Naming Compounds Writing Formulas Chapter 5 Systematic Naming There are too many compounds to remember the names of them all. Compound is made of two or more elements. Put together atoms. Name should tell us how many and what type of atoms. Periodic Table More than a list of elements. Put in columns because of similar properties. Each column is called a group. 1A Representative elements The group A 2A elements The tall columns 5A 7A 3A4A 6A 0 Metals Transition metals The Group B elements Dull Brittle Nonconductors - insulators Non-metals Metalloids or Semimetals Properties of both Semiconductors Atoms and ions Atoms are electrically neutral. Same number of protons and electrons. Ions are atoms, or groups of atoms, with a charge. Different numbers of protons and electrons. Only electrons can move. Gain or lose electrons. Anion A negative ion. Has gained electrons. Non metals can gain electrons. Charge is written as a superscript on the right. 1F 2O Has gained one electron Has gained two electrons Cations Positive ions. Formed by losing electrons. More protons than electrons. Metals form cations. 1+ Has lost one electron K 2+ Has lost two electrons Ca Two Types of Compounds Molecular compounds Made of molecules. Made by joining nonmetal atoms together into molecules. Two Types of Compounds Ionic Compounds Made of cations and anions. Metals and nonmetals. The electrons lost by the cation are gained by the anion. The cation and anions surround each other. Smallest piece is a FORMULA UNIT. Two Types of Compounds Smallest piece Types of elements State Melting Point Ionic Molecular Formula Unit Molecule Metal and Nonmetal Nonmetals solid Solid, liquid or gas High >300ºC Low <300ºC Chemical Formulas Shows the kind and number of atoms in the smallest piece of a substance. Molecular formula- number and kinds of atoms in a molecule. CO2 C6H12O6 Formula Unit The smallest whole number ratio of atoms in an ionic compound. Ions surround each other so you can’t say which is hooked to which. Charges on ions For most of Group A elements, location on the Periodic Table can tell what kind of ion they form Elements in the same group have similar properties. Including the charge when they are ions. Charge in groups 1A, 2A and 3A is the group number 1+ 2+ in 5A, 6A and 7A 3+ 3- 2- 1are different. Can also use electron dots If it has a few it loses them 3+ Al If it has many, it gains enough for octet 3- + K F N - What about the others? We have to figure those out some other way. More on this later. Naming ions Cation- if the charge is always the same (Group A) just write the name of the metal. Most transition metals can have more than one type of charge. Indicate the charge with Roman numerals in parenthesis. Co2+ Cobalt(II) ion Naming ions A few, like silver, zinc and cadmium only form one kind of ion Don’t get roman numerals Ag+ silver ion Zn2+ zinc ion Cd2+ cadmium ion Na1+ 2+ Ca 3+ Al Fe3+ Fe2+ 2+ Pb 1+ Li Name these Sodium ion Calcium ion Aluminum ion Iron(III) ion Iron(II) ion Lead(II) ion Lithium ion Write Formulas for these Potassium ion Magnesium Copper(II) ion ion K1+ 2+ Mg 2+ Cu 6+ Cr Chromium(VI) ion ion 2+ Ba Mercury(II) 2+ Hg Barium ion Naming Anions Anions are always the same. Change the element ending to – ide 1 F Fluorine Naming Anions Anions are always the same. Change the element ending to – ide 1 F Fluorin Naming Anions Anions are always the same Change the element ending to – ide 1 F Fluori Naming Anions Anions are always the same Change the element ending to – ide 1 F Fluor Naming Anions Anions are always the same Change the element ending to – ide 1 F Fluori Naming Anions Anions are always the same Change the element ending to – ide 1 F Fluorid Naming Anions Anions are always the same Change the element ending to – ide 1 F Fluoride Naming Anions Anions are always the same Change the element ending to – ide 1 F Fluoride ion Name these Cl1- N3Br1O2Ga3+ Chloride ion Nitride ion Bromide ion Oxide ion Gallium ion Write these Sulfide Iodide ion I1- ion Phosphide Strontium S2ion P3- ion Sr2+ Polyatomic ions Groups of atoms that stay together and have a charge. Covalently bonded You must note these. (pg 178 Table 2) 1- ions Acetate C2H3O21- NO311 Nitrite NO2 Nitrate Hydroxide 1OH Permanganate Cyanide CN1- MnO41- 1- ions Perchlorate ClO41- ClO311 Chlorite ClO2 Chlorate 1 Hypochlorite 2- ions Sulfate Sulfite SO4 2- SO32- Carbonate Chromate CO322- CrO4 Dichromate Cr2O72 Silicate SiO32- 3- ions 3- Phosphate PO4 Phosphite PO33- 1+ ion Ammonium NH41+ Adding Hydrogen to Polyatomics Hydrogen ions are 1+ Attach to other polyatomic ionschanges charge by one Sulfate SO42 Hydrogen sulfate HSO41 Phosphate PO43 Hydrogen phosphate HPO42 Dihydrogen phosphate H2PO41- Ions in Ionic Compounds Naming Binary Ionic Compounds Binary Compounds - 2 elements. Ionic - a cation and an anion. The name is just the names of the ions. Cation first anion second Easy with Group A elements. NaCl = Na+ Cl- = sodium chloride MgBr2 = Mg2+ Br- = magnesium bromide Na2S Naming Binary Ionic Compounds The problem comes with the transition metals. Cation name includes the charge. The compound must be neutral. same number of + and – charges. Use the negative charge to find the charge on the positive ion. Naming Binary Ionic Compounds Write the name of CuO Need the charge of Cu O is 2 copper must be 2+ Copper(II) oxide Name CoCl3 Cl is 1- and there are three of them = 3 Co must be 3+ Cobalt(III) chloride Naming Binary Ionic Compounds Write the name of Cu2S. Since S is 2-, the Cu2 must be 2+, so each one is 1+. copper(I) sulfide Fe2O3 Each O is 23 x 2- = 6 2 Fe must = 6+, so each is 3+. iron(III) oxide Naming Binary Ionic Compounds Write the names of the following KCl Na3N CrN Sc3P2 PbO PbO2 Na2Se Ternary Ionic Compounds Will have polyatomic ions At least three elements (3 capital letters) Still just name the ions NaNO3 CaSO4 CuSO3 Ternary Ionic Compounds (NH4)2O Fe(OH)3 LiCN (NH4)2CO3 NiPO4 Writing Formulas The charges have to add up to zero. Get charges on pieces. Cations from name or periodic table. Anions from periodic table or polyatomic. Balance the charges by adding subscripts. Put polyatomics in parenthesis if there is more than one of them Writing Formulas Write the formula for calcium chloride. Calcium is Ca2+ Chloride is Cl11- would have a 1+ charge. Ca2+ Cl Need another Cl1 Ca2+ Cl21 Crisscross Switch the numerical value of the charges 33 2 2+ Ba N Ba3 N2 Reduce ratio if possible Write the formulas for these Lithium sulfide tin (II) oxide tin (IV) oxide Copper (II) sulfate Iron (III) phosphide gallium nitrate Iron (III) sulfide ammonium sulfide Write the formulas for these Ammonium chloride barium nitrate Roman Numeral? Polyatomic? Yes No Charge from name Charge from table Yes No Formula and charge from memory M+X Charge from table Nm-Y MYNmX Ionic Yes Group 1A, 2A or 3A? Poly atomic? Yes No Yes Metal Name Metal (charge) Ionic No Name +ide Things to look for If cations have (), the number is their charge. Not how many. If anions end in -ide they are probably off the periodic table (Monoatomic) If anion ends in -ate or -ite it is polyatomic The positive piece always gets written first Hydrogen- it depends on where it’s at – If it is second, it’s a nonmetal -hydride Molecular Compounds Writing names and Formulas Molecular compounds made of just nonmetals smallest piece is a molecule can’t be held together because of opposite charges. can’t use charges to figure out how many of each atom Easier Ionic compounds use charges to determine how many of each. – Have to figure out charges. – Have to figure out numbers. Molecular compounds name tells you the number of atoms. Uses prefixes to tell you the number Prefixes 1 mono 2 di 3 tri 4 tetra 5 penta 6 hexa 7 hepta 8 octa 9 nona 10 deca Naming To write the name write two words Prefix name Prefix name -ide Exception - we don’t write mono- if there is only one of the first element. No ao oo double vowels when writing name, io, oi, and ai are okay. Name These N2O NO2 Cl2O7 CBr4 CO2 BaCl2 Write formulas for these diphosphorus pentoxide tetraiodine nonoxide sulfur hexaflouride nitrogen trioxide Carbon tetrahydride phosphorus trifluoride aluminum chloride diagram Name 1 Name 2 Yes No No Does Name 2 have a prefix? Yes Prefix Prefix Nm Nm XxYy Yes No Yes Is X a metal? No Prefix+name (no mono) Prefix+name+ide Molecular Acids Writing names and Formulas Acids Compounds that give off hydrogen ions when dissolved in water. Must have H in them. will always be some H next to an anion. The anion determines the name. Naming acids If the anion attached to hydrogen is ends in -ide, put the prefix hydro- and change -ide to -ic acid HCl - hydrogen ion and chloride ion hydrochloric acid H2S hydrogen ion and sulfide ion hydrosulfuric acid Naming Acids If the anion has oxygen in it it ends in -ate or -ite change the suffix -ate to -ic acid HNO3 Hydrogen and nitrate ions Nitric acid change the suffix -ite to -ous acid HNO2 Hydrogen and nitrite ions Nitrous acid Name these HF H3P H2SO4 H2SO3 HCN H2CrO4 Writing Formulas Hydrogen will always be first name will tell you the anion make the charges cancel out. Starts with hydro- no oxygen, -ide no hydro, -ate comes from -ic, -ite comes from -ous Write formulas for these hydroiodic acid acetic acid carbonic acid phosphorous acid hydrobromic acid diagram Name 1 Name 2 Is Name 2 acid? Yes No No Does Name 2 have a prefix? Yes No Hydro- ? No Yes Charge from table -ic acid? Yes -ate Nm-Y HYNm No -ite XxYy Is X hydrogen? Yes No Yes Is X a metal? No Oxygen? Yes -ate? No No Yes ____ ic acid ____ ous acid Acid Hydro____ ic acid 38.Name these acids a) H2C2O4 b) HF c) HClO2 d) H2CO3 39.Write formulas for these compounds a) nitrous acid b) hydroselenic acid c) phosphoric acid d) acetic acid 43. Name these compounds a) AlF3 b) SnO2 c) Fe(C2H3O2)3 d) KHSO4 e) CaH2 f) HClO3 g) Hg2Br2 h) H2CrO4 44. Write formulas for these a) Phosphorus pentabromide b) Carbon chloride c) potassium permanganate 43. Name these compounds a) AlF3 b) SnO2 c) Fe(C2H3O2)3 d) KHSO4 e) CaH2 f) HClO3 g) Hg2Br2 h) H2CrO4 44. Write formulas for these a) Phosphorus pentabromide b) Carbon chloride c) potassium permanganate d) Calcium hydrogen carbonate e) dichlorine heptoxide f) trisilicon tetrahydride g) sodium dihydrogen phosphate Summary Periodic table – Grouped by properties Metals- make cations – 2 types those with () and those without Nonmetals make anions – Three types • Without O -ide • With O -ite and -ate Only electrons can move to make ions Summary Make all the decisions. First determine type of compound Then figure out name or formula Acid = H to start Metal = Ionic No H, No metal = molecular Only molecular get prefixes Roman numeral is NOT how many Hydro means no O