Annelies Aarts Jeroen Langeveld Marie-Claire ten Veldhuis Luuk Rietveld Is it necessary to collect local data to estimate the Event Mean Concentrations from Combined Sewer Overflow pollutants? Which location specific properties cause differences in EMC between CSO locations? 2 Event Mean Concentrations from literature search ◦ Individual CSO events ◦ European locations ◦ Information about the CSO location available The final database contained 278 CSO events measured at 24 catchments in 8 countries 3 Location specific characteristics Location River Population density Catchment size Land use Impermeable area Terrain Runoff coefficient Sewer length (collectors) Sewer slope Rainfall per year CSO frequency per year Rain event characteristics Rain depth Mean intensity Max intensity Rain duration Overflow duration Overflow volume Previous dry weather 4 Pollutants pH Dissolved oxygen Electrical conductivity Total suspended solids, volatile suspended solids COD, BOD, TOC Total nitrogen, ammonium, nitrate, nitrite Total phosphate, ortho-phosphate Chlorine, Sulphate Cupper, Lead, Zinc, Iron, Chromium, Nickel, Mercurium, Arsenicum Calcium, Sodium PAH E.Coli 5 Kruskal Wallis (non-parametric equivalent of ANOVA) to compare medians Spearman rank correlations (no assumption of linear relationships) to study the correlations between the pollutant EMC and the location specific properties 6 TSS COD BOD total-N NH4+ total-P Cd Pb Zn Median Mean 10% 90% 251 311 80 10 4 2 1 91 320 368 462 164 14 59 38 268 140 343 61 81 17 4 0.90 1.02 0.20 38 61 870 906 409 28 15 6.9 81 362 699 7 Kruskal Wallis test EMC of TSS, COD, BOD, total-N, total-P, Cd, Pb and Zn is significantly different in at least one location EMC of NH4+ is NOT significant different between the locations (insufficient data from the other pollutants) 8 Correlation matrix: location properties and EMC Area Impermeable area Annual rainfall TSS COD BOD total-N NH4+ total-P Cd Pb Zn 0.18 0.32 0.37 -0.16 0.36 0.15 -0.17 0.33 0.34 -0.26 9 Correlation matrix: rain event properties and EMC TSS Rain sum Rain duration COD BOD tot-N NH4+ tot-P Cd -0.35 -0.44 -0.43 -0.26 -0.54 -0.46 -0.60 -0.35 -0.58 -0.27 Mean intensity Max 0.32 0.16 0.60 Overflow Volume Duration 0.17 0.19 0.30 -0.18 0.23 0.21 0.33 0.22 PDWD 0.50 0.35 0.59 0.27 0.35 0.61 0.43 0.36 0.57 -0.33 -0.36 -0.41 Mean Flow Max Zn -0.33 0.46 0.24 0.39 0.47 0.51 Pb -0.27 -0.44 0.48 10 0.53 0.37 Correlation matrix: location and rain properties! A_i A A_i AR RS RD I_m AR RS RD I_m 0.93 0.12 -0.24 OV OD 0.64 1 1 0.68 0.14 0.39 0.50 0.49-0.23 1 -0.49 -0.31 0.43 1 0.51 0.18 OV 1 Q_x 0.38 -0.24-0.29 1 0.55 Q_m PWDP 0.55 0.64 -0.17 0.72 I_x OD Q_m Q_x 0.63 0.79 -0.33 0.82 0.50 0.35 1 I_x -0.33 0.60 0.65 0.88 0.75 1 -0.41 1 0.87 1 11 There is a significant difference of the pollutant EMC between locations but not for NH4+ Weak correlations between EMC and the location specific properties was identified Stronger correlations were observed between EMC and PDWD, rain duration and max rain intensity Correlation with not included sewer and land/area characteristics is possible but couldn’t be verified 12 This CSO database could (should) be ◦ the start of CSO data sharing between city’s, countries ◦ a direct source of information for sewer, CSO treatment designers ◦ a reference for future CSO monitoring campaigns ◦ a source of calibration data for wet sewage models ◦ other? Would you like to add/share your own CSO data? 13