UNIT 5 – Stoichiometry & The Mole Chapter 10 – Chemical Quantities Chapter 12 – Stoichiometry Chapter 10 Chemical Quantities Anything in black letters = write it in your notes (‘knowts’) Some similar but slightly different terms… Atomic Mass - mass of an atom (a.m.u.) 1 C atom = 12.011 a.m.u. Molecular Mass - mass of a molecule (a.m.u.) 1 CO2 molecule = 12.011 + 2(15.999) = 44.009 a.m.u. Formula Mass - mass of a formula unit (a.m.u.) 1 MgO formula unit = 24.305 + 15.999 = 40.304 a.m.u. 10.3 – Percent Composition Percent Composition of a Compound mass due to atom(s) = x 100 total mass of compound Example: calculate the percent composition of oxygen in K2CrO4 Example: calculate the percent composition of oxygen in K2Cr2O7 ASSIGNMENT: Chapter 10 Worksheet #1 10.1 – The Mole A mole is a number of particles 1 mole = 6.02 x 1023 particles Avogadro’s Number A particle can be an atom, molecule, formula unit, ion, etc Mole is abbreviated as mol – no joke! Mole – latin for large structure How big is Avogadro’s Number? If you could travel at the speed of light, it would take you more than 100 billion years to travel 6.02 x 1023 miles. 6.02 x 1023 baseballs would cover the Earth to a height of several hundred miles. How big is Avogadro’s Number? A computer that can make 200 million counts per second would need almost 100 million years to count up to 6.02 x 1023 A stack of paper with 6.02 x 1023 sheets would be so tall that it would reach from here to the sun—not just once but more than a million times! How big is Avogadro’s Number? If 6.02 x 1023 dollars were divided among the 7 billion people on Earth, we would have enough money that each of us could spend a million dollars every minute, night and day, for as long as we lived an still have more than half of it left. …but where would we put all those dollars? What is the point of a mole? What is the point of a dozen? To count large numbers of particles easier. Yes, the mole was created to make things EASIER! You will have to be able to measure an amount of matter and convert to moles of that substance. The number of moles really tells you the number of particles (atoms, molecules or formula units). Atomic Mass – mass of an atom (a.m.u.) Molecular Mass – mass of a molecule (a.m.u.) Formula Mass – mass of a formula unit (a.m.u.) 6.02 x 1023 Molar Mass – mass of 1 mole of particles measured in grams The molar mass (in grams) equals the particle’s mass (in a.m.u.) Examples… 1 atom Na = 22.99 a.m.u. 6.02 x 1023 Na atoms (1 mol) = 22.99 g Na 1 formula unit NaCl = 58.44 a.m.u. 6.02 x 1023 NaCl formula units (1 mol) = 58.44 g NaCl 1 molecule H2O = 18.0 a.m.u. 6.02 x 1023 H2O molecules (1 mol) = 18.0 g H2O We will rarely talk about 6.02 x 1023 because it is large and inconvenient. Just say ‘1 mole’ instead of ‘6.02 x 1023’ The molar mass is used as a conversion factor between grams and moles. Remember conversion factors??? Conversion factors are equalities that can be used to convert from 1 unit to another. 12 inches = 1 foot 60 sec = 1 min know any others…? Conversion factors are set up so that units will cancel. Example: Convert 20.5 inches into feet. 12 inches = 1 foot 1 foot _________ 20.5 inches x = 1.708333… feet 12 inches = 1.71 feet “Multiply by the top, divide by the bottom.” Converting from moles to grams Molar mass of MgO 40.304 g MgO _________ 2.2 mol MgO x 1 mol MgO = 88.669 g MgO = 89 g MgO Converting from grams to moles Molar mass of MgO 1 mol CaCl2 _____________ 10.1 g CaCl2 x 110.986 g CaCl2 = 0.0910 mol CaCl2 ASSIGNMENT: Chapter 10 Worksheet #2 How to convert from grams to moles you need to calculate the molar mass, then use it as a conversion factor How to convert from moles to grams you need to calculate the molar mass, then use it as a conversion factor If you ever need to know the number of particles… use 1 mole = 6.02 x 1023 as a conversion factor EXTRA STUFF BEYOND THIS SLIDE… Say that an egg has a mass of 10 grams and bowling ball has mass of 5 kg Quantity 4 dozen eggs 4 mol eggs 4 dozen bowling balls 4 mol bowling balls Mass Apples can be measured in three different ways • At a fruit stand, they are often sold by the count. • In a supermarket, you usually buy apples by weight or mass. • At an orchard, you can buy apples by volume. By count: 1 dozen apples = 12 apples By mass: 1 dozen apples = 2.0 kg apples By volume: 1 dozen apples = 0.20 bushel apples Example: Use conversion factors to calculate how many apples are in 1 bushel? By count: 1 dozen apples = 12 apples By mass: 1 dozen apples = 2.0 kg apples By volume: 1 dozen apples = 0.20 bushel apples “Multiply by the top, divide by the bottom.” Example: What is the mass of 90 average-sized apples if 1 dozen apples have a mass of 2.0 kg? “Multiply by the top, divide by the bottom.”