Aerobic and Anaerobic Reactor Configurations Biochemical Environment Aerobic Conditions: Oxygen is used as electron acceptor Anoxic Conditions: Nitrate is the electron acceptor Anaerobic Conditions: absence of oxygen and nitrate and organic compounds are converted to biomass, CO2, CH4 and H2S. Organic matter + H2O CH4 + CO2 + NH3 + H2S+ new cell Why anaerobic Treatment Process stability Produced Methane can be used to produce energy Produced amount of excess sludge is about 10 % of aerobic treatment. Hence, reduction of waste disposal cost Low nutrient requirement (BOD/N/P is 100/5/1 for aerobic; 700/5/1 for anaerobic mo.s No air supplementation, so lower operational cost No off-gas air pollution Biodegradation of aerobic non-biodegradable Seasonal treatment is appropriate Possible disadvantages of anaerobic Treatment long startup Alkalinity should be sufficient Under mesophilic conditions, optimum temperature is 35 ºC Nitrification not possible Low kinetic rates at low temperature If COD < 1000 mg/L anaerobic treatment is not practical economically Effluent from anaerobic treatment is generally not acceptable for direct discharge and aerobic polishing step is needed. wastewater Waste ? Aerobic Bioreactor Equilization basin Anaerobic Bioreactor Anaerobic Reactor Configuratios Anaerobic Contact Stabilization: CSTR with cell recyle under anaerobic conditions. Well-mixed reactor suspended growth Before settling tank a gas separator is used to make settling easier Advantages: Simple and inexpensive Disadvantages: System is not stable for shock loading and toxic compounds Settling is problem Anaerobic Filters Attached growth systems In this type of reactor, waste enters in the bottom and flows through the rocks or plastic media used for biomass immobilization. Recirculation is used to dilute any toxic compound in the influent. The main limitations of reactor : accumulation of solids in the packing material (plugging). So, wastes containing high amount of suspended solids are not suitable for A.F channeling cost of packing material Table.1. Some Studies on the treatment of industrial wastewaters using A.F. Type of Tempr. wastewater (°C) Organic HRT (h) Loading Rate (kg/m3.d) Removal efficiency Sugar industry Distillery wastes Chemical process leachate 35-37 - 12-36 55% 35 15 72 90 37 12-15 22-30 80-90 37 0.2-0.7 30-40 d 90-96 Upflow Anaerobic Sludge Blanket Reactor (UASB) This type of reactor was developed to avoid the main problems of the anaerobic filter. Flow is in upward direction. Biomass settles in the bottom usually in the forms of granule. Advantages: High biomass concentrations. Hence high organic loading rates can be applied. so excellent COD removals due to high biomass concentrations. Compared to Anaerobic filter, wastewaters with higher suspended solid concentrations can be applied. Disadvantages: Sludge granulation is complex and not fully understood process Biomass escape at the effluent at higher loading rates hybrit reactors are used to avoid this problem) Fluidized and Expended Bed Reactors gas Effluent ORP, pH probes Recirculation pump High Recycle ratios are used to keep the particles in suspension Water-jacketed glass reactor carrier Glass beads wastewater In these systems microorganisms grow on small inert particles such as fine sand or activated carbon The rate of liquid flow and the resulting degree of expansion of the bed (10-25%) determine whether the reactor is a fluidized or an expanded (less expansion) bed reactor limitation: high and uniform upflow so high pumping cost Table 2. Some treatability studies using UASB Type of Influent wastewat COD er OLR Temperat HRT (h) (kg/m3/d) ure C Beer industry Agricultu ral waste Slaughter hause Paper industry Sugar industry 10001500 11 000 4.5-7 20-24 5 % COD removal Efficienc y 75-80 2-5 30 48 70-65 20003500 1000 4 30 19 85 5 - 49 75 400060000 20-25 28-32 - 92-95 Aerobic Treatment Systems Activated sludge Process (CSTR with/wo cell recycle) Contact Stabilization Oxidation Ditch Sequencing batch reactor (SBR) Extended Aeration Step feed Contact stabilization wastewater mixing Contact Basin Secondary clarifier Stabilization Tank Air Sludge waste Fill SBR No settling tank, no sludge pumping React Aerobic/anoxic/anaerobic cycles for nutrient removal process flexibility for bulking Settle sludge Tolerant to shock loading No washout Draw Idle Oxidation Ditch Nitrification and denitrification is also possible Typically operate in an extended aeration mode