Ch. 10 Stoichiometry GCC CHM 130 10.1 Interpreting a Chemical Equation 2 NO (g) 2 molecules 10 molecules 2 moles N2 (g) + + O2 (g) → 2 NO2 (g) 1 molecule 5 molecules 1 mole 3 H2 (g) → ___ molecule(s) ___ molecule(s) ____ mole ____ mole 2 molecules 10 molecules 2 mole2 2 NH3 (g) ___molecule(s) ____ mole So coefficients give us molecule or mole ratios. 10.2 Mole-Mole Ratios ___ Fe2O3 (s) + ___ CO (g) g __ Fe (s) + ___CO2 (g) 1 mol 3 mol Examples: 1 mol Fe2O3 3 mol CO 2 mol 3 mol CO 1 mol Fe2O3 3 mol 2 mol Fe 3 mol CO 1. How many moles of iron can be formed from 10.2 moles of carbon monoxide? 10.2 mol CO ( 2 mol Fe / 3 mole CO) = 6.80 mol Fe 2. How many moles of iron(III) oxide are needed to form 17 moles of carbon dioxide? 17 mol CO2 ( 1 mol Fe2O3 / 3 mole CO2) = 5.7 mol Fe2O3 Another Example Balance this reaction: 2 SO2 (g) + ___O2(g) g ___SO 2 ___ 3(g) How many moles of SO3 will form if 0.165 moles of oxygen gas react? 0.165 mol O2 (2 mol SO3 / 1 mol O2) = 0.330 mol SO3 How many moles of SO2 are needed to make 0.042 moles of sulfur trioxide? 0.042 mol SO3 (2 mol SO2 / 2 mol SO3) = 0.042 mol SO2 10.3-4 Mass – Mass Stoichiometry Grams given Molar Mass 3 FeO(s) Moles given Mole Ratio Moles find + 2 Al(s) g 3 Fe(s) Molar Mass + Grams find Al2O3(s) 1. Calculate the mass of iron (II) oxide needed to react completely with 5.55 g of aluminum. 2. Calculate the mass of aluminum oxide produced when 10.25 g of aluminum reacts completely. 3 FeO(s) + 2 Al(s) g 3 Fe(s) mol Al 1. 5.55 g Al 26.98 g Al + Al2O3(s) 3 mol FeO 71.85 g FeO 2 mol Al mol FeO = 22.2 g FeO mol Al 2. 10.25 g Al 26.98 g Al = 19.37 g Al2O3 1 mol Al 2 O 3 101.96 g Al 2 O 3 mol Al 2 O 3 2 mol Al 10.5-6 Mass – Volume and Volume-Volume problems Write and balance the reaction of HCl (aq) and solid cobalt. Note cobalt will be +2 as an ion in this example. 2 HCl(aq) + Co(s) g CoCl2(aq) + H2(g) How many liters of gas at STP will form if 5.00 grams of cobalt reacts? 5.00 g Co(mol/58.93)(1 molH2/1molCo)(22.4L/mol) = 1.90 L H2 If 2.374 L of hydrogen gas formed, how many grams of HCl reacted? 2.374 L H2 (mol/22.4L)(2 mol HCl/1 mol H2)(36.46 g/mol) = 7.73 g HCl HCl gas plus oxygen gas produces chlorine gas and water vapor. • How many liters of chlorine can be formed if 3.00 liters of oxygen react completely at STP? 4 HCl(g) + O2(g) g 2 Cl2(g) + 2 H2O(g) 3.00 L O2 (mol / 22.4 L)(2 mol Cl2 / 1 mol O2)(22.4 L/mol) = 6.00 L Cl2 Skip sections 10.7 - 9 Try at Home Carbon reacts with oxygen gas to form carbon monoxide. How many liters of carbon monoxide at STP can be made from 1. 15.0 grams carbon? 2. 20.0 liters of oxygen gas? Remind me to show answers next time 2 C(s) + O2(g) g 2 CO(g) 15.0 g C (mol /12.01g)(2 mol CO/2 mol C)(22.4 L / mol)= 28.0 L CO 20.0 L O2 (mol /22.4L)(2 mol CO /1 mol O2)(22.4 L/mol)= 40.0 L CO Self Test • Page 288 • Try 1-6, 10, 14 • Answers in Appendix J