Lecture 15: Capillary motion Capillary motion is any flow governed by forces associated with surface tension. Examples: paper towels, sponges, wicking fabrics. Their pores act as small capillaries, absorbing a comparatively large amount of liquid. Water absorption by paper towel Capillary flow in a brick Height of a meniscus The meniscus will be approximately hemispherical with a constant radius of curvature, R h0 a R1 R 2 cos θ Applying the Young-Laplace equation we obtain a Hence, patm pliq gh 0 2c cos h0 2 2 cos g a a 2 cos a g 2 c is the capillary length. h0 may be positive and negative, e.g. for mercury θ~1400 and the meniscus will fall, not rise. For water, α=73*10-3N/m, and in 0.1mm radius clean glass capillary, h0=15cm. Let us calculate the rate at which the meniscus rises to the height h0. Assume that the velocity profile is given by the Poiseuille a profile, A 2 2 Aa 4 v a r ; Q 2 vrdr 4 8 0 The average velocity is Q Aa 2 p1 p 2 a 2 dh v 2 a 8 h 8 dt Here h h 0 is the instantaneous distance of the meniscus above the pool level. The pressure difference at the pool level, p1, and at the top of the capillary (just under the meniscus) , p2, is 2 cos p1 p 2 Thus, 2 dh 2 cos a gh dt a 8h a gh Or, separating the variables, 8 h dh 8 h d h dt 2 2 ga 2 cos ga h 0 h g a h For integration, it is also continent to rearrange the terms in the rhs h0 h h0 h0 h dh d h 1 dh h0 h h0 h h0 h Integration gives 8 h h 0 lnh 0 h t c 2 ga The constant of integration c can be determined from initial condition, h 0 at t 0 . Hence, 8 0 h 0 ln h 0 c 2 ga Finally, h 0 8h 0 h0 8 h t h h 0 ln ln 2 2 ga h 0 h ga h 0 h h 0 Or, introducing 8h 0 , we obtain 2 ga h0 h t ln h0 h h0 As h h 0 , h/h0 t ln h0 h0 h t h h 0 1 exp For water in a glass capillary of 0.1mm radius, t/τ 12s For this solution, we assumed the steady Poiseuille flow profile. This assumption is not true until a fully developed profile is attained, which implies that our solution is valid only for times a2 t For water in a capillary tube of 0.1mm radius, a 2 ~ 10 2 s Lecture 16: Non-isothermal flow • Conservation of energy in ideal fluid • The general equation of heat transfer • General governing equations for a singlephase fluid • Governing equations for non-isothermal incompressible flow Conservation of energy in ideal fluid v 2 e -- total energy of unit volume of fluid 2 kinetic internal energy, energy e is the internal energy per unit mass 2 Let us analyse how the energy varies with time: v e . t 2 For derivations, we will use the continuity and Euler’s equation (NavierStokes equation for an inviscid fluid): div v 0 t v p v v t v 2 v 2 v 2 e e e 1: (differentiation of a product) t 2 t 2 2 t t t v e v 2 (use of continuity equation) v e div v t t 2 p (use of Euler’s e v 2 v v v e div v 2 equation) t Next, we will use the following vector identity (to re-write the first term): v2 v2 v v v v iv k kv i v k k v 2 2 and the 1st law of thermodynamics (applied for a fluid particle of unit mass, V=1/ρ): p 1 d e T d S p d T d S 2 d Equation (1) takes the following form: v2 v 2 S p v 2 e v v p T e div v 2: t 2 2 t t 2 (use of 2 2 v S v p continuity v v p T e div v 2 t 2 equation) We will also use the enthalpy per unit mass (V=1/ρ) defined as h e p dh de dp p 2 d T dS dp dp d h T dS Equation (2) will now read v2 v 2 S v 2 e v v h Tv S T h div v 3: t 2 2 t 2 v 2 S div v h T v S t 2 If a fluid particle moves reversibly (without loss or dissipation of energy), then d S S v S 0 dt t Finally, v 2 v 2 conservation of energy e div v h for an ideal fluid t 2 2 v 2 v h -- energy flux 2 In integral form, using Gauss’s theorem v 2 v 2 v 2 e dV div v h dV v n h d S t V 2 2 2 V S v 2 v n e d S pvn dS 2 S S energy transported by the mass of fluid work done by the pressure forces The general equation of heat transfer v 2 v 2 e div v h t 2 2 conservation of energy for an ideal fluid The conservation of energy still holds for a real fluid, but the energy flux must include (a) the flux due to processes of internal friction (viscous heating), v (b) the flux due to thermal conduction (molecular transfer of energy from hot to cold regions; does not involve macroscopic motion). For (b), assume that q (i) is related to the spatial variations of temperature field; (ii) temperature gradients are not large. Heat flux due to thermal q T conduction: thermal conductivity 12 The conservation of energy law for a real fluid v v e div v h v T t 2 2 2 2 viscous heating heat conduction We will re-write this equation by using (1) (2) (3) div v 0 t v p 1 v v t -- continuity equation -- Navier-Stokes equation p 1 d e T d S p d T d S d (4) d h d e 2 dp p 2 d T dS -- 1st law of thermodynamics d p -- 1st law of thermodynamics in terms of enthalpy h e p e, h and S are the internal energy, enthalpy and entropy per unit mass 13 v2 vivi vi vi v v (5) t 2 t 2 t t 2 v v2 (6) v v v v ivk kv i vk k v 2 2 (7) a div A A a ai Ai Ai ia iaAi div aA 1st term in the lhs: Differentiation of product (1+5) (2) v v v v v div v v t 2 2 t t 2 2 t (6) v2 p 1 div v v v v 2 (4) 2 2 2 2 v2 v2 div v v v p v 2 2 v2 v2 div v v v h Tv S v 2 2 14 2nd term in the lhs: Differentiation of product (3) (1) e S p e e e T t t t t t t S p S e div v T div v h div v T t t 15 LHS (1+2): v 2 e 2 v2 v2 S h div v v h T v S v t 2 2 t v2 S div v h T v S v t 2 (7) RHS: v2 div v h v T 2 LHS=RHS (canceling like terms): S v S v div v T t T 16 In the lhs, v vk i ik In the rhs, div v ivk ik vk i ik ik ivk Finally, vi general equation of S v S div T ik xk heat transfer t T heat gained by unit volume heat conducted into considered volume energy dissipated into heat by viscosity 17 Governing equations for a general single-phase flow div v 0 t -- continuity equation v v v p t -- Navier-Stokes equation vi S T v S div T ik xk t -- general equation of heat transfer + expression for the viscous stress tensor + equations of state: p(ρ, T) and S(ρ, T) 18 Incompressible flow To define a thermodynamic state of a single-phase system, we need only two independent thermodynamic variables, let us choose pressure and temperature. Next, we wish to analyse how fluid density can be changed. p ,T 2 d d p dT T p T d c 2 d p d T p c p -- sound speed S c 1 p a c , c 2 2 p T T 1 V 1 V T T p V p -- thermal expansion coefficient 19 1. Typical variations of pressure in a fluid flow, p v 2 2. Variations of density, v T c 2 3. Incompressible flow ≡ slow fluid motion, v 1 c 2 4. Hence, we can neglect variations in density field caused by pressure variations T 5. Similarly, for variation of entropy. In general, S S dS d p dT T p p T but for incompressible flow, c S dS d T dT T T p p S -- specific heat (capacity) c T T under constant pressure p p 20 For incompressible flow, the general equation of heat transfer takes the following form: v T c v T div T p t ik x i k Frequently, (i) the thermal conductivity coefficient κ can be approximated as being constant; (ii) the effect of viscous heating is negligible. Then, the general equation of heat transfer simplifies to T v T T t c p -- temperature conductivity 21 Boundary conditions for the temperature field: 1. wall: a) given temperature, T T q b) given heat flux, T n c) thermally insulated wall, T 0 n wall n 2. interface between two liquids: T T T1 T2 and 1 1 2 2 n n 22 Governing equations for incompressible non-isothermal fluid flow divv 0 -- continuity equation v p v v v t -- Navier-Stokes equation T v T T t -- general equation of heat transfer Thermal conductivity and viscosity coefficients are assumed to be constant. + initial and boundary conditions 23