Physical Characteristics Dr. Muanmai Apintanapong Physical Characteristics Considering either bulk or individual units of material. – Shape, size, volume, specific gravity surface area, bulk density and etc. Size Shape Weight Volume Shape and size Inseparable in a physical object = (sh, s) = Index sh = shape s = size Other applications = (sh, s, o, p, f,…) Y = b1X1+b2X2+b3X3+b4X4+b5X5 Irregular in shape Seeds, grains, fruits and vegetables are irregular in shape important to know what criterion should be used to decide when adequate number of measurements has been made to define the form of object. Griffith (1964) : related volume (V) to their axial dimension (a) V = a1b1 a2b2 a3b3 … anbn log V = b1 log a1 + b2 log a2 +….+ bn log an Criteria for describing shape and size Size : a representative dimension In fruit and cereal: 3 main projected area – a = length – b = width – c = thickness Average dimension Arithmatic mean size length width thickness 3 Geometric mean size (length width thickness)1 3 Size based on volume V De De (6V )1 3 6 3 Average dimension Size based on surface area S A Ds Ds (S A )1 2 2 Size based on projected area Ap Dp / 4 Dp (4 Ap ) 2 12 Measuring Grain Dimension Grain Type very long long medium short Length (mm) > 7.5 > 6.5 < 7.5 >5.5 < 6.5 < 5.5 Physical Properties>>shape The concept of shape factor – Geometric dimensions (L,W,T) of various objects are plotted against their volumes, surface areas or projected areas – The slope of regression line yields shape factor (α) V αv LWT SA αSA (LWT)2/3 Ap αAp (LWT)2/3 Example Axial dimension (cm) Weight (g) Volume (cm3) a b c apples 7.0 6.76 5.64 145.5 180.3 potatoes 8.2 7.2 5.3 204.0 184.0 tomatoes 6.45 5.92 4.72 127.3 126.2 Determine: v, density, equivalent diameter of sphere, average diameter, geometric mean diameter Charted standards Compare longitudinal and lateral cross section with the shapes listed on a charted standard Roundness Measure of sharpness of the corners of the solid Ap = largest projected area in natural rest position Ac = area of smallest circumscribing circle Roundness r Roundness NR r = radius of curvature as defined in figure R = radius of maximum inscribed circle N = total number of corners summed in numerator Roundness r Roundness R r = radius of curvature of the shapest corner R = mean radius of object Sphericity di Sphericity dc di = diameter of the largest inscribed circle dc = diameter of the smallest circumscribed circle Sphericity de Sphericity dc dc de = diameter of a sphere of same volume of object dc = diameter of the smallest circumscribed sphere (usually the longest diameter of object) Sphericity Vol of solid Sphericity Vol of circum scribed sphere Sphericity abc 6 3 a 6 1 1 3 3 bc 2 a 1 3 abc geom etricm eandiam eter Sphericity 6 m ajordiam eter a3 6 a = longest intercept b = longest intercept normal to a c = longest intercept normal to a and b 1 3 abc 3 1 a Shape factor () SAof spherehavingsam evolum e Shape factor( ) SAof object Measurement of axial dimension Use photographics enlarger to determine a, b, c Use shadowgraph Resemblance to geometric bodies Shape can be approximated by one of the following standard geometric shapes: – Prolate spheroid – Oblate spheroid – Right circular cone or cylinder Resemblance to geometric bodies Prolate spheroid – Volume V= – Surface area S= A prolate spheroid is a spheroid in which the polar diameter is longer than the equatorial diameter. a, b = major & minor semi-axes of ellipse of rotation 1 e = eccentricity 2 b 2 e 1 V = volume a S = surface area Resemblance to geometric bodies Oblate spheroid – Volume V= – Surface area S= An oblate spheroid is a rotationally symmetric ellipsoid having a polar axis shorter than the diameter of the equatorial circle whose plane bisects it. a, b = major & minor semi-axes of ellipse of rotation 1 e = eccentricity 2 b 2 e 1 V = volume a S = surface area Resemblance to geometric bodies Frustum of right cone – Volume V= – Surface area S= r1 & r2 = radii of base & top h = altitude A cone that has its apex aligned directly above the center of its base. Right Circular Cylinder A right cylinder with bases that are circles. Resemblance to geometric bodies Estimation of V and S in this manner should be corrected. Correction factor is determined by finding actual volume and surface area experimentally and establish correction factor for the typical shape of each variety of product. Average projected area Camera set up for recording the criterion area (above left) of fruits and vegetables for several orientations. Average projected area Based on Theory of Convex body (Bannesen and Fenchel, 1948) – Sphere: V 6 D 3 , S D 2 2 3 D V 6 1 3 3 S 36 D 2 2 – Nonsphere: V2 1 3 S 36 Polya & Szega (1951) Assume averaged projected area of convex body = ¼ of surface area For sphere: V2 1 , S 4 Ap 3 S 36 2 V 1 3 36 4 Ap Ap 1.21V 2 3 1 9 3 K 1.21 16 For nonsphere: K 1.21 Volume and Density Platform balance method: for large objects such as fruits and vegetables wt. of displacedwater V wt. densityof water wt. in air sp. gr. of water specific gravity wt. of displacedwater Example Assuming a specific gravity of 1.0 and a weight density of 62.4 lb/ft3 for water, using a platform scale method, the volume and specific gravity of an apple was determined as follows: – Weight of apple in air = 0.292 lb – Weight of container+water = 2.24 lb – Weight of container+water+apple submerged = 2.61 lb – Weight of displaced water = 2.61-2.24 = 0.37 lb Specific gravity balance For smaller objects such as small fruits, peas and beans, kernels of corn, etc. Specific gravity balance If solid is heavier than water: V wt. in air wt in water wt. densityof water wt. in air SG of water specific gravity wt . in air wt in water If solid is lighter than water (attach another solid as sinker) Wa object SG of water specific gravity W W both W W sin ker w a w a Wa = wt. in air Ww = wt. in water Specific gravity gradient tube Fast and accurate Ex: toluene & CCl4 (sp. gr. 0.87-1.59) Measure the height after object reaches equilibrium and calculated and compared with calibration curve. Air comparison pycnometer The density of a solid in any form can be measured at room temperature with the gas comparison pycnometer. The volume of a substance is measured in air or in an inert gas in a cylinder of variable calibrated volume. For the calculation of density one mass measurement is taken after concluding the volume measurement. Air comparison pycnometer Pycnometer method Specific gravity bottle and toluene Toluene (C6H5CH3) has the advantages of: – Little tendency to soak into the kernel – Low surface tension, enabling it to flow smoothly over kernel – Little solvent action on constituents of kernel especially fats and oils – High boiling point – Not changing its specific gravity and viscosity on exposure to atmosphere – Having low specific gravity Pycnometer method sg . gr. of tolueneat 20C wt. of grain specific gravity wt. of toluenedisplacedby grain Example Consider the volume measurement for a sample of 16 corn kernels coated with Pliabond – Weight of sample = 4.4598 g – Weight of pycnometer = 55.6468 g – Weight of pycnometer+toluene = 78.2399 g – Weight of pycnometer+toluene+sample = 79.6226 g – Weight of pycnometer+water = 81.7709 g Porosity Void volume or pore volume (empty space) relative to total volume volum eof void porosity total volum e volum eof void void ratio volum eof solid void ratio porosity porosity f (m oisturecontent, particlesize) Porosity tank V2 void volum e V1 Example To determine the porosity of dry shelled corn, tank 2 of the apparatus is filled with a sample of this corn to a bulk density of 47 lb/ft3. The pressure readings were P1 = 15.2 and P2 = 10.4 in Hg Porosity Porosity is also referred to as packing factor (PF): solid densityof particles densityof packing PF solid densityof particles Porosity and bulk density Weight and surface area W V SA KW 23 Surface area Leaf and stalk surface area Light planimeter Indirect estimation (projected area) Surface coating method – Estimated by the weight of coating material – Material is coated on grains and glass beads of known surface area (control). Surfaceareasample surfaceareaglass beads Wglassbeads Air permeability method Wsample Shape, Size and Area Using image analysis – The image analysis setup consists of a color CCD camera and a circular lighting chamber connected to a host Pentium II 400 MHz computer. Top view of the Image Analysis Set up CCD Camera Illumination Chamber Image Analysis Software Two image analysis software are available for extracting the dimensional feature of rice kernels 1. Image Tool 2: This program was developed at the University of Texas Health Science center at San Antonio, Texas and available from the internet (http://ddsdx.uthscsa.edu/dig/download.html). 2. Particle Image Analysis: This program was developed by Procure Vision AB Ltd., Stockholm, Sweden and the evaluation version is available from the internet (http://www.acoutronic.com).