Laboratory and Field Evaluations of Corrosion Resistance Reinforcement Virginia Concrete Conference Bridge Breakout Session March 4, 2011 9:00—9:30 a.m. Presented By: Stephen R. Sharp, Ph.D., P.E. Overview • Information from several research projects – Corrosion Resistant Reinforcing Steel Testing • VCTIR – Stephen R. Sharp • VDOT – Materials Division – Larry J. Lundy , Harikrishnan Nair • Virginia Polytechnic Institute and State University – Cris D. Moen, Josiah Johnson, Brian Sarver – Route 123 Bridge over Occoquan River – Accelerated Test Method for CRR March 4, 2011 2 Overview continued • VDOT Bridge-deck reinforcing steel type is changing Coated Alloyed • Higher performance concrete needs higher performance steel rebar • Methodology for accepting CRR is important – testing for alloying – mechanical properties – corrosion resistance March 4, 2011 3 Why is it Important to Understand these Different Alloys? • Old Specification – One Rebar Grade – ASTM A615 Grade 60 – Differentiated by color • Black • Grey (galvanized) • Green/yellow/purple/etc. (epoxy-coated) • New Specification – Multiple alloy grades • ASTM A955 – multiple grades of stainless steel bar • ASTM A1035 – MMFX, etc. • AASHTO MP13 – Multiple grades of stainless steel clad bar March 4, 2011 4 Lessons Learned: Many Varieties Cost of Bars Range from $0.33 up to $3.50 / lb. March 4, 2011 5 Lessons Learned: Stainless Steel Cost • Alloyed steels are sensitive to alloy costs and some are more sensitive than others. • Steels with lower nickel and molybdenum provide greater price stability March 4, 2011 6 Publications on Corrosion Resistance • FHWA, VCTIR & others have sponsored a number of studies • Different bars exhibit different levels of corrosion resistance March 4, 2011 Improved Moderate High Corrosion Corrosion Corrosion Resistance Resistance Resistance MMFX2, 2101LDX (unpickled), 2201 Clad Bar, 2304 316LN, 304, 2205 7 Lessons Learned: Visual Assessment of Different Bars Carbon steel MMFX2 Duracor • Different Types of Bars Can Look Similar March 4, 2011 8 Lessons Learned: Visual Assessment of A Single Bar Type The Same Type of Steel Can Look Very Different March 4, 2011 9 Lessons Learned: Manufacturers Markings N 32 2205 Same bar markings, yet different alloys March 4, 2011 10 Lessons Learned: Magnetic Response Bar MMFX2 Black 2101 2304 2205 Steel Mart./ Aus. Res† 0.16 Fer./ Dup. Dup. Pear. 0.85 0.91 1.3 N32 304 316 Dup. Aus. Aus. Aus. 2.7 >25 >25 >25 †Response measured using coating thickness gage 2205 316 March 4, 2011 11 Lessons Learned: X-Ray Fluorescence • Provides a means of quickly identifying the composition of rebar in the lab or field • Performed following Manufacturers Guidelines – Turn on x-ray fluorescence analyzer – Allow to warm up for 5 minutes – Perform Checks • If XRF checks, proceed with analysis • if not, calibrate instrument and recheck • Alloy Identification Within Seconds – longer analysis time for greater accuracy • Total test time (warm-up + calibration) – less than 10 minutes • Provides alloy type,% confidence of alloy ID, list % elements detected, and confidence limit per element detected March 4, 2011 12 Lessons Learned: Visual Bar Assessment Care must be taken when accepting bars at the jobsite based on visual assessment and markings. – A magnet can be used as a rough sorting method to differentiate between magnetic and nonmagnetic alloys. – Handheld XRF devices can be useful in determining alloy composition. – Industry should push ASTM to revise the standards that govern the bar markings and include a requirement that markings be added that indicate the type of steel. March 4, 2011 13 Lessons Learned: Uniaxial Tensile Test March 4, 2011 14 Lessons Learned: Elongation Bar MMFX Dura Black SS 2304 2205 N32 2 Corr Steel Clad Elong 8 10 12 19 20 28 39 (%) March 4, 2011 15 Lessons Learned: Percent Reduction in Cross-Section Bar Black SS Steel Clad Red.(%) 7.5 21.5 March 4, 2011 N32 35.8 MMFX 316 2 LN 38.5 48.5 Dura Corr 52.6 16 Relative Rib Area Measurements • ASTM A615 • Takes into account both the rib height and spacing Cord width measurement Rib spacing measurement Rib height measurement Bar diameter measurement March 4, 2011 17 Lessons Learned: Example of Influence of Relative Rib Area • Relative Rib Area Makes A Difference (From VTRC 04-R5) Black: Rr = 0.80, NX (clad): Rr= 0.53 March 4, 2011 18 Lessons Learned: Material Properties • Lesson Learned → Knowledge of the material properties and how each bar will interact with the concrete is important. – Alloying changes not only the corrosion resistance, but other material properties as well. – With several companies producing different types of bars, features vary and can result in different responses when loaded to failure • Differences in relative rib area • Debonding of clad from steel March 4, 2011 19 Lessons Learned: Costs • The initial cost of CRR is a function of the reinforcement specified and ranges from about the same as ECR to 3 times more. • The additional initial cost of solid stainless CRR is typically less than 5 percent of the total project cost. • The cost of one deck overlay far exceeds the extra cost of solid stainless reinforcement. March 4, 2011 20 Lessons Learned: ASTM A1035 • ASTM A1035-09 The chromium content range listed eliminates all candidate materials with a content greater than 10.9% March 4, 2011 21 Lessons Learned: ASTM A955 • ASTM A955-06a • A955-09b & A955-10 Loss of ASTM A276 decreased the number of UNS designated stainless steel products by nearly 93% March 4, 2011 22 Lessons Learned: Route 123 Bridge Deck 1.75”-2.25” Ave. Total Chloride, lb/yd3 • Uncracked ▪ 0.380 • Cracked ▪ 2.404 March 4, 2011 Resistivity, KΩ cm Half-Cell, mV vs CSE • No. of Points ▪ 38 • Median ▪ 57 • Mean ▪ 55 • Standard Deviation ▪ 16 • No. of Points ▪ 1149 • Median ▪ -92 • Mean ▪ -101 • Standard Deviation ▪ 51 23 Lessons Learned: Route 123 Bridge Deck continued March 4, 2011 24 Lessons Learned: Route 123 Bridge Deck continued March 4, 2011 25 Lessons Learned: Route 123 Bridge Deck continued March 4, 2011 26 Lessons Learned: Route 360 Over Banister River, Halifax County • Void between clad layer and black steel core March 4, 2011 27 Lessons Learned: Route 360 Over Banister River, Halifax County continued • Rust does not penetrate through the stainless cladding • Deep groove is present along the rolling direction, reducing clad thickness March 4, 2011 28 Lessons Learned: Route 360 Over Banister River, Halifax County continued • Average Clad Thickness 0.7-mm • Thinnest Value: 0.215-mm • Thickest Value (excluding stainless bulb area):1.351-mm March 4, 2011 29 Future Evaluation: Route 460 Over Route 29 Bypass, Campbell County • Placed Late 2001/Early 2002 • End protection evaluation? (From VTRC 04-R5) March 4, 2011 30 Summary • VDOT is implementing CRR • Visual assessment can not be relied on to determine bar type • Steel fabricator markings cannot be relied on to identify the type of steel. • Magnetic sorting provides a quick and easy method for differentiating between magnetic and nonmagnetic alloys. March 4, 2011 31 Summary continued • X-ray fluorescence provides a practical, and much needed, method for positively identifying bars. • Relative rib area should be monitored as it varies from producer to producer. • Uniaxial tensile tests provide the stressstrain behavior, elongation and reduction in cross-section upon fracture can significantly vary for different CRR alloys. March 4, 2011 32 Summary continued • Corrosion and mechanical testing of CRR is necessary to identify the most cost effective bars with acceptable properties. • Simple quality control measures need to be established to ensure VDOT receives the corrosion protection it needs • VDOT should evaluate using VTM for their acceptance criteria while pursuing a single CRR test method via AASHTO March 4, 2011 33 Thank You – Questions? Acknowledgements: Federal Highway Administration, VDOT Materials Division, VDOT Structure and Bridge Division, University of Virginia, Virginia Center for Transportation Innovation and Research, and Virginia Polytechnic Institute and State University