016 pg b) 223 ml to gal .059 gal 11. A piece of copper is 12 cm long by 8.5 cm wide and .5 cm thick. What is the mass of the copper? 457 g 12. Perform the following calculations using the rules for significant figures: a) 4.07 + 1.863 5.93 b) 3127.55 – 784.2 2343.4 c) 9.40 x 2.6 24 d) 1.50/2 .8 13. Identify the following as endothermic or exothermic: a) melting ice endothermic b) burning charcoal exothermic c) photosynthesis endothermic d) water evaporating endothermic 14. B 15. Why is it important to make temperature change come out as a positive value when performing specific heat problems? No such thing as negative energy or negative mass 16. Aluminum has a specific heat more than twice that of copper. Identical masses of aluminum and copper, both at 0C, are dropped simultaneously into the same can of hot water. When the system has come to thermal equilibrium: A) the aluminum is at higher temperature than the copper B) the copper is at higher temperature than the aluminum C) the aluminum and copper are at the same temperature C 17. E A 18. Choose 1 of the 6 following scenarios.