CHAPTER 10 Chemical Quantities Before We Begin… a) b) c) d) I can write numbers in scientific notation. I can write numbers in standard notation. I can multiply numbers written in scientific notation. I can divide numbers written in scientific notation. Before We Begin… We need to review some scientific notation. Scientific notation is a way of writing very large and very small numbers. How to Write Numbers in Scientific Notation Always written as a coefficient multiplied by 10 raised to a power. 3.5 x 1034 coefficient power Examples: Write the following in scientific notation: a) 234560000 b) 0.00056974 c) 8524000000 d) 0.000000044258 How to Multiply in Scientific Notation To multiply numbers written in scientific notation you multiply the coefficients and add the powers. (2.35x1014) x (3.25x10-23) Multiply Add (2.35x3.25) x 1014+-23 How to Multiply in Scientific Notation To multiply numbers written in scientific notation you multiply the coefficients and add the powers. (2.35x1014) x (3.25x10-23) Multiply Add Answer = 7.64x10-9 Examples: Multiply the following numbers: a) (1.23x104) x (4.56x107) b) (7.89x10-1) x (1.23x1010) c) (4.56x107) x (7.89x10-10) d) (1.23x10-11) x (4.56x10-23) How to Divide in Scientific Notation To divide numbers written in scientific notation you divide the coefficients and subtract the powers. (2.35x1014) ÷ (3.25x10-23) Divide Subtract 2 . 35 14 23 x10 3 . 25 How to Divide in Scientific Notation To divide numbers written in scientific notation you divide the coefficients and subtract the powers. (2.35x1014) ÷ (3.25x10-23) Divide Subtract Answer =0.72x1037 Examples: Divide the following numbers: a) (1.23x104) ÷ (4.56x107) b) (7.89x10-1) ÷ (1.23x1010) c) (4.56x107) ÷ (7.89x10-10) d) (1.23x10-11) ÷ (4.56x10-23) Section 1 The Mole: A Measurement of Matter Section 1 Learning Targets 10.1.1 – I can describe methods of measuring the amount of something. 10.1.2 – I can define Avogadro’s number as it relates to a mole of a substance. 10.1.3 – I can distinguish between the atomic mass of an element and its molar mass. 10.1.4 – I can describe how the mass of a mole of a compound is calculated. Measuring Matter You often measure the amount of something by one of three different methods – by count, by mass, and by volume. Example: If 0.20 bushel is 1 dozen apples and a dozen apples has a mass of 2.0kg, what is the mass of 0.50 bushel of apples? What Is a Mole? Mole (mol) – 6.02x1023 representative particles of that substance (SI unit for measuring the amount of something). Avogadro’s number - 6.02x1023 named after Amadeo Avogadro di Quarenga (1776-1856) A mole of any substance contains Avogadro’s number of representative particles, or 6.02x1023 representative particles. Converting Number of Particles to Moles You can use Avogadro’s number as a conversion factor. Example: How many moles is 2.80x1024 atoms of silicon? Converting Moles to Number of Particles The reverse also works. Example: How many molecules are in 5.6 moles of NO2? The Mass of a Mole of an Element The atomic mass of an element expressed in grams is the mass of a mole of the element. Molar mass – the mass of a mole of an element. Find the element on the periodic table and the mass that’s listed is the mass of one mole. The Mass of a Mole of a Compound To calculate the molar mass of a compound, find the number of grams of each element in one mole of the compound. Then add the masses of the elements in the compound. Example: What is the mass of 1.00 mol of sodium hydrogen carbonate? Section 2 Mole-Mass and Mole-Volume Relationships Section 2 – Learning Targets 10.2.1 – I can describe how to convert the mass of a substance to the number of moles of a substance, and moles to mass. 10.2.2 – I can identify the volume of a quantity of gas at STP. The Mole-Mass Relationship Use the molar mass of an element or compound to convert between the mass of a substance and the moles of a substance. Example: Find the mass, in grams, of 4.52x10-3mol of C20H42. The reverse is also true. Example: Calculate the number of moles in 75.0g of dinitrogen trioxide. The Mole-Volume Relationship Avogadro’s hypothesis – states that equal volumes of gases at the same temperature and pressure contain equal numbers of particles. Standard temperature and pressure (STP) – means a temperature of 0°C and a pressure of 101.3kPa or 1 atmosphere (atm). At STP, 1 mole or 6.02x1023 representative particles, of any gas occupies a volume of 22.4L Molar volume – the 22.4L of a gas. Calculating Volume at STP 22.4L = 1 mol at STP provides a nice conversion factor. Example: What is the volume of 3.70 mole N2 at STP? Example How many moles are in 102 L of carbon dioxide, CO2? Calculating Molar Mass from Density Different gases have different densities and is usually measured in g/L so we can calculate different things using density as a conversion factor. Example: A gaseous compound composed of sulfur and oxygen, which is linked to the formation of acid rain, has a density of 3.58 g/L at STP. What is the molar mass of this gas? The Mole Road Map A helpful tool to figure out easily which conversion factor to use. This can also be found on page 303 in your Chemistry book