Sedimentary Geology Geos 240 – Chapter 8 Depositional Environments Part 5 Shallow Carbonates & Evaporites Dr. Tark Hamilton Readings from Sediments & Basins: (8:1-67) Camosun College Bahamas Platform & Fringing Reefs . La Habana Transgression & Optimal Carbonate Factory Continental Shelf Eastern Nicaragua Florida Keys: Shallow Back Reef – Lagoon – Mangrove Swamps 20 km The Great Barrier Reef: Cretaceous through Recent! Queensland OZ Lateral Progradation Bahamas Bank Reflection Seismic Section & Interpretation Cross Section of Redwater Reef, Dev. NW of Edmonton flexed later Devonian Reef, Gyrfalcon Bluff, Banks Is Devonian Crinoid Reef, Princess Royal Is Fossiliferous Producing Dev Kee Scarp Reef Norman Wells Devonian Coral Reef, Norman Wells NWT Dev. Reef: Dolomite/Stromotoporoid Norman Wells Ordovician Bioherm, Niagara Falls Devonian Reef: Dolomitized Stromotoporoid Cairns Formation, Grassi Lakes Reef, Canmore Devonian Reef: Dolomitized Stromotoporoid Cairns Formation, Grassi Lakes Reef, Canmore Devonian Reef: Dolomitized Stromotoporoid Cairns Formation, Grassi Lakes Reef, Canmore Proterozoic Stromatolites, Dismal Lakes NWT Silurian Stromatolites, Somerset Island NWT Supertenuous Drape Tidal Scour Algal Mound Buildup Sabkha Depositional Model, Persian Gulf Arid Tidal Coast Ancient Tidal Limestone Facies Mississippian Lisburne Limestone Tidal Crossbeds Diagenetic Chert Ordovician Intraclast Dolomite Breccia, Somerset Is. NWT Silurian Ripples & Flasers Dolomites, Somerset Is. NWT The New Conservative Ordovician Burrow Mottled Limestone Ottawa Ordovician Tyndall Stone, Burrow Mottled Dolomite, Red River Fm Manitoba Ripups & Scours Silurian Dolomites, Somerset Is. NWT Transgressive Phase Rising System Tract Seds can come from Out of plane Regressive Phase Falling System Tract C-Ord. Cow Head Turbidites, NF C-Ord. Cow Head Debris Flow, NF C-Ord. Cow Head Deformed Clast Exhumed Carboniferous Facies Transition Sverdrup Basin, Ellesmere Island Sverdrup Basin Rim Bioclastic Debrites Anhydrite, Shale, Detrital Carbonates Evaporites & Evaporite Basins Geographically Enclosed Water Bodies Tropics +/- 30° Latitude, descending dry air Sabkhas, Playas, Salinas, Salt Lakes Incipient Rift Basins – Triassic Margins of Atlantic Restricted Back Reef Basins: Carb’s + Anhydrite Evaporated Cratonic/Epicontinental Seas: Devonian of Alberta, Sask., Michigan & Zechstein Perm/Penn of North Sea Basin Often alternate climatically with humid clastics Usiglio’s Experiment: Evaporation of Sea Water & Sequence of Salts s.g. = 1.035 Calcite Anhydrite Halite Bitterns Development of Evaporite Basin Development of Evaporite Basin Evaporite Minerals Dominant Evaporite Minerals include: Carbonates, Chlorides, Sulphates, Borates & Nitrates Marine systems dominantly produce Carbonates, Chlorides & Sulphates Arid Terrestrial Systems produce unusual diagenetic minerals in pore spaces and beds of Borates & Nitrates additional to the Carbonates, Chlorides & Sulphates. Additional to the unusual Continental anion Chemistry, salts of metals form some unusual brine minerals, Cu, Ni, Zn, Pb, Ag and even (NH4)+ ! Salts precipitate in inverse order depending on their solubility. (solubility in strong/odd brines is empirical) Salts in vadose zone porosity are important in soils Textures in Resedimented Evaporites, Italy Messinian (~5Ma) Mediterranean Basin Evaporite Minerals Carbonates: Mineral Formula Calcite CaCO3 Dolomite CaMg (CO3 )2 Siderite FeCO3 Natrite Na2CO3 & Natron•6(H2O) Trona Na3(CO3)(HCO3)•2(H2O) (Green River, WY; Lake Magadi, Kenya) Carbonate Minerals Trona Natrite Sandstone with Cubic Halite Casts Jurassic, Utah Evaporite Minerals Chlorides: Mineral Halite Sylvite Carnallite Formula NaCl KCl KMgCl3 · 6H2O Chloride Minerals Sylvite Halite Hopper Crystals Carnallite Halite Cyclic & Crossbedded Devonian Halite, Goderich ON In what kind of Basin would “Cyclic Halite” beds form? In what sort of flow regime would Halite X-beds form? Evaporite Minerals Sulphates: Mineral Formula Anhydrite CaSO4 CaSO4· 2H2O K2Mg2(SO4)3 K2Ca2Mg(SO4)4 · 2H2O MgSO4· H2O KMg(SO4)Cl · 3H2O Gypsum Langbeinite Polyhalite Kieserite Kainite Interbedded Gypsum & Calcsiltite, Silurian Somerset Island ? Solutional Collapse Interbedded Anhydrite & Shale Ellesmere Island Sulphate Minerals Polyhalite Langbeinite Kieserite Kainite Evaporite Minerals Nitrates: Mineral Formula Niter KNO3 NaNO3· 2H2O Ca(NO3)2 · 4H2O Ba(NO3)2 Cu2(NO3)(OH)3 Nitratine Nitrocalcite Nitrobarite Gerhardtite Nitrate Minerals Nitratine Niter Nitrobarite Nitrocalcite Gerhardtite Borax Mines Death Valley CA Evaporite Minerals Borates: Mineral Boracite Formula Mg3[ClB7O13 ] Borax Na2[B4O7]2 · 10H2O Colemanite Ca[B3O4(OH)3] · 3H2O HydroBoracite CaMg [B3O4(OH)3]2 · 3H2O Larderellite (NH4 )B5O6(OH)4 Tincalconite Na2[B4O7] · 5H2O Ulexite NaCa[B5O6(OH)6]· 5H2O Boracite Borate Minerals Colemanite Hydroboracite Borax Larderellite Tincalconite Ulexite Salar de Atacama, Antofagasta Chile The End: Chapter 8 Part 5!