Dielectro-Rheological Device (DRD) www.anton-paar.com Dielectric Spectroscopy: The measurement Electrical current flowing through a sample as a response to an alternating electric field is measured as a function of the field frequency Dielectric spectrum gives information on structure and behavior of the material Voltage application + Dielectric + Induction of an - electric field - Voltage DC or AC voltage LCR meter Current Measurement of the flowing current www.anton-paar.com Dielectro-Rheological Device (DRD) Setup for Peltier and CTD chambers available Contact at upper geometry by spring (Rotation) or wire (Oscillation) Applications Filled rubbers Polymers nanocomposites carbon nanotubes clays Battery research Conductivity of filled polymers www.anton-paar.com Rheo-Dielectric-Spectroscopy Dielectro Rheological Device DRD An electrical potential is applied by a spring system onto the shaft and the capacitance is measured. Ceramic isolation Goldspring or -wire contact Measuring Plate PP25/PP50 Sample The bottom measuring plate is isolated to the Rheometer Contact Peltier Counter Cooling Uniform temperature distribution with Peltier Hood (-40°C - +200°C) www.anton-paar.com Dielectro Rheology Example: Polymer Carbon Black Composite Creep Test 2.5 Rheology: 2 strain [%] Carbon black clusters dispersed in a polymer matrix. Carbon black induces dielectric properties in the composite. (Shear stress: 65400 Pa) 1.5 1 0.5 0 0 50 100 150 200 250 300 350 time [s] Conductivity 1.00E-07 Slow mechanical relaxation of long chain polymers Fast electrical relaxation of carbon black clusters σ' [S/cm] Dielectricity: (Frequency: 1 kHz) 1.00E-08 1.00E-09 1.00E-10 0 50 100 150 200 250 300 time [s] www.anton-paar.com 350 Epoxy resin filled with carbon nanotubes The nanotubes are inducing electric conductivity in the resin. Flow curve: 0.1 – 100 s-1 , 1 kHz and 1V 2.50E-08 1000 Capacitance [F] 2.00E-08 100 1.50E-08 1.00E-08 10 Viscosity [Pas] Capacity Viscosity 5.00E-09 0.00E+00 1 0.1 1 10 100 Shear rate [s-1] Capacity changes due to an orientation of the nanotubes www.anton-paar.com Epoxy resin filled with carbon nanotubes 5.00E-08 4.50E-08 4.00E-08 3.50E-08 3.00E-08 2.50E-08 2.00E-08 1.50E-08 1.00E-08 5.00E-09 0.00E+00 1.00E+03 1.00E+02 1.00E+01 Capacitance G´ G´´ Storage / Loss modulus [Pa] Capacitance [F] Strain sweep 0.1 -1000% at 10 1/s, 1kHz and 1V 1.00E+00 0.1 1 10 100 1000 Strain [%] Capacity is constant within the linear viscoelastic range and decreases in the nonlinear regime due to an alignment in flow direction. www.anton-paar.com