lithium nitrate lead (II) sulfide lithium nitride barium sulfide lithium nitrite Chemistry sulfur dioxide Unit 5: Bonding and Inorganic Nomenclature NaClO3 NO2 Fe(ClO3)2 N2O4 Fe(ClO3)3 N2O5 Bonding Types 1. Ionic Bonding • • • with ions (+/- charges) atoms gaining/losing eM + NM 2. Covalent Bonding • • atoms sharing eNM + NM 3. Metallic Bonding • • • metals share e- freely “sea of e-” good conductors Chemical Bonding Ionic Bonds: atoms give up or gain e– and are attracted to each other by coulombic attraction Na loses e– Na+ Na+ + Cl– Cl gains e– NaCl ionic compounds = salts K+ + NO3– KNO3 Cl– ionic bonds: M + NM cation + anion where NO3– is a polyatomic ion: a charged group of atoms that stay together Common Polyatomic Ions Names of Common Polyatomic Ions Ion Name Ion Name NH4 + *NO2 NO3 *SO3 2SO4 2HSO4OH CN C2H3O2MnO4 PO4 3*PO3 3H2PO4 - ammonium *nitrite nitrate *sulfite sulfate hydrogen sulfate hydroxide cyanide acetate permanganate phosphate *phosphite dihydrogen phosphate CO3 2HCO3 *IO3*IO4*ClO *ClO2 ClO3 *ClO4 *BrO3C2O42Cr2O7 2CrO4 2O2 2- carbonate bicarbonate *iodate *periodate *hypochlorite *chlorite chlorate *perchlorate *bromate oxalate dichromate chromate peroxide Memorize the BOLD ions Zumdahl, Zumdahl, DeCoste, World of Chemistry 2002, page 100 * = you will also be responsible for knowing these Polyatomic Ion Trends *Charges NEVER change between different forms +1 oxygen “Per____ate” BrO4perbromate ClO4- perchlorate IO4periodate “Normal” “–ate” form BrO3bromate ClO3chlorate IO3iodate NO3nitrate CO32carbonate SO42sulfate PO43phosphate -1 oxygen “-ite” form -2 oxygens “hypo___ite” BrO2- BrO- bromite hypobromite ClO2- ClO- chlorite hypochlorite IO2- IO- iodite hypoiodite NO2nitrite CO22carbonite SO32sulfite PO33phosphite Properties of Ionic Salts 1. very hard each ion is bonded to several oppositely charged ions 2. high melting points 3. brittle many bonds must be broken with sufficient force, like atoms are brought next to each other and repel calcite Writing Formulas of Ionic Compounds chemical formula: has neutral charge; shows types of atoms and how many of each To write an ionic compound’s formula, we need: 1. the two types of ions (i.e., cations and anions) 2. the charge on each ion Na+ and F– NaF Ba2+ and O2– BaO Na+ Ba2+ and and O2– Na2O F– BaF2 K+ e- e- potassium atom BrBr bromine atom bromide ion potassium potassium ion bromide Notice that the pink pieces are cations (metals) and the blue are anions (non-metals) KBr Br Mg2+ Br 1 Mg2+ 2 Br - MgBr2 magnesium bromide K+ O2K+ potassium oxide K2O Chemical Bonding Activity Examples N3- Na+ Pb4+ OH - 1 Na + 1 OH N3- - N3- Pb4+ NaOH Pb4+ OH N3- Mg2+ OH - 1 Mg2+ 2 OH - Mg OH 2 Pb4+ Pb3N4 N3Pb4+ N3- criss-cross rule: charge on cation / anion “becomes” subscript of anion / cation ** Warning: Reduce to lowest terms Al3+ and O2– Ba2+ and S2– In3+ and Br1– Al 2 O 3 Ba 2S 2 In 1 Br 3 Al2O3 BaS InBr3 Writing Formulas w/Polyatomic Ions Parentheses are required only when you need more than one “bunch” of a particular polyatomic ion Ba2+ SO42– BaSO4 Mg2+ and NO2– Mg(NO2)2 NH4+ and ClO3– NH4ClO3 Sn4+ and SO42– Sn(SO4)2 Fe3+ and Cr2O72– Fe2(Cr2O7)3 N3– (NH4)3N and NH4+ and The Importance of Parentheses Calcium hydroxide ide Ca2+ OH- CaOH2 Ca - O H H vs. Ca(OH)2 HO - Ca - OH The formulas imply two totally different compounds! Charges Reminder! 1+ 2+ Group 1: Group 2: Group 3: Group 5: Group 6: Group 7: Group 8: 1+ 2+ 3+ 3– 2– 1– 0 0 3+ 3– 2– 1– Inorganic Nomenclature potassium nitrate KNO3 copper (II) sulfate CuSO4 dinitrogen monoxide N2O sodium hydroxide NaOH Nomenclature - Humor Fe2+ Fe2+ Fe2+ Fe2+ Fe2+ Fe2+ Fe2+ Fe2+ “Ferrous Wheel” Fe = iron (Latin = ferrum) Fe2+ = lower oxidation state = ferrous Fe3+ = higher oxidation state = ferric BaNa2 “BaNaNa” What weapon can you make from the elements nickel, potassium and iron? A KNiFe Teacher: What is the formula for water? Student: H, I, J, K, L, M, N, O Teacher: That’s not what I taught you. Student: But you said the formula for water was…H to O. "H-O-H"?! WHAT'S THAT SPELL?! mis WATER? “Little Johnny took a drink, Now he shall drink no more. For what he thought was H2O, Was H2SO4.” Under aged Pb walks into a bar and the bartender turns to the gold Bouncer and says, “Au, get the lead out!” “Perhaps one of you gentlemen would mind telling me just what is outside the window that you find so attractive..?” Image courtesy NearingZero.net Ionic Compounds (cation/anion combos) Fixed-Charge Cations with Elemental Anions i.e., “pulled off the The fixed-charge cations are: Table” anions groups 1, 2, 13, Ag+ and Zn2+ 1+ 2+ 3+ 3– 2– 1– Fixed-Charge Exceptions 3+ • Start with Al • Go backwards down the stairs • Decrease the charge after each stair 3+ Al 13 2+ Zn 30 Ag 47 + Fixed-charge cations Variable-charge cations Elemental anions 1+ 1 H 1 2 3 7 2 3- 2- 1- B C N O F Ne 3 4 5 6 7 8 9 10 Al Si P S Cl Ar 13 14 15 16 17 18 Na Mg K 12 Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr 23 24 35 36 I Xe 53 54 20 21 22 Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In 39 40 41 42 49 Hf Ta W 72 73 74 37 6 1 Be 19 5 3+ He Li 11 4 2+ H 38 Cs Ba 55 56 Fr Ra 87 88 * W 25 43 26 44 Re Os 75 76 27 28 29 47 30 45 46 Ir Pt Au Hg Tl 77 78 81 79 48 31 80 32 33 34 Sn Sb Te 50 51 Pb Bi 82 83 52 Po At Rn 84 85 86 Rf Db Sg Bh Hs Mt 104 105 106 107 108 109 La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu 57 58 59 Ac Th Pa 89 90 91 60 U 92 61 62 63 64 65 66 Np Pu Am Cm Bk Cf 93 94 95 96 97 98 67 68 69 70 71 Es Fm Md No Lr 99 100 101 102 103 1+ Na 2+ 3+ 3– 2– 1– A. To name, given the formula: Ba 1. Use name of cation 2. Use name of anion (it has the ending “ide”) NaF sodium fluoride BaO barium oxide Na2O sodium oxide BaF2 barium fluoride Ca Zn 1+ 2+ 3+ Ag 3– 2– 1– B. To write formula, given the name: 1. Write symbols for the two types of ions 2. Balance charges to write formula silver sulfide Ag+ S2– Ag2S zinc phosphide Zn2+ P3– Zn3P2 calcium iodide Ca2+ I– CaI2 Variable-Charge Cations with Elemental Anions i.e., “pulled off the Table” anions The variable-charge cations are: Pb, Sn, and the transition metals (but – of course! – not Ag or Zn) A. To name, given the formula: Fe Cu 1. Figure out charge on cation. 2. Write name of cation. 3. Write Roman numerals in ( ) to show cation’s charge. 4. Write name of anion. -6 Stock System of nomenclature FeO 2+oxide ? iron Fe O2– Fe2O3 ? 3+oxide iron Fe Fe?3+ O2– O2–O2– iron (III) oxide CuBr – copper Cu+? Brbromide copper (I) bromide CuBr2 – Br – copper Cu?2+ Brbromide copper (II) bromide iron (II) oxide B. To find the formula, given the name: 1. Write symbols for the two types of ions. 2. Balance charges to write formula. Co Sn cobalt (III) chloride Co3+ Cl– CoCl3 tin (IV) oxide Sn4+ O2– SnO2 tin (II) oxide Sn2+ O2– SnO Ionic Nomenclature Practice 1. sodium hydroxide NaOH 9. iron (III) oxide Fe2O3 2. HgSO4 mercury (II) sulfate 10. Mg(NO3)2 magnesium nitrate 3. lead (II) phosphate 4. (NH4)2S Pb3(PO4)2 ammonium sulfide 5. aluminum chlorate 6. Cu2CO3 Al(ClO3)3 copper (I) carbonate 7. manganese (IV) oxide 8. MnSO4 MnO2 manganese (II) sulfate 11. calcium sulfide CaS 12. K2O potassium oxide 13. magnesium chloride 14. Cr2O3 MgCl2 chromium (III) oxide 15. gold (III) bromide 16. Zn(NO2)2 AuBr3 zinc nitrite Traditional System of Nomenclature …used historically (and still some today) to name compounds w/multiple-charge cations To use: 1. Use Latin root of cation. 2. Use -ic ending for higher charge; -ous ending for lower charge. 3. Then say name of anion, as usual. Element gold, Au lead, Pb tin, Sn copper, Cu iron, Fe Latin root aurplumbstanncuprferr- Write formulas: cuprous sulfide Cu+ S2– Cu2S auric nitride Au3+ N3AuN ferrous fluoride FeF2 Fe2+ F– -ic Au3+ Pb4+ Sn4+ Cu2+ Fe3+ -ous Au+ Pb2+ Sn2+ Cu+ Fe2+ Write names: ? P3– Pb4+ Pb3P4 plumbic phosphide Pb?2+ P3– Pb3P2 plumbous phosphide Sn?4+ Cl– Sn SnCl4 stannic chloride Compounds Containing Polyatomic Ions Insert name of ion where it should go in the compound’s name. Write formulas: iron (III) nitrite Fe3+ NO2– Fe(NO2)3 ammonium phosphide NH4+ P3– (NH4)3P ammonium chlorate NH4+ ClO3– NH4ClO3 zinc phosphate Zn2+ PO43– Zn3(PO4)2 lead (II) permanganate Pb2+ MnO4– Pb(MnO4)2 Write names: (NH4)2S2O3 ammonium thiosulfate AgBrO3 silver bromate (NH4)3N ammonium nitride CrO42– ? CrO 2– uranium (VI) chromate U(CrO4)3 U6+ 4 CrO42– ? SO 2– Cr2(SO3)3 Cr3+ chromium (III) sulfite 3 Cr?3+SO32– SO32– Self-Test Quiz 1. lithium nitrate 2. lithium nitride 3. lithium nitrite 4. NaClO3 5. Fe(ClO3)2 6. Fe(ClO3)3 7. lead(II) sulfide 8. barium sulfide 9. Never show charges in a compound’s formula. (T/F) 10. When writing names with Group 9 cations, you need to use Roman numerals. (T/F) 11. When using an anion off the polyatomic ion sheet, change name’s ending to “-ide.” (T/F) 12. A Roman numeral indicates the charge on the anion. (T/F) Self-Test Quiz Answers 1. lithium nitrate LiNO3 2. lithium nitride Li3N 3. lithium nitrite LiNO2 4. NaClO3 sodium chlorate 5. Fe(ClO3)2 iron(II) chlorate 6. Fe(ClO3)3 iron(III) chlorate 7. lead(II) sulfide PbS 8. barium sulfide BaS Self-Test Quiz Answers T 9. Never show charges in a compound’s formula. T 10. When writing names with Group 9 cations, you need to use Roman numerals. 11. When using an anion off the polyatomic ion sheet, change the name’s ending to “-ide.” F F 12. A Roman numeral indicates the charge on the anion. Covalent Bonds (2 nonmetals) …atoms share e– to get a full valence shell C 1s2 2s2 2p2 4 valence e1s2 2s2 2p5 F 7 valence e- Both need 8 valence e- for a full outer shell… otherwise known as the octet rule o o C o xx o x x F xx x Draw the Lewis dot structure for the following elements: Si 1s2 2s2 2p6 3s2 3p2 4 valence e- O 1s2 2s2 2p4 6 valence e- P 1s2 2s2 2p6 3s2 3p3 5 valence e- B 1s2 2s2 2p1 3 valence e- Ar 1s2 2s2 2p6 3s2 3p6 8 valence e- Br 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p5 7 valence e- Notice any trends…? Drawing Lewis Structures Lewis structure: a model of a covalent molecule that shows all of the valence e– 1. Two shared e– make a single covalent bond, four make a double bond, etc. 2. unshared pairs: pairs of unbonded valence e– 3. Each atom needs a full outer shell, i.e., 8 e–. Exception: H needs 2 e– Let’s bond two F atoms together… Each F has 7 v.e. and each needs 1 more e- F F F F F2 Now let’s bond C and F atoms together… carbon tetrafluoride (CF4) F F C F F F C F F F And now, a video break… nitrogen triiodide (NI3) x x x x x x x x o o o N o o I x x x x x x x o o o x I N o x x x x x x x Ix x x x x x o x x x Ix x I x x x x x x x x I carbon dioxide (CO2) x x o o x x o C o x x x x Ox x Ox x x x x x Ox o x o o C o xx x Ox xx x x xx O =C=O xx xx covalent compounds = molecular compounds -- have lower melting points than do ionic compounds (consist of two or more nonmetal elements) butter Dihydrogen Monoxide: A Tale of Danger and Irresponsibility major component of acid rain found in all cancer cells inhalation can be deadly excessive ingestion results in acute physical symptoms: e.g., frequent urination, bloated sensation, profuse sweating often an industrial byproduct of chemical reactions; dumped wholesale into rivers and lakes Covalent Compounds -- contain two types of nonmetals ** Key: FORGET CHARGES! Use Greek prefixes to indicate how What to do: many atoms of each element, but don’t use “mono” on first element. 1 – mono 2 – di 3 – tri 6 – hexa 7 – hepta 8 – octa 4 – tetra 5 – penta 9 – nona 10 – deca EXAMPLES: carbon dioxide CO2 CO carbon monoxide dinitrogen trioxide N2O3 N2O5 dinitrogen pentoxide carbon tetrachloride CCl4 NI3 nitrogen triiodide Metallic Bonds In metals, valence shells of atoms overlap, so v.e– are free to travel between atoms through material. In insulators (like wood), the v.e– are attached to particular atoms. Not so in metals. Properties of Metals ductile malleable conduct heat and electricity All due to free-moving v.e–. Other Types of Forces/Attractions dipole-dipole forces hydrogen bonds London dispersion forces ion-dipole forces boiling H2O DNA These are much weaker than ionic, covalent, or metallic bonds, but very important in determining states of matter, boiling and melting points, and molecular shape (among other things). Empirical Formula and Molecular Formula lowest-terms formula shows the true number and type of atoms in a m’cule Compound Molecular Formula Empirical Formula glucose C6H12O6 CH2O propane C3H8 C3H8 butane C4H10 C2H5 naphthalene C10H8 C5H4 sucrose C12H22O11 C12H22O11 octane C8H18 C4H9 Nomenclature Review Flow Chart Formula Name? Metal + Nonmetal? (Including NH4+) Ionic d,f-block Pb,Sn Metal Type? Columns 1, 2, 13 Ag+, Zn2+ Variable Fixed Two Nonmetals? Covalent Steps 1 & 4 ONLY 1. Write name of cation (metal) 2. Determine the charge on the metal by balancing the (-) charge from the anion 3. Write the charge of the metal in Roman Numerals and put in parentheses 4. Write name of anion (Individual anions need –ide ending!) Use Prefixes! *Mono* Di Tri Tetra Penta Hexa Hepta Octa Nona Deca Add –ide to 2nd element Name Formula? No Prefixes? Ionic Prefixes? Covalent 1. Determine the ions present and the charge on each (Roman Numeral = cation charge, otherwise use PT) 1. FORGET CHARGES!!! 2. Balance formula (criss-cross) 3. Do NOT reduce subscripts! 3. Reduce subscripts (if needed) 2. Use prefixes to determine subscripts Ionic Compounds Covalent Two nonmetals Variable-charge cation carbon sulfur tetrabromide N NCl O35 2dichloride vanadium niobiumMn Pt(IO (V) (II) Sperchlorate )4 2 53chromate rubidium sulfate NH4KI ClOoxide barium 3 Roman numeral for name only Roman numeral Greek prefixes Charge CrissCross Rule Roman numeral Fixed-charge Don’t know the charge from Know the charge from PT Polyatomic ions OK PT Polyatomic ions OK Where would you file this? VCrO4 dinitrogen pentoxide BaO platinum (IV) iodate CBr4 ammonium chlorate Nb(ClO4)5 potassium iodide SCl2 nitrogen trichloride Rb2SO4 manganese (V) sulfide Overall Nomenclature Practice Ionic/variable Ir F3 iridium (III) fluoride Ca S calcium sulfide Ti S2 titanium (IV) sulfide HCl(aq) hydrochloric acid Acid BaBr2 barium bromide Ionic/fixed N3P2 trinitrogen diphosphide Covalent HF(aq) hydrofluoric acid Zn I2 zinc iodide Ionic/fixed NCl4 nitrogen tetrachloride Covalent Au 2O3 gold (III) oxide Na 3P sodium phosphide Ionic/fixed Ionic/variable Acid Ionic/variable Ionic/fixed Ionic Nomenclature Practice Ionic/variable Ir2 (Cr2O7)3 iridium (III) dichromate Ca (OH)2 calcium hydroxide HNO3 (aq) nitric acid Pt (CH3COO)2 platinum (II) acetate HBrO2(aq) bromous acid Sr SO4 strontium sulfate Ionic/fixed KCN potassium cyanide Ionic/fixed Zn (NO2)2 zinc nitrite Ionic/fixed Mn (ClO3)4 manganese (IV) chlorate Ionic/variable Au PO4 gold (III) phosphate Ionic/variable H2 SO3 (aq) sulfurous acid Ionic/fixed Acid Ionic/variable Acid Acid Write the compound formed by the following ions: 1) Al3+ S22) Mg2+ PO43- When a formula is given…write the proper name. When a name is given…write the proper formula. 3) BaO 4) lithium bromide 5) Ni2S3 6) triphosphorus heptoxide 7) N2O5 8) molybdenum (VI) nitride Write the total number of atoms that make up each compound. 9) trinitrotoluene (TNT)… CH3C6H2(NO2)3 10) phosphoric acid H3PO4 Extra credit: What is the formula for plumbic iodide? (Hint: lead is Pb2+ or Pb4+) Write the compound formed by the following ions: 1) Al3+ S22) Mg2+ PO43- When a formula is given…write the proper name. When a name is given…write the proper formula. 3) BaO POP QUIZ 4) lithium bromide 5) Ni2S3 6) triphosphorus heptoxide 7) N2O5 8) molybdenum (VI) nitride Write the total number of atoms that make up each compound. 9) trinitrotoluene (TNT)… CH3C6H2(NO2)3 10) phosphoric acid H3PO4 Extra credit: What is the formula for plumbic iodide? (Hint: lead is Pb2+ or Pb4+) Answer Key Write the compound formed by the following ions: 1) Al3+ S22) Mg2+ Al2S3 Mg3(PO4)2 PO43- When a formula is given…write the proper name. When a name is given…write the proper formula. 3) BaO barium oxide LiBr 4) lithium bromide 5) Ni2S3 nickel (III) sulfide P3O7 6) triphosphorus heptoxide 7) N2O5 dinitrogen pentoxide 8) molybdenum (VI) nitride MoN2 Write the total number of atoms that make up each compound. 9) trinitrotoluene (TNT)… CH3C6H2(NO2)3 10) phosphoric acid H3PO4 21 8 Extra credit: What is the formula for plumbic iodide? (Hint: lead is Pb2+ or Pb4+) PbI4 Writing Chemical Names Use poly. Formula RN/GP/neither ion sheet? Name 1. Ni2 S3 RN no nickel (III) sulfide 2. N F3 GP no nitrogen trifluoride 3. Na BrO3 neither yes sodium bromate 4. S F6 GP no sulfur hexafluoride 5. Fe (NO3)3 RN yes iron (III) nitrate 6. Sr SO4 neither yes strontium sulfate Writing Chemical Formulas Use poly. Name Charges matter? ion sheet? 1. copper (II) phosphide yes no 2. lithium phosphate yes yes Formula Cu3P2 Li3PO4 3. phosphorus triiodide no no PI3 4. zinc arsenate yes yes Zn3(AsO4)2 5. silver nitride yes no Ag3N 6. sulfur dibromide no no SBr2 7. dinitrogen pentasulfide no 8. tin (IV) nitride yes no no N2S5 Sn3N4 9. rubidium nitrite yes yes RbNO2 10. oxygen difluoride no no OF2 11. iron (III) sulfite 12. ammonium oxide yes yes yes yes Fe2(SO3)3 (NH4)2O Writing Chemical Names Use poly. Formula RN/GP/neither ion sheet? Name 7. S O3 8. Sn Br4 GP neither no no sulfur trioxide tin (IV) bromide 9. K3 PO4 neither yes potassium phosphate 10. NH4 OH neither yes yes ammonium hydroxide 11. C S2 12. Cu F GP RN no no carbon disulfide copper (I) fluoride Writing Chemical Formulas Use poly. Name Charges matter? ion sheet? 1. copper (II) phosphide yes no 2. lithium phosphate yes yes Formula Cu3P2 Li3PO4 3. phosphorus triiodide no no PI3 4. zinc arsenate yes yes Zn3(AsO4)2 5. silver nitride yes no Ag3N 6. sulfur dibromide no no SBr2 7. dinitrogen pentasulfide no 8. tin (IV) nitride yes no no N2S5 Sn3N4 9. rubidium nitrite yes yes RbNO2 10. oxygen difluoride no no OF2 11. iron (III) sulfite 12. ammonium oxide yes yes yes yes Fe2(SO3)3 (NH4)2O Writing Chemical Formulas Use poly. Name Charges matter? ion sheet? 1. copper (II) phosphide yes no 2. lithium phosphate yes yes Formula Cu3P2 Li3PO4 3. phosphorus triiodide no no PI3 4. zinc arsenate yes yes Zn3(AsO4)2 5. silver nitride yes no Ag3N 6. sulfur dibromide no no SBr2 7. dinitrogen pentasulfide no 8. tin (IV) nitride yes no no N2S5 Sn3N4 9. rubidium nitrite yes yes RbNO2 10. oxygen difluoride no no OF2 11. iron (III) sulfite 12. ammonium oxide yes yes yes yes Fe2(SO3)3 (NH4)2O Writing Chemical Names Use poly. Formula RN/GP/neither ion sheet? Name 1. Ni2 S3 RN no nickel (III) sulfide 2. N F3 GP no nitrogen trifluoride 3. Na BrO3 neither yes sodium bromate 4. S F6 GP no sulfur hexafluoride 5. Fe (NO3)3 RN yes iron (III) nitrate 6. Sr SO4 neither yes strontium sulfate 7. S O3 8. Sn Br4 GP neither no no sulfur trioxide tin (IV) bromide 9. K3 PO4 neither yes potassium phosphate 10. NH4 OH neither yes ammonium hydroxide 11. C S2 12. Cu F GP RN no no carbon disulfide copper (I) fluoride Writing Chemical Formulas Name Charges matter? 1. copper (II) phosphide yes 2. lithium phosphate yes Use poly. ion sheet? no yes Formula Cu3P2 Li3PO4 3. phosphorus triiodide no no PI3 4. zinc arsenate yes yes Zn3(AsO4)2 5. silver nitride yes no Ag3N 6. sulfur dibromide no no SBr2 7. dinitrogen pentasulfide no 8. tin (IV) nitride yes no no N2S5 Sn3N4 9. rubidium nitrite yes yes RbNO2 10. oxygen difluoride no no OF2 11. iron (III) sulfite 12. ammonium oxide yes yes yes yes Fe2(SO3)3 (NH4)2O