Welcome @ Bruface Universite Libre de Bruxelles Dept Water Pollution Control Environmental Technology ChimH409 (2-0-1) Michel Verbanck mikeverb@ulb.ac.be 2012 A follow-up to the course: Environmental Pollution (ChimH302) • Presented the main environmental issues • with a chemistry viewpoint • with a relatively wide perspective regarding intervention strategies • crossing all three environmental compartments Universite Libre de Bruxelles School of Bioscience Engineering (EIB) Environmental Technology (2-0-0 visit) Michel Verbanck mikeverb@ulb.ac.be 2012 Delegates: please provide your coordinates Course structure Part 1. Introduction (incl. generic methods) Part 2. Air pollution control engineering Part 3. Water & wastewater treatment Part 4. Solid and hazardous wastes Reading recommendations for the course “Environmental Technology” (ChimH409) Reference textbooks [1] Baumbach G. (1996). Air quality control. Springer-Verlag, 490p. [2] Metcalf & Eddy (2003) Wastewater engineering: treatment, disposal, reuse. McGrawHill, 4th edition. [3] Freeman H.M. (1998). Standard handbook of hazardous waste treatment and disposal. McGraw-Hill, 2nd edition. Valid general information can also be found in: [4] Masters G.M. & Ela H.P. (2008) Introduction to environmental engineering and science. Prentice-Hall Engineering, Upper Saddle River, NJ, 3d edition, 625p. [5] Kiely G. (1998). Environmental Engineering, McGraw-Hill, 1st edition, 1008p. access to the course slides through the Dept Web page: Password: Depoll13 Part 1. Introduction, methods, toolboxes • brief overview of earlier course (compartments, scales, sustainable development & resources) • materials balance analysis: its relevance in environmental diagnostic • an introduction to industrial ecology: Kalundborg, DK • main principles of green engineering (green design) • Life-cycle-analysis (LCA / Ecobilan) • the spinash cannery example: exposed to stringent environmental regulations Part 1. Introduction, methods, toolboxes • brief overview of earlier course (compartments, scales, sustainable development & resources) • materials balance analysis: its relevance in environmental diagnostic • an introduction to industrial ecology: Kalundborg, DK • main principles of green engineering (green design) • Life-cycle-analysis (LCA / Ecobilan) • the spinash cannery example: exposed to stringent environmental regulations Principles of green engineering * same product, same material components, BUT: . . making component disassembly much easier Principles of green engineering * same product, same material components, BUT: . . making component disassembly much easier . . revision of the manufacturing process . . revision of the mode of operation new water input wastewater wastewater collected Pretreatment Regeneration Diversion of regained water Posttreatment discharge to sewer Water management in a modern car-wash facility discharge to surface water Counter-Current Washing Material Flow Water Flow Principle: The cleanest product is washed with the cleanest water and the most contaminated product is washed with the dirtiest water. • The system leads to huge savings in water use. • It also allows to reduce costs in wastewater treatment implementation. Note: in environmental engineering DILUTION is generally one of your most worrying enemies. Principles of green design * same product, same material components, BUT: . . making component disassembly much easier . . revision of the manufacturing process . . revision of the mode of operation * identify material components of lesser polluting impact * product with identical functionality (service to customer) but totally reimagined & redesigned Alternative materials and formulations Paper industry paper inks can be reformulated so that they are easier to remove when paper is recycled Inks & pigments new inks without Cadmium Aeronautics replace cyanide baths for metal-plating by non-cyanurated baths Textile industry • use UV-desinfection instead of chlorine-based biocides • replace organic solvent by aqueous medium • dry cleaning can be performed using supercritical CO2 as a solvent (instead of highly-polluting perchloroethylene) dry cleaning of textiles can be performed using supercritical CO2 as a solvent (instead of highly-polluting perchloroethylene) Merits: has the density and the solvant capacity of a liquid; but has viscosity, and importantly the diffusivity, of a gas (occupies all available volume). Critical temperature is low (31°C) -> allows thermosensitive applications Non-inflammable, no odour, chemically inert. Let’s now consider the entire ‘life’ of a product Life-Cycle-Analysis (LCA / Ecobilan) Recently appointed as Environment & Safety Officer in a company Vegetable processing and canning 10 Tons / day net products How could I enforce up-to-date environmental management in the company ? • technical aspects . . internal to the plant . . external • regulatory aspects . . emission standards . . immission standards . . . Environmental regulations ? The activity of my canning company corresponds to NACE code 15.33 (not elsewhere classified) Set of local regulations WILL be written in the local language! Sectorial norm for vegetable-processing factories (Walloon Region, 2003) Pollutant Pathogens Temperature pH Settleable solids Total suspended solids largest size of TSS particles should be smaller than BOD 5 at 20°C COD oils & grease detergents (anionic, cationic & nonionic) Petrol-ether extractible hydrocarbons if discharged to surface water if discharged to the public sewer network disinfection if necessary 30 6.5 - 9 1.5 60 45 6 - 9.5 1000 2 mm 2 mm mg/l mg/l mg/l 60 360 not visually observable - mg/l 3 - mg/l - 500 units °C ml/l mg/l Annual tax due for a given wastewater discharge settled water 2hr If If toxins are present If smaller than 2000 E.H. (discharged to sewers or WWTP)