Ionic Charges • • • • • • • What kind of charge do ions formed from metals have? Nonmetals? What is the difference between Cu and Cu2+? Cu is the neutral atom of copper; Cu2+ is the cation of Cu, which has lost 2 electrons What is the difference between Cu2+ and Cu+? Cu2+ indicates the loss of 2 electrons; Cu+ indicates the loss of one electron What does the ionic formula for hypochlorite, ClO-, indicate? that the atoms in a hypochlorite ion act as a unit with an overall charge of 1- Monatomic ions ions consisting of only one atom, the ionic charges can often be determined by using the PT 1 Li+ Ionic Charges of Representative Elements 2 3 4 5 6 7 Be2+ N3O2F- Na+ Mg2+ K+ Ca2+ Rb+ Sr2+ Cs+ Ba2+ Al3+ P3- S2- Cl- As3- Se2- Br- I- 8 Cations of the transition metals have more than 1 common ionic charge Formulas and Names of Common Metal Ions with More than One Ionic Charge Formula Stock Name Classical Name Cu+ Copper (I) ion Cuprous ion Cu2+ Copper (II) ion Cupric ion Fe2+ Iron (II) ion Ferrous ion Fe3+ Iron (III) ion Ferric ion Hg22+ Mercury (I) ion Mercurous ion Hg2+ Mercury (II) ion Mercuric ion Pb2+ Lead (II) ion Plumbous ion Pb4+ Lead (IV) ion Plumbic ion Sn2+ Tin (II) ion Stannous ion Sn4+ Tin (IV) ion Stannic ion Cr2+ Chromium (II) ion Chromous ion Cr3+ Chromium (III) ion Chromic ion Mn2+ Manganese (II) ion Manganous ion Mn3+ Manganese (III) ion Manganic ion Co2+ Cobalt (II) ion Cobaltous ion Co3+ Cobalt (III) ion Cobaltic ion Transition Metals • -suffix “-ous” is used to name the cation with the lower of the two ionic charges • ous, less • suffix “-ic” is used to name the cation with the higher of the two charges • Silver (Ag) is a transition metal that nearly always has a 1+ charge • Cadmium and Zinc are transition metals that nearly always have a 2+ charge What is the charge of the ion typically formed by each element? • • • • • • sulfur lead, 4 electrons lost strontium argon bromine copper, 1 electron lost • • • • • • S2Pb4+ Sr2+ no ion BrCu1+ Name the ion and state whether it is a cation or an anion • Sulfur • sulfide ion/anion • lead, 4 electrons lost • • strontium Argon • lead (IV) ion or Plumbic ion/cation • strontium ion/cation • no ion • • bromine copper, 1 electron lost • bromide ion/anion • copper (I) ion or cuprous ion/cation Polyatomic Ions • tightly bound groups of atoms that behave as a unit and carry a charge. • Examples: • • • • Nitrate ion NO3Phosphate ion PO43Sulfate ion SO42Ammonium ion NH4+ Naming • “-ite” and “-ate” • (less) (more) • These terms refer only to the number of oxygen atoms involved. It doesn’t tell you how many, it just tells you which one has more or less “ite” SO32- sulfite “ate” SO42sulfate NO2- nitrite NO3- nitrate ClO2chlorite ClO3chlorate Common Polyatomic Ions 1- charge 2- charge 3- charge Formula Name Formula Name Formula Name H2PO4- Dihydrogen phosphate HPO42- Hydrogen phosphate PO33- Phosphite C2H3O2- Acetate C2O42- Oxalate PO43- Phosphate HSO3- Hydrogen sulfite SO32- Sulfite HSO4- Hydrogen sulfate SO42- Sulfate HCO3- Hydrogen carbonate CO32- Carbonate NO2- Nitrite CrO42- Chromate NO3- Nitrate Cr2O72- Dichromate CN- Cyanide SiO32- Silicate OH- Hydroxide MnO4- Permanganate ClO- Hypochlorite ClO2- Chlorite ClO3- Chlorate ClO4- Perchlorate 1+ charge Formula Name NH4+ Ammonium Ionic Charges Review Questions • Write the formula for each ion • • • • • • • • ammonium ion tin (II) ion chromate nitrate ion cyanide ion iron (III) ion permanganate ion manganese (II) ion • • • • • • • • NH4+ Sn2+ CrO42NO3CNFe3+ MnO4Mn2+ Ionic Charges Review Questions • Write the symbol for each ion. Be sure to include the charge • • • • • • oxide ion lead (II) ion lithium ion nitride ion cupric ion fluoride ion • • • • • • O2Pb2+ Li+ N3Cu2+ F- Ionic Charges Review Questions • Name the following ions • • • • • • Ba2+ IAg+ Hg2+ P3Sn4+ • • • • • • barium ion iodide ion silver ion mercury (II) ion phosphide ion tin (IV) ion Ionic Charges Review Questions • Name the following ions • • • • • • • • OHPb4+ SO42O2HPO42Cr2O72Al3+ ClO2- • • • • • • • • hydroxide lead (IV) sulfate oxide hydrogen phosphate dichromate aluminum chlorite