Uses for Nuclear Material Half-Life is the required for of a radioisotope’s nuclei to decay into its products. For any radioisotope, # of ½ lives % Remaining 0 1 2 3 100% 50% 25% 12.5% 4 5 6 6.25% 3.125% 1.5625% Half-Life Half-Life 100 90 80 % Remaining 70 60 50 40 30 20 10 0 0 1 2 3 # of Half-Lives 4 5 6 7 Half-Life For example, suppose you have 10.0 grams of strontium – 90, which has a half life of 29 years. How much will be remaining after x number of # of ½ lives Time (Years) Amount years? Remaining (g) You can use a table: 0 1 2 3 4 0 29 58 87 116 10 5 2.5 1.25 0.625 Half-Life Or an equation! Half-Life Example 1: If gallium – 68 has a half-life of 68.3 minutes, how much of a 160.0 mg sample is left after 1 half life? 2 half lives? 3 half lives? mt = m0* (.5)n mt = 160mg * (.5)1 mt = 160mg * (.5)2 mt = 160mg * (.5)3 mt = 80mg mt = 40mg mt = 20mg Half-Life Example 2: Cobalt – 60, with a half-life of 5 years, is used in cancer radiation treatments. If a hospital purchases a supply of 30.0 g, how much would be left after 15 years? n = total time/half-life n = 15/5 = 3 mt = m0* (.5)n mt = 30g * (.5)3 mt = 3.75g Half-Life Example 3: The half-life of polonium-218 is 3.0 minutes. If you start with 20.0 g, how long will it take before only 1.25 g remains? mt = m0* (.5)n 1.25 = 20g * (.5)n 0.0625 = (.5)n ln(0.0625) = ln((.5)n) ln(0.0625) = n*ln(.5) 4= n 4*3mins =12 mins Half-Life Example 4: A sample initially contains 150.0 mg of radon-222. After 11.4 days, the sample contains 22.75 mg of radon-222. Calculate the half-life. mt = m0* (.5)n 22.75 = 150g * (.5)n 0.152 = (.5)n ln(0.152) = ln((.5)n) ln(0.152) = n*ln(.5) 2.72= n n = total time/half-life 2.72 = 11.4/half-life half-life = 11.4/2.72 half-life = 4.19 days Uses of Radiation Medical applications Radiation of cancer cells Radioactive tracers to detect disease Sterilization of equipment Commercial products (smoke alarms) Radioactive dating Radiation therapy High doses of radiation can causes the normal functioning of living cells to mutate and leads to abnormal growth and eventually cancer. VERY HIGH doses will kill cells – especially fast-growing ones like cancer cells Gamma ray treatment Radioactive Tracers in Diagnosis Used to follow the flow of a substance through the body. Pattern of colors/locations can tell doctors how well particular organs are functioning. Technetium-99 is one of the most common – used extensively in imaging Iodine-131 for thyroid function Thalium-201 for cardiac problems Flourine-18 for PET scans Sterilisation Sterilisation - Killing microorganisms on medical instruments using a strongly ionising source of radiation. Used on medical instruments while they are still within their packaging. Food can also be irradiated to increase shelf-life. Sterile syringe within its packaging Commercial products: Smoke detectors A radioactive source inside the alarm ionises an air gap so that it conducts electricity – americium-241, an alpha emitter Very long half-life In a fire, smoke prevents the radiation and therefore a drop in electric current which sets off the alarm. Radioactive Dating Radiocarbon dating: the ages of specimens of organic origin can be estimated by measuring the amount of cabon-14 in a sample. Radiocarbon dating Living material (for example a plant) contains a known tiny proportion of radioactive carbon-14. This isotope is produced when high speed neutrons (part of cosmic radiation) collide with nitrogen gas in our atmosphere. 14 7 N + 1 0 14 n 6 C + 1 1 p When organisms die, they no longer have a constant proportion of carbon-14. It decays by beta emission back to the stable nitrogen-14 with a half-life of about 5600 years. 14 6 C 14 7 N + 0 -1 β - Calculating ages Example: A piece of wood taken from a cave dwelling in New Mexico is found to have a carbon-14 activity (per gram of carbon) only 0.636 times that of wood today. Estimate the age of the wood. (The half-life of carbon-14 is 5730 years.) mt = m0* (.5)n 0.636 = 1 * (.5)n 0.636 = (.5)n ln(0.636) = ln((.5)n) ln(0.636) = n*ln(.5) 0.65= n 0.65*5730 = 3741.1 yrs Limitations of radiocarbon dating The dating process assumes that the level of cosmic radiation reaching the Earth is constant – corrected by using known ages of objects, esp trees (tree rings) Radiocarbon dating is limited to reasonably young samples no older than ~50,000 years because the amount of carbon-14 becomes to small to measure accurately Rocks and other very old objects are dated using isotopes with significantly longer half-lives. Potassium-40 decays to argon-40: half-life = 1.25 billion years Uranium-238 decays to lead-206: half-life = 4.47 billion years