Carbon Cycle Carbon Carbon exists in the nonliving environment as: • Carbonic acid ( HCO3−) • Carbonate rocks (limestone and coral = CaCO3) • Deposits of Fossil fuels Organic Carbon • Hydrocarbons: CH4 • Carbohydrate: CH2O Inorganic carbon • Carbon Dioxide: CO2 • Calcium Carbonate: CaCO3 Mandale Limestone Quarry Carbon Reservoirs Carbon reservoirs •The atmosphere -as carbon dioxide •The biosphere - as organic carbon (include fresh water systems and non-living organic material, such as soil carbon). •The oceans - as dissolved carbon dioxide and molecules like calcium carbonate ( including dissolved inorganic carbon and living and non-living marine biota). •The lithosphere as sedimentary rock like limestone and metamorphic rock like marble (sediments, Earth core including fossil fuels). Carbon Cycle Carbon is released into the atmosphere in several ways •Respiration by plants and animals. •Decay of animal and plant matter. •Combustion of organic material •Production of cement made from limestone •The ocean releases CO2 by diffusion into the atmosphere. •Volcanic eruptions and metamorphism Carbon is taken from the atmosphere in several ways • Photosynthesis. • The oceans when the seawater becomes cooler, more CO2 dissolve and become carbonic acid. • In the upper ocean areas organisms convert reduced carbon to organic molecules, or carbonates. Photosynthesis sunlight 6CO2 + 12H2O + ---------->C6H12O6 + 6 O2 Chlorophyll Respiration C6H12O6 + 6O2 --> 6CO2 + 6H2O + usable energy(ATP) Combustion or Oxidization of hydrocarbon CH4 + 2 O2 --> CO2 + 2 H2O + energy Human Impacts on the Carbon Cycle The burning of fossil fuels has a serious impact on the carbon cycle. Fossil Fuel 86% of global primary energy consumption is fossil fuels. Fossil Fuels • Petroleum • Natural Gas • Coal CO2 Concentration Pre-Industrial value: 280 ppm (600 billion tons) Current value: 400 ppm (840 billion tons) Critical value: 560 ppm (1200 billion tons) Keeling Curve Question: Why does line of the curve go up and down by about 5 ppmv instead of in a straight line? What process is occurring at each number? Plant Respiration Animal Respiration Photosynthesis Decay of plant litter Decay of animal wastes Carbon Cycle Summary C changed from C changed to CO2 C6H12O6 All organisms C6H12O6 CO2 Decay bacteria, Fungi Organic Carbon Organic Carbon Process Organism Photosynthesis Green Plants, Algae, some bacteria Respiration Decomposition Combustion Dissolution (Dissolved) Lithification Eruption of volcanos N/A Burning N/A In water N/A Forming rocks N/A Gas from volcanos CO2 CO2 CO2 Carbonic acid Plant and animal remains Fossil fuels CaCO3 Calcium carbonate Limestone, Marble Limestone, Marble CO2 Part II: The Carbon Reservoirs On a global scale , carbon moves between four major reservoirs (also called carbon Atmosphere sinks). These reservoirs include ______________________, Ocean Biosphere ______________________,______________________, and Lithosphere __________________________. Lithosphere Which reservoir contains the most carbon? _______________. Part III: The Biological (Biotic) Processes 1. Photosynthesis is a process that takes place in organisms containing pigments capable of capturing the energy of light. The main photosynthetic pigment is the green pigment called chlorophyll found in green plants, algae, and Cyanobacteria. Organisms Carbon dioxide with this pigment are able to remove ___________________________ from the Water atmosphere and combine it with ________________ in the presence of chlorophyll and Glucose sunlight making ____________________ (energy storage molecules) and releasing the Oxygen gas _________________ to the atmosphere. Complete the generalized equation: Sunlight C6H12O6 6 O2 12 H O 6 CO 2 2 ________ + ________ --------------------> ________ + ________ Chlorophyll 2. Cellular respiration is a process that takes place in cells that releases the chemical energy stored in larger molecules to be restored in small molecules that cells can use. Glucose The process takes the larger energy storage molecule called __________________ Oxygen and combines it with __________________ from the atmosphere. This releases the ATP chemical energy that is captured by the small energy molecules called ____________ carbon dioxide that can be used by cells. End products of cellular respiration are _______________ water and _________________ which is released into the atmosphere. Complete the generalized equation: ATP 6 CO2 C6H12O6 6 H2O 6 O2 __________ + __________ --------------------> _________ + __________ + __________ Part IV: The Inorganic (abiotic) Processes 1.The burning of any organic matter form fossil fuels to forests rapidly releases the Carbon dioxide carbon stored in its molecules as the gas _______________________ to the atmosphere. Carbon dioxide 2. Carbon as the gas _____________________ readily dissolves into bodies of water from ponds to oceans. This gas readily combines with water molecules to form an acid Carbonic Acid called _______________________ often lowering the pH of the water. 3. Aquatic organisms that protect themselves with shells combine the gas Carbon dioxide Calcium carbonate _____________________ with the mineral calcium making _____________________, the material that forms its shell. When these shelled organisms died, their shells rain down to the bottom of the lake or ocean collecting in deep layers as sediment. Slowly, the shells are compressed into sedimentary rock in a process called Limestone _________________________ 4. Over geologic time, sedimentary and metamorphic rock containing carbon are subducted, melted and rise toward the surface of the earth as magma and gases Carbon dioxide like _________________________ which are released into the atmosphere when Erupt volcanos ______________________.