2011. 7. 15 서울특별시 제4회 물산업 신기술 발표회 하폐수 처리 MBR기술 최신 동향 KSMBR e - MBR ( eco friendly + energy saving ) 1 Contents Development in Wastewater Treatment 5 ECONITY Membrane 10 e-MBR Process 19 MBR Technology References 28 Water Reuse System 36 2 Ssangyong’s MBR Technology 연혁 3 우리나라 공공하수처리시설 방류수 수질기준 변경 연혁 초고도처리 필요 4 Development in Wastewater Treatment 5 Development in Wastewater Treatment 1970 1980 1990 2000 Future CAS (Conventional Activated Sludge) BNR (Biological Nutrient Removal) MBR (Membrane Bio-Reactor) 6 Conventional Activated Sludge Biological Nutrient Removal (A2O) Membrane Bio-Reactor 7 MBR ? Membrane BNR BOD, N, P Removal + SS, Coliforms Removal MBR = (Membrane Bio-Reactor) BNR Process Membrane Unit Biological N, P Removal Mechanism Physical Barrier for Separation Nitrification Denitrification P Release & Uptake BOD Removal SS Removal Coliforms Removal 8 Quality of Treated Water Effluent Parameter CAS BNR (A2O) MBR e-MBR BOD ○ ○ ◎ ◎ Biochemical Oxygen Demand - Organics indicator COD ○ ○ ○ ○ Chemical Oxygen Demand - Organics indicator SS ○ ○ ◎ ◎ Suspended Solids - Solids indicator ◎ Total Nitrogen - Nitrogen(nutrient) indicator - TKN(organic N+Ammonia) + NOx T-N × ○ ○ Remark T-P × ○ ○ ◎ Total Phosphorous - Phosphorous(nutrient) indicator - Poly P + ortho P Coliforms × × ◎ ◎ Coliform Bacteria Note : ◎ excellent, ○ good, × has no treatment mechanism 9 ECONITY Membrane 10 Principle of Hollow Fiber Membrane 11 Surface of ECONITY Membrane Outer Inner 12 Benefits of ECONITY Membrane ECONITY Hollow Fiber Membrane Technical Benefits Economical Benefits Manufacturing Process Stretching Method Porosity: High (above 77%) Pore Shape: Slit Type Permeability ↑, Screen Effect ↑ Manufacturing Cost ↓ Material HDPE(Hydrophilic Coating) Traditional Stability & Safety Chemical Resistance: Strong Life-time: Long Construction Cost ↓ Nominal Pore Size 0.4 μm (Micro Filtration) Complete Separation of Solids & Bacteria OD/ID/Wall Thickness 0.65/0.41/0.12 mm High Packing Density Footprint: Small Energy Consumption: Low Operation Flux 0.3~0.5 m3/m2/d Tolerance of Fouling: Strong Term of Chemical Cleaning: Long Membrane Replacement Cost ↓ Maintenance Cost ↓ Note : Membrane Life time is usually around 8~10 years and may vary subject to influent & operation conditions. 13 ECONITY Membrane Manufacturing Plant Location : Yongin, Republic of Korea 14 ECONITY Cartridge Module Permeate Handle 320W×396H×490L, Weight 7kg ECONITY Hollow Fiber Membrane 15 ECONITY Frame Permeate Air “M” Type for Air Distribution Uniformly Sludge Discharge Aeration KMS-6007CF (1,326W×3,233H×2,948L, Q=600m3/day) 16 Features of ECONITY Membrane System Energy Saving - Due to high packing density, improved air supply pipe & dual aeration(fine/coarse bubble) Easy to Clean & Maintain - Cartridge module is simple to insert/attach to/remove from frame - Light enough for one person to handle (cartridge module 7kg) - Cleaning in place (CIP) Maintenance cleaning : 1 time / 2 weeks Recovery cleaning : 1~2 times / year The Materials are Highly Resistant to Chemicals & Other Impacts 17 Quality Certification of Membrane by Public Procurement Service, Republic of KOREA Note : The original company name was ‘KMS.” The company had its name changed to “Econity” in 2009 18 e-MBR Process ( New Excellent Technology No.337 Certified by Ministry of Environment, Republic of KOREA ) 19 20 Features of MBR Process vs Conventional Type High Quality & Stable Effluent - Use of submerged hollow fiber membrane - Not affected by sludge settling characteristics Smaller Site (50% Reduction) & Lower Civil Work Cost - Does not need sedimentation, clarifier, disinfection, etc. Waste Disposal Cost Saving - Due to substantial sludge reduction Effluent Reuse - Perfect removal of SS & coliforms 21 Advantages of e-MBR vs other MBR Improved Nitrogen & Phosphorous Removal Efficiency - Pre & post denitrification with external carbon (optional) - Minimization of inhibition for nitrogen & phosphorous removal through DO control in Oxic 1 Energy Saving - DO recycle from oxic 2 to oxic 1 - Substantial energy saving during bio treatment in oxic 1 - Dual aeration(fine/coarse bubble) in membrane reactor realizes additional aeration saving (optional) 22 Advantages of e-MBR 23 High Quality Effluent (Unit : mg/L, Nr/mL) Effluent Parameter A2O, SBR and Other Conventional Type +Tertiary Treatment +Disinfection Typical Level (without chemical) Achievable Level (with chemical) BOD5 5 ~ 10 <2 <2 SS 5 ~ 10 <1 <1 T-N 5 ~ 15 < 15 < 10 T-P 0.5 ~ 1.5 < 1.5 < 0.5 Coliforms < 200 < 30 < 30 e-MBR Note : Typical levels of N & P depend on influent characteristics such as C/N, C/P. Lower levels of N & P can be achieved by using additional chemicals. 24 Required Installation Area e-MBR Process Conventional Process (A2O+Tertiary) Reducing around 1/2 25 e-MBR EPC Cost (80) Civil 30 Mechanic 25 Electric 15 Mem. 10 e-MBR (85) (95) (100) Civil 30 Mechanic 25 Electric 15 Mem. 15 Civil 50 Mechanic 30 Electric 15 Civil 55 Mechanic 30 Electric 15 Other MBR SBR + Tertiary A2O + Tertiary Note : Excluding land purchase costs 26 e-MBR EPC + O&M Cost (90) (100) (95) O&M 20 O&M 10 EPC EPC (100) O&M 10 O&M 15 EPC 75 e-MBR 80 Other MBR 85 SBR + Tertiary EPC 90 A2O + Tertiary Note : EPC cost + 20years O&M cost (assumed under the same condition, 10,000㎥/d) Including power, chemical, sludge treat. and membrane replace cost Excluding labor, repair and other miscellaneous cost 27 MBR Technology References MBR Bio + Membrane Upgrade KSMBR Improvement of Nutrient Removal Upgrade e-MBR Optimization of BNR for Ultimate Nutrient Removal Improvement of Using Energy by SSANGYONG & ECONITY 28 Applications of Ssangyong MBR Technology South Korea Okcheon STP 18,000㎥/day (Operating) Youngjong Songsan STP 30,000㎥/day (Constructing) Daegu Dalsung WWTP 25,000㎥/day (Operating) Jinhae Undong STP 10,000㎥/day (Constructing) Incheon Gongchon STP 65,000㎥/day (Constructing) MBR Technology (KSMBR) 160 Plants ECONITY Membrane 1, 100 Plants Songsan Green-City STP 84,000㎥/day (Designing) 29 After KSMBR Retrofitting Before Retrofitting (CAS+Tertiary) Project : Okcheon STP Capacity : 18,000 m3/day Location : Okcheon-gun, Chungcheongbuk-do, Korea 30 After KSMBR Retrofitting Before Retrofitting (CAS+Tertiary) Project : Daegu Dalseong Industrial Complex WWTP Capacity : 25,000 m3/day Location : Dalseong-gun, Daegu, Korea Reuse : Industrial Water 31 Track Record of Ssangyong MBR Technology Nation Site Capa. (㎥/day) S. Korea Sihwa Jeongok ect. STP S. Korea Daegu Dalsung Industrial Complex S. Korea Yeoncheon Baekhak Industrial Complex Site Nr Sum of Capa. (㎥/day) 400 31 3,403 WWTP 25,000 1 25,000 WWTP 500 1 500 STP 18,000 1 18,000 STP 510 23 2,930 Daechung Dam Area 2 STP 190 13 1,210 Namgang Dam Area 1 STP 80 12 870 Remark In Operation S. Korea Sewage Facilities Expansion Project In the Upper Stream of Dam Daechung Dam Area 1 S. Korea Youngjong Songsan STP 30,000 1 30,000 S. Korea Incheon Gongchon STP 65,000 1 65,000 S. Korea Jinhae Unngdong ect. STP 10,000 18 24,895 S. Korea Ansan Sihwa MTV STP 32,000 1 32,000 S. Korea Songsan Green-City STP 84,000 1 84,000 S. Korea Wonju Business-City ect. STP 18,000 52 79,200 S. Korea Cheonan Pungse Industrial Complex ect. WWTP 5,000 4 8,300 China Inner Mongolia WWTP 600 1 600 China Qingdao WWTP 50 2 70 China Beijing WWTP 200 1 200 China Yunnan STP 20 1 20 Russia Dekastri STP 300 1 300 N. Korea Pyeongyang STP 40 1 40 N. Korea Gangwon Goseong STP 400 1 400 Under Construction Designing Total 168 In Operation 376,938 32 KSMBR 33 KSMBR e-MBR 34 < 2007 Korea Environment Technology Awards > “KSMBR” won President Grand Award ! “KSMBR” Certified Green Technology by Ministry of Environment, Republic of KOREA 35 Water Reuse System 36 Water Reuse System Water Quality City Water e-MBR + RO Treatment for Water Supply / Desalination e-MBR Water in Use Conventional Treatment Water Source Reuse (High Quality) Reuse (General Quality) Discharge Sewage Time Sequence 37 Simplified Approach to Reuse Fresh Water Industrial Water Clean Water Using City Water RO Agricultural Water Gardening Water Treated Water Sewage e-MBR Cleaning Water Supplement Water Stream Maintenance 38 Concepts of Process for Reuse BNR + Sand Filter (+ Biological Activated Carbon) BNR + Microfiltration (+ Reverse Osmosis) Membrane Bio-reactor (+ Reverse Osmosis) 39 e-MBR + RO Process Sewage Reuse e-MBR RO Module Produced Water RO Module RO Module Concentrated Water Recycle or Waste No pre-treatment is required for RO process 40 Thank you 41 Attachment 1 e-MBR Energy Users Permeate Pump 7% Aeration (Bio+Mem.) 47% Misc. 2% inlet pump 3% Mixing 18% RAS Pump 23% Note : This is the result from pilot scale (60㎥/day) test and specific inlet loading condition, so it can be different according to plant scale and condition. In conventional MBR processes, aeration (bio aeration + membrane aeration) takes up over 70% of total energy used. E-MBR yields substantial energy saving, thanks to its efficient aeration process, from 70% to 50%. 42 Attachment 2 ECONITY Company Description Name : Econity Co., Ltd. Location : Yongin-Si, Gyeonggi-do, S.Korea Branch Office : Shanghai, Los-Angeles Established : Sep., 1st, 1998 No. of Employee : 100 persons Patents and New Environmental Technology Local Patents Membrane manufacture : 5 Module & System : 5 WWT Process : 3 Sludge Reduction : 1 MBR+RO Reuse : 1 International Patents New Technology US Patent registration 3 KSMBR Process for Adv. WWT (Membrane, Module, Air Diffuser) e-MBR Process for Adv. WWT 2Patents Application in China 2Patents Application in Europe 43 Note : The original company name was ‘KMS.” The company had its name changed to “Econity” in 2009 44 Note : The original company name was ‘KMS.” The company had its name changed to “Econity” in 2009 45