Quantities in Chemistry The Relationship Between Mole and Molar Mass Mole Review • A Mole is a unit of measurement in chemistry. It represents 6.02 x 1023 of an entity. One mole of sodium is 6.02 x 1023 atoms of sodium. • The symbol for mole is “n”. The unit for mole is “mol” • 6.02 x 1023 is also known as Avogadro’s number. How do we measure out 1 mol? • Do you count out 6.02 x 1023 atoms in the lab? • Do you use special equipment? • Can you measure it as a volume? • Can you measure it as a mass? Amazing! 1 mole = amu of the element in grams For Example: 1 mol of H atoms = 1.01g 1 mol of O atoms = 16.0g 1 mol of C atoms = 12.01g 1 mol of Na atoms = 22.99g 1 mol of Au atoms =197.0g Molar Mass • Molar Mass (MM) is the mass (in grams) of one mole of a substance. • The formula for molar mass is MM m ass ( m ) m ole ( n ) • For example, Hydrogen’s molar mass = 1.01 g/mol Molar Mass of Compounds • The molar mass of a compound is equal to the sum of the molar masses of the atoms in the molecules or ions in the compound. • For example, the molar mass of water is: • MH2O= 2(MH) + (MO) = 2(1.01g/mol) + 1(16.0g/mol) =18.02 g/mol Example: Find the molar mass of H2CO2 • M H2CO2 = 2(MH) + (MC) +2(MO) = 2(1.01g/mol) + (12.00g/mol) + 2(16.0g/mol) =46.02 g/mol Atoms, Moles, Mass & Molar Mass Calculations • Example 1: Calculate the molar mass of magnesium if 0.330 mol has a mass of 8.02 g M=m/n = 8.02g/0.330mol = 24.3g/mol Atoms, Moles, Mass & Molar Mass Calculations • Example 2: Calculate the mass, in grams, of 2.00 mol of calcium atoms. M=m/n m=Mxn = 40.08g/mol x 2.0 mol = 80.2g Atoms, Moles, Mass & Molar Mass Calculations • Example 3: How many moles of gold are in 275.8g of pure gold? M=m/n n = m/M = 275.8g / 197.0 g/mol = 1.400 mol Calculating Number of Atoms • If you have a mass of the number of moles of an item, you can determine the number of molecules in an amount of an element using Avogadro’s number. • Avogadro’s number = 6.02 x 1023 particles/mol Atom Calculations Example 4: How many atoms of gold are in a 232.8g of pure gold? Step 1: Determine the number of moles n = m/M = 232.8g / 197.0g/mol = 1.182 mol Step 2: Using Avogadro’s number and the number of moles, determine the number of particles. N= n x NA = 1.182 mol x 6.02 x 1023 particles/mol = 7.12 x 1023 particles Step 3: Determine the number of atoms per particle, and multiply Atoms = (1atom/particle)(7.10 x1023 particles) = 7.10 x1023 atoms Atom Calculations Example 5: How many atoms of oxygen are in a 230.0g of oxygen gas? Step 1: Determine the number of moles n = m/M = 230.0g / 32.0g/mol = 7.188 mol Step 2: Using Avogadro’s number and the number of moles, determine the number of atoms. N= n x NA = 7.188mol x 6.02 x 1023 atoms/mol = 4.327 x 1024 atoms Step 3: Determine the number of atoms per particle, and multiply Atoms = (2 oxygens)(4.327x1024atoms) = 8.654 x1024 atoms of oxygen