Electrostatic Precipitator (ESP) Reading: Chap. 5 • • • • • • • • 2015/4/13 Ying Electrical migration Positive Electrical mobility Cation Man Corona discharge Love ESP theory Attraction Charging mechanisms Hell Ash resistivity Republican Flue gas conditioning War Power consumption Aerosol & Particulate Research Lab Yang Negative Anion Woman Hate Repel Heaven Democrat Peace 1 Electrical Migration • Coulomb’s law Electric Field q1q2 FE K E 2 r E FE (q=ne) q – Statcoulomb (stC): the charge that causes a repulsive force of 1 dyne when 2 equal charges are separated by 1 cm (3.3310-10C) – Unit charge: 4.8 10-10stC (1.610-19C) 2015/4/13 Aerosol & Particulate Research Lab 2 Millikan Experiment (Robert Millikan, US, 1868-1953; Nobel Prize Laureate, 1923) Hinds, Aerosol Technology, 1999 http://nobelprize.org/nobel_prizes/physics/laureates/1923/millikan-bio.html 2015/4/13 Aerosol & Particulate Research Lab 3 Electrical Mobility • Terminal velocity in an electrical field (electrical migration velocity/drift velocity) May the force be with the particles! FE FD qE (force balance) 3d pVTE Cc qECc VTE w qEB 3d p qCc VTE Z qB E 3d p (for Re < 1) Q: Difference between cyclone and ESP in terms of forces acting on the system? What’s the effect? Q: What is the physical meaning of electrical mobility? Q: When does a particle have a higher mobility? 2015/4/13 Aerosol & Particulate Research Lab 4 Q: How can we generate charges? Electron Molecule Corona Discharge Particle Positive Corona + - Negative Corona - + Step 1 - + Step 2 + - + + - + + Step 3 - - + Step 4 Electrode + - + Collection Plate + Electrode Ozone generation - http://www.mtcnet.net/~jdhogg/ozone/ozonation.html 2015/4/13 Aerosol & Particulate Research Lab Collection Plate 5 Electrostatic Precipitator Turbulent Flow with Lateral Mixing Model 1 1 (20) 2015/4/13 2 3 2 3 (12) (8) Aerosol & Particulate Research Lab 6 • Turbulent flow: uniformly mixing • Perfect Collection • The fraction of the particles removed in unit time = the ratio of the area traveled by drift velocity in unit time to the total crosssection • Deutsch-Anderson Equation dN 2RVTE dt 2VTE dt N R 2 R N (t ) 2V t exp( TE ) N0 R VTE Ac 1 P 1 exp Ac/Q: Specific Collection Area (SCA) Q Q: How to increase the efficiency? 2015/4/13 Aerosol & Particulate Research Lab 7 Q: An ESP that treats 10,000 m3/min of air is expected to be 98% efficient. The effective drift velocity of the particles is 6.0 m/min. (a) What is the total collection area? (b) Assuming the plates are 6 m high and 3 m long, what is the number of plates required? 6m Internal Configuration: self-review 2015/4/13 Aerosol & Particulate Research Lab 3m 8 Charging Mechanism: Diffusion Charging • Random collisions between ions and particles The total number of charges on a particle n d p kT 2e 2 d p ci e 2 N i t ln 1 2kT (ci ~ 2.4104 cm/s) Use esu, not SI units. The total charges on a particle q ne Q: Does q depend on time? Does q depend on dp? 2015/4/13 Aerosol & Particulate Research Lab 9 Charging Mechanism: Field Charging • Bombardment of ions in the presence of a strong field Total number of charges by field charging 2 Ed 3 p eZi N i t n 2 4e 1 eZi N i t (Zi ~ 450 cm2/stV•s) Saturation charge 2 Ed 3 p ns 2 4e Q: Is the charging rate dependent on particle size? On field strength? On time? On material? Aerosol Technology, Hinds, W. C., John Wiley & Sons, 1999. 2015/4/13 Aerosol & Particulate Research Lab 10 Comparison of Diffusion & Field Charging dp (um) 0.01 0.02 0.05 0.1 0.2 0.5 1 2 5 10 20 50 ndiff 0.10 0.30 1.1 2.8 7 21 48 108 311 683 1490 4134 nfield 0.02 0.06 0.40 1.6 6.5 40 161 646 4035 16140 64562 403510 ntotal 0.12 0.36 1.50 4.38 13.2 61.2 209 754 4346 16824 66052 407644 Zdiff 0.66 0.49 0.31 0.23 0.18 0.15 0.16 0.16 0.18 0.20 0.21 0.23 ZField 0.10 0.11 0.12 0.13 0.17 0.30 0.52 0.98 2.34 4.61 9.16 22.78 Z (stC•s/g) 0.76 0.60 0.43 0.36 0.35 0.45 0.68 1.14 2.52 4.80 9.37 23.0 Nit = 107 s/cm3 = 5.1 E = 5 KV/cm T = 298 K Number of Charges vs dp 106 Diffusion charging Field Charging 105 104 Q: Does collection efficiency increase as particle size increase (because of a higher number of charges)? n 103 102 101 100 10-1 10-2 0.01 0.1 1 10 dp (um) 2015/4/13 Aerosol & Particulate Research Lab 11 ELectrical Mobility vs dp Z (stC.s/g) 10 Diffusion charging Field Charging Combined Charging 1 Typical fly ash size distribution 0.1 0.01 0.1 1 10 dp (um) Q: If the ESP is used to collect the fly ash, how will the particle size distribution at ESP outlet look like? 2015/4/13 Aerosol & Particulate Research Lab 12 Resistivity/Conductivity • Impact of particles’ resistivity on ESP’s performance: 109 - 1010 ohm-cm is desired • Factors: temperature, composition • Flue gas conditioning Q: How does resistivity affect an ESP’s performance? 2015/4/13 Aerosol & Particulate Research Lab 13 Effects of sulfur content and temperature on resistivity Q: Is S in coal good or bad? 2015/4/13 Aerosol & Particulate Research Lab 14 Flue Gas Conditioning Water spray for cement kiln dust 2015/4/13 Aerosol & Particulate Research Lab 15 Effective drift velocity as a function of resistivity by measurement Use the same Deutsch-Anderson Equation with new we. Q: Estimate the total collection area required for a 95% efficient fly-ash ESP that treats 8000 m3/min. The ash resistivity is 1.6×1010 ohm-cm. 2015/4/13 Aerosol & Particulate Research Lab 16 Good for moderate collection efficiency (90% ~ 95%) 2015/4/13 Aerosol & Particulate Research Lab 17 High Efficiency ESP (>95%) Q: In designing a high efficiency ESP, a smaller drift velocity is to be used. Why? Matts-Ohnfeldt Equation k A 1 exp C we Q Use k = 1 for fly ash k = 0.5 or 0.6 for industrial category Rule of Thumb • Below 95%, use Deutsch-Anderson Equation • Above 99%, use Matts-Ohnfeldt Equation • Between them, use an average 2015/4/13 Aerosol & Particulate Research Lab 18 Power Consumption • Corona power PC ICVavg • Drift velocity kPC we AC Power density ~ 1-2 W/ft2 • Efficiency vs. Corona Power kPC 1 exp Q k = 0.55 for Pc/Q in W/cfs up to 98.5% 2015/4/13 Aerosol & Particulate Research Lab 19 Quick Reflection 2015/4/13 Aerosol & Particulate Research Lab 20