Salinity of Lakes, Rivers, and Reservoirs Saline vs. Marine • Marine water mainly sodium chloride 35%o • Saline waters vary in dominant ions • Surface waters range from almost pure water to several times the ionic strength of sea water Saline lake Classification Name Concentration range Subsaline 0.5-3‰ Hyposaline 3-20‰ Mesosaline 20-50‰ Hypersaline >50‰ Some Saline Inland Waters Name Location Salinity Other Don Juan Pond Antarctica >400‰ Never freezes Lake Vanda Antarctica <400‰ Meromictic Lake Assal Djibouti (Affar) 348‰ -155m Dead Sea Jordan/Israel 337‰ -378m Great Salt Lake Utah, USA 50-270‰ Remnant of Lake Bonneville Mono Lake California, USA 50-99‰ Highly productive • Don Juan Pond (~400‰) • Lake Vanda –deep meromictic lake Lake Assal -Djibouti • Crater lake 155m below sea level. • Salinity 348 ‰ Dead Sea 337‰ and 378m below sea level Great Salt Lake Mono Lake Major Cations of Surface Waters Hard Water • Calcium • Magnesium • Sodium • Potassium Soft Water • Calcium • Sodium • Magnesium • Potassium Major Anions of Surface Waters comment on Tables 10-1, 10-3, & 10-4 Hard Water • Bicarbonate • Carbonate • Sulfate • Chloride Soft Water • Chloride • Sulfate • Carbonate Salinity due to: • Substrate (soil, geology) • Total precipitation • Ratio of precipitation to evaporation Comment on Table 10-2 Aral Sea Saline lakes form when • Outflow is restricted • Evaporation rate exceeds inflow or outflow • Inflow equals evaporation plus outflow Saline Lakes are different from hard water lakes • Mainly sodium chloride • Conductivity • Specific conductance Sources of ions • Direct weathering of rock (e.g. sodium chloride) • ReDox reactions involving iron, manganese, sulfur, nitrogen, phosphorus, and carbon • H+ from carbonic acid, acid rain, humic acids • Influence of groundwater Precipitation as a source of ions • Wind-borne salt • Dust • Acid rain Calcium • Essential element for most living things • Soft-water: low Ca • Hard-water: high Ca • Photosynthesis causes decline of Ca • Metabolism causes increase of Ca Interpret Figures 10-3, 10-4, & 10-5 Ca & conductivity in Lawrence Lake Ca in Wintergreen Lake Magnesium • Necessary for chlorophyll • Unlike Ca, very soluble and does not easily precipitate Interpret Figure 10-6 and compare with Figure 10-3 Magnesium in Lawrence Lake • Sodium, potassium and other minor cations also very soluble Sodium concentrations Monovalent: Divalent Cation Ratios • M:D < 1.5 favors diatoms • M:D > 1.5 favors desmids Anions, especially halides in surface waters • Examine Figure 10-8, chloride concentrations in Little Crooked Lake Chloride in Little Crooked Lake Origins of freshwater biota • Bacteria: homiosmotic • Protists: variable, most from marine forms • Plants: from terrestrial groups, few saline plants (e.g. Spartina). Some like Nymphaea primitive freshwater aquatic forms • Animals: Many from marine environments; however, insects from terrestrial groups