Conclusions

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Concluding
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Statements
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A Shortcourse on Isotope Hydrology
Concluding
Statements
Prof. Jeff McDonnell
Richardson Chair in Watershed Science
Dept. of Forest Engineering
Oregon State University
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Related programs to consider in the
future

The International Atomic Energy Agency (IAEA)

The UNESCO-IAEA Joint International Isotope
Hydrology Program

The International Commission on Tracers

The International Association of Hydrological
Sciences PUB Initiative

IGBP Biospheric Aspects of the Hydrological
Cycle
© Oregon State University
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Web sites to check out

IGBP http://www.igbp.kva.se/cgi-bin/php/frameset.php
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GEWEX http://www.gewex.org/

WCRP http://www.wmo.ch/web/wcrp/wcrp-home.html

JWP http://www.igbp.kva.se/cgi-bin/php/frameset.php

PUB http://www.cig.ensmp.fr/~iahs/PUBs/PUB-proposal250602.htm

HELP http://www.nwl.ac.uk/ih/help/

BAHC http://www.pik-potsdam.de/~bahc/
Check these out on the web
© Oregon State University
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International journals where you will
see papers that explore this
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References - Textbooks

Clark, I. and Fritz, P. 1998. Environmental Isotopes in
Hydrogeology. Lewis Publisher (w/ web-link)

Kendall, C. and McDonnell, J.J. (eds.), 1998. Isotope
Tracers in Catchment Hydrology. Elsevier (w/ web-link)

Ferronsky, V. I. And Polyakov, V. A., 1982 .
Environmental Isotopes in the Hydrosphere. Wiley &
Sons.

Mazor, E., 1991. Applied Chemical and Isotopic
Groundwater Hydrology. Open University Press.
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References - Internet

USGS Isotope Interest Group Home Page
(http://wwwcamnl.wr.usgs.gov/isoig/)

ISOGEOCHEM Web Page with an E-mail Discussion
List in Stable Isotope Geochemistry
(http://geology.uvm.edu/geowww/isogeochem.html)
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Critical Thinking Is Inherent in Isotope
Hydrology
 Data
are scant
 Data
are insufficient
 Data
are wrong
 Hydrogeologic
systems are open
 Mathematical
solutions are
inexact
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Isotope Hydrology
Physical
Chemical
Photo: Kevin McGuire
Explicit solution of water and tracer mass balance
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Isotopic
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
Day 1




Morning: Groundwater Surface Water Interaction, Hydrograph separation
basics, time source separations, geographic source separations, practical
issues
Afternoon: Processes explaining isotope evidence, groundwater ridging,
transmissivity feedback, subsurface stormflow, saturation overland flow
Day 3



Morning: Introduction, Isotope Geochemistry Basics
Afternoon: Isotope Geochemistry Basics ‘cont, Examples
Day 2


Summary
Morning: Mean residence time computation
Afternoon: Stable isotopes in watershed models, mean residence time and
model strcutures, two-box models with isotope time series, 3-box models
and use of isotope tracers as soft data
Day 4

Field Trip to Hydrohill or nearby research site
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Why spend money on isotopes?
 Isotopes
can be powerful tools for testing
hypotheses about sources of water and solutes.
 While
isotope analyses are not CHEAP, they can
be much less expensive than being wrong.
 In
many cases, they are more useful
“fingerprints” of waters or solute sources than
other physical constituents because…
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Kendall (2001
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Isotopes are useful “fingerprints”
because…
Basics
1.
Many isotopes are relatively conservative in
reactions with matrix materials.
2.
Waters of different ages, recharge zones,
hydrologic/geochemical history, etc., are often
isotopically very distinctive.
3.
If the water from one area gets to another
area, it must be hydraulically and
hydrologically possible for it to get there
regardless of what the models predict.
© Oregon State University
Kendall
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Why Spend Money On Isotopes?

Isotopes can be powerful tools for testing hypotheses about
sources of waters and solutes.

In many cases they are more useful “fingerprints” of waters or
solute sources than other physical constituents because:
1) Many Isotopes are relatively conservative in reactions with
matrix materials.
2) Waters of different ages, recharge zones,
hydrologic/geochemical history, ect., are often isotopically very
distinctive.
3) If the water from one area gets to another area, it must be
hydraulically and hydrologically possible for it to get there,
regardless of what models predict.

While isotope analyses are not CHEAP, they can be much less
expensive than being wrong.
© Oregon State University
Why Do Environmental
Hydrogeologists Under-utilize
Isotopes?
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Possible Explanations:
1)
Awkward terminology: one of the major obstacles to using isotopes
is often the unfamiliar terminology, including:
**compositions are in terms of δ (pronounced delta), not ppm.
**units are 0/00 (spelled permil, per mil, or per mile.
**values of isotopic compositions are often negative number.
2)
Price? Not a problem. Many analyses are in the range of $50 to
$150 per sample.
3)
Complicated collection procedures? Not a problem: typically
procedure are no more complicated than for chemical analyses.
4)
Fear of the unknown.
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Fretwell’s Law
“Warning! Stable isotope data may cause
severe and contagious stomach upset if taken
alone.
To prevent upsetting reviewers’ stomachs and
your own, take stable isotope data with a
healthy dose of other hydrologic, geologic, and
geochemical information. Then, you will find
stable isotope data very beneficial.”
(Marvin O. Fretwell, USGS, pers. Comm. 1983)
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Thankyou
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