The Chemistry of Life

Atoms and Their Interactions

Water and Diffusion

Life Substances

Atoms

Smallest particle of an element that has the characteristics of an element.

Basic unit of matter

Atomos = (greek) unable to be cut

Atomic Structure and Subatomic

Particles

Nucleus—strong forces bind protons and neutrons at center of the atom;

Protons - + charged particles

Neutrons - particles with no charge

Electrons - charged particle; 1/1840 mass of proton; constantly in motion in space surrounding nucleus; attracted to protons in nucleus

Electron Energy Levels

Electrons travel around the nucleus in certain regions known as Energy Levels .

The innermost level (small) maximum of 2 electrons.

2nd level (larger)-up to 8

3rd level-up to18 electrons.

Element

Pure substance that consists entirely of one type of atom.

Earth

•Between 88 – 94 elements occur naturally

•About two dozen found living organisms)

Trace Elements

Elements in living things in very small amounts.

(help maintaining healthy cells)

Examples: iron and magnesium

What is the most abundant element that exist in living things? (Number)

Most abundant weight

Periodic Table of Elements

Periodic-Elements in same group have similar chemical and physical properties

• Elements and symbols are organized

• Rows-period; Same number of electron shells

• Vertical-groups; Electrons in outer energy level

Element

Neutral Atoms

# of Electrons = # of protons therefore have no net charge.

Same # Electrons = same chemical properties

Mass number= Protons + Neutrons

Isotopes

Atoms of the same elements that have different numbers of neutrons.

Atomic Mass= Average of the masses of an element’s isotopes.

Example: Carbon-14 (6 +, 6 -) is an isotope of carbon,

8 neutrons instead of 6 neutrons

Carbon 13- 7 neutrons, 6 protons

Isotopes-number of electrons

 same chemical properties

•Isotopes that have unstable nuclei and break down at a constant rate over time. (radiation)

•Medical

•Smoke detectors

•Archeological dating

RADIO ISOTOPES

Radioisotopes in Medicine

• Detect and treat cance

Kill bacteria that causes food to spoil

• “Tracers” to follow movement of substances within an organism.

Compounds

• Substance formed when atoms of two or more elements are chemically combined in definite proportions.

• Example: H

2

O (2:1), NaCl (1:1)

Compound Unique

Characteristics

• Specific combination of elements in a fixed ratio.

• Chemically and physically different than elements its comprised. (eg. Water different than H and O)

• Cannot be broken down into simpler compounds or elements by physical means

Chemical Bonds

• Force that holds substances together

• Stability

• Forming and breaking bonds-provides energy for growth, development, adaptation, and reproduction

Ionic Bonds

Electrical attraction b/w 2 oppositely charged atoms or group of atoms.

Ion

An atom (or group of atoms) gains or loses electrons has an electrical charge.

An ION is a charged particle.

Molecules close together, slight attraction can form b/w oppositely charged portion of nearby molecules- the intermolecular forces

--Helps form water droplets, geckos climb using structures on toes and atoms on surface climbing.

VAN DER WAALS FORCES

-EX. HYDROGEN BONDS

Covalent Bonds

A chemical bond formed when two atoms combine by sharing electrons .

Molecule

Substances with covalent bonds and having no overall charge.

Most compounds in living things.

Example : Water, DNA

Covalent Bonds

• Single-Each atom shares one electron

• Double- Each atom shares two electrons

• Triple- Each atom shares three electrons

Chemical Reactions

process that changes, or transforms, one set of chemicals into another

Chemical bonds formed and broken

Metabolism

All chemical reactions that occur within an organism

Responsible for break down and building of molecules

How do I know chemical reaction has occurred?

Color change new substances might reflect different colors of light.

Heat change the container may get hotter or colder.

Gas produced bubbles or smoke may be observed.

Precipitate formed an insoluble solid might form in a liquid.

Reactants

Substances that undergo chemical reactions.

a substance obtained from another substance through chemical change

PRODUCTS

Energy in reactions

• Energy changes- Some reactions release energy (spontaneous, form of heat), others absorb energy (will not happen w/o energy)

• Energy Sources-sun >plants>animals

• Activation Energy- Energy needed to get reaction started.

Mixture

A material composed of 2 or more elements or compounds that are physically mixed but not chemically combined

Solution—A mixture in which all the components are equally distributed (salt water solution)

Solute—Substance being dissolved. (salt)

Solvent—Substance that does the dissolving.

(water)

Universal solvent is water!!

Suspension

Mixture containing non dissolved particles distributed within a solid, liquid or gas.

Examples: Orange Juice, Blood, Salad

Dressing.

Colloid

A thick substance formed when very fine particles (such as large molecules) that cannot be dissolved stay scattered throughout liquid, solid, or gas without sinking.

Examples: Gelatin, Toothpaste, Shaving Cream,

Smoke and Milk

Tyndall Effect

Scattering of light by colloidally dispersed particles.

Detected with the aid of a light beam.

Water

• Liquid most of Earth’s surface

Expands slightly as it changes from liquid to solid

• Covers 75% of Earth’s surface

Most abundant compound in nearly all living organisms

Water resist temperature change

Water continued….

• Polar Molecule—Due to an uneven distribution of electrons, water molecules are slightly charged on each end.

– Oxygen has a slight negative charge

– Hydrogen have a slight positive charge.

• Strong attraction between water and other molecules; the universal solvent.

Dissolve ionic compounds, as well as sugars.

Hydrogen Bonds

Weak chemical bond formed by the attraction of the hydrogen atoms to other negatively charged atoms. weak "hydrogen" bonds in water partially get their identity from stronger "covalent" bonds in the H2O molecule

Cohesion

Attraction between molecules of the same substance

Water forms beads on smooth surface

• reason insects can walk on water

Surface Tension

How difficult it is to stretch or break the surface of a liquid.

Water has a high surface tension b/c of cohesion of hydrogen bonds.

Adhesion

Attraction b/w molecules of different substances.

Eg. Water molecule in a graduated cylinder

Capillary Action

Unique property of being able to creep up thin tubes.

Water tension and capillary action allow water to move from soil to top of trees.

Heat Capacity

• Result of hydrogen bonds b/w water molecules is that it takes large amount of heat energy to cause molecules to move faster

– Large bodies of water absorb large amounts of heat w/ small changes in temperature

– Organisms in water are protected from drastic change

– Cell level-water absorbs heat produced by cell processes, regulating cell temperatures

pH-Acids and Bases

pH Scale—A measurement system that indicates the relative concentrations of hydrogen and hydroxide ions.

Acids

Compounds that release hydrogen ions (H+) into a solution.

Acids have a pH between 0-6

Bases

Compounds that release hydroxide ions (OH-) into a solution.

Bases have a pH between 8-14

Neutral

strong acid (H+) + strong base (OH-) = water and salt.

pH of 7

Buffers

Weak acids or bases that can react with strong acids or bases to prevent sharp, sudden changes in pH

Diffusion

Net movement of particles from an area of higher concentration to an area of lower concentration.

Factors that influence rate of diffusion

• Concentration of substance. The more concentrated the substance, the more rapid diffusion.

Temperature

—The higher the temperature the more rapid the molecules will move and the speedier diffusion will be.

Pressure

—As pressure increase, the more rapid molecular movement, the speedier diffusion will occur.

Result of Diffusion

Dynamic Equilibrium

—A condition in which there is a continuous movement of particles (Brownian

Motion) but no overall change in concentration.

Concentration Gradient

Differences in concentration of substances across space.

Molecules of Life

Organic (come from organisms)

• Chemical compounds that exist or derived from plants or animals, (all carbon compounds)

• No manufactured chemicals

Carbon

2 electrons 1 st energy level,

4 electrons on outer energy level

6 protons, 6 neutrons

Bonds well with other carbon atoms, as well as with other elements.

Single, double and triple bonds

Single, Double, Triple Bonds

Carbon continued…

• Straight chains, branched chains, or rings.

• Isomers—compounds that have the same simple formula but different three-dimensional structure.

Molecular Chains

Macromolecules—Large molecules

Example Proteins

(meros-part)

Polymer—large molecule formed when many smaller molecules bond together. (repeating units)

Monomer—simple compound whose molecules can join together to form polymers

Condensation Reactions alias: Dehydration synthesis

A chemical reaction by which polymers are formed.

Water is formed

Hydrolysis

•A method by which polymers can be broken apart.

•H+ and OH- from water attach to bonds between subunits that make up polymer, thus breaking the polymer.

Four Types of Organic

Compounds

Carbohydrates

Lipids

Proteins

Nucleic Acids

Carbohydrates

An organic compound composed of

C arbon, Hydrogen, and Oxygen

(CHO Family) .

2 hydrogen:1Oxygen:1Carbon

Source of energy; structural

Types of Carbohydrates

Monosaccharides

Disaccharides

Polysaccharides

Monosaccharide

Simple sugar

Example: Fructose and Glucose

Disaccharide

Two monosaccharides linked together;

A two-sugar carbohydrate.

Example:

Glucose and Fructose

Sucrose

(condensation reaction)

Polysaccharides

Largest carbohydrate molecules; polymers composed of many monosaccharide sub units.

Examples:

Starch (Food storage in plants)

G lycogen (form in which animals store food in their liver),

Cellulose (in plant cell wall, gives structural support.

Cereals

Breads

Fruits

Vegetables

SOURCES OF

CARBOHYDRATES

Lipids

• A large portion (much greater then 2 to 1) of C-H bonds and less oxygen than carbohydrates (CHO family).

• Fats and oils

• Insoluble (non-polar, no charge, therefore not attracted)

• Cells uses: Energy, storage, insulation, and protective coatings.

• Useful in food preparation.

• Subunits: Glycerol, fatty acids.

Sources: nuts, butter, vegetable oil, and cheeses

Phospholipids- contain glycerol, two fatty acids, and a phosphate group, and are important in cell structures.

Steroids- are complex ring structures, and include cholesterol, which is used to synthesize the sex hormones.

Saturated Fats/ Unsaturated Fats

Fatty acids with hydrogen at every position along the carbon chain are saturated

Fatty Acids with one or more double bonds are called unsaturated fats

Proteins

A large, complex polymer composed of carbon, hydrogen, oxygen, nitrogen and usually sulfur.

(CHO + NS)

•structure for tissues and organs

• metabolism (all of the body’s chemical reactions)

Soybeans

Milk products

Meat

Eggs

Fish

Beans

SOURCES OF PROTEINS

Amino Acids

• Basic building blocks of proteins.

• 20 common amino acids

• AA combinations can make thousands of proteins

(vary more in structure then any other organic molecule)

• Amino Acids link together when a (+H) from one amino acid and an (-OH) group from another amino acid are removed to form a water molecule.

• Covalent bond formed between the two amino acids--peptide bond.

• # amino acids and order determine protein.

Types of Proteins/ Functions

Enzymes -catalyze chemical reactions

Antibodies -Immune System

Hemoglobin -Oxygen transport in blood

Hormones -regulate metabolism

Actin and Myosin -Muscle proteins

Glycoproteins -Cell membrane

Keratin and Collagen - structural, or support proteins.

catalyst

Substances that speeds up the rate of chemical reactions

Proteins that act as biological catalyst (lower activation energy)

• Site where reactants brought together to react

• Reactants are call substrates

• The products are released

Site where substrate binds to enzyme is called active site.

Temperature, pH and regulatory molecules can affect the activity of enzymes.

Nucleic Acids

A complex macromolecule that stores cellular information in the form of a code.

Nucleotides

• Nucleic acids are polymers made of smaller subunits called nucleotides .

Nucleic Acids

Consist of carbon, hydrogen, oxygen, nitrogen, and phosphorus atoms arranged in three groups—A nitrogen base, simple sugar (ribose) and phosphate group.

Examples : DNA (deoxyribonucleic acid) and RNA (ribonucleic acid)