National Taiwan Normal University General Physics Experiment Handout Editing Group 12. Experiment: measurement of specific heat Purpose: Determine the specific heat of aluminum blocks at the temperature between 45℃ and 65℃ using the heat transfer phenomenon. Instrument: Equipment quantity Equipment quantity Plastic cup with lid 1 Electric kettle 1 set Digital thermometers (available 2 Iron clip 1 Aluminum blocks 1 Pipette 1 stopwatch 1 Tape (shared) Water (specific heat at 45℃ range -10℃~ 200℃) Electronic scales (shared) ~65℃ is 𝟒. 𝟏𝟖𝟔 𝐉 𝐠℃ ) Preview steps: Procedues: Preview 1. Before the experiment, Familiarizewith the principles and answer the questions in the appendix. 2. Measure the mass of the aluminum block and record it. 3. Boiled hot water: Place the electric kettle in the center of the experimental table and arrange the wires to keep the device safe; Fill the kettle with water more than the edge of the metal pan and put on the lid; Insert a thermometer in the middle of the lid and adjust the heat setting to medium, as shown in Figure 1. Around 5 minutes, if the thermometer shows that the temperature is higher than 80℃, reduce the heat to low (hot water above 50℃ will cause burns, be careful when handling it.) 4. Place the aluminum block in the plastic cupand add cold water until the aluminum block is completely covered.Mark the height of the water surface H in the plastic cup with a small piece of tape, and empty the cup. 5. Turn on the digital thermometer to record room temperature Tr every 30 seconds, 5 times in total. 6. Add hot water into the plastic cup (at least 70℃). The amount of hot water needs to reach the height H indicated in step 4. Put in a digital thermometer and close the lid tightenly. 7. After the temperature of the water drops to 65℃, record the time t it takes for the temperature decrease by 1℃. Plot the temperature-time curve of the system from 65℃ to 45℃. Record the mass of the water m1. 8. Warm up aluminum block: Put the aluminum block into the plastic cup and fill with hot water (at least 70 12 -1 National Taiwan Normal University General Physics Experiment Handout Editing Group ℃) to warm up the aluminum block. When the aluminum block reaches 70 ℃, use the iron clip to hold the aluminum block and remove the water from the cup. Repeat the step if needed. 9. Add hot water (at least 70℃) to the plastic cup until the water level reaches the same height H; Put in a digital thermometer and close the lid tightly. 10.When the temperature of the water drops to 65℃, record the time t it takes for the temperature to drop by 1oC. Plot the temperature-time curve of the system from 65℃to 45℃. Record the mass of the hot water m2 and the aluminum block m. 11.After the experiment is completed, repeat step 5 and measure the room temperature 5 times. Calculate the average Tr and the standard deviation △Tr with the room temperature data before the experiment. 12.Using the experimental data and the formulas from Appendix, Question 1, and Question 3, to determine the K value, and its uncertainty △K. Calculate sAl and kJ ) kg K its uncertainty △sAl. (The specific heat of water is Appendix - Principle: In steps 2 and 3, the temperature drop in the plastic cup is caused by heat exchange between the substance in the cup (ignoring the thermal capacity of the plastic cup at this stage) and the surrounding environment. According to Newton's law of cooling, the heat exchange is proportional to the temperature difference between the two, i.e. (1) −CdT = (T − Tr )dt where C is the thermal capacity (C1 or C2) and α is a proportional constant. The integral of (1) is − t T − Tr = (T0 − Tr )e C (2) where T0 is the initial temperature of the water in the cup. Take the log of (2), which makes it linear. Thus, obtain 𝛼 log(𝑇 − 𝑇𝑟 ) = log(𝑇0 − 𝑇𝑟 ) − ( log 𝑒)𝑡 (3) 𝐶 From this relationship above to find the value of K and its uncertainty △K, and determine the value of sAl, and estimate its uncertainty △sAl. Calculate the specific heat of the aluminum block from 45oC to 65oC. Questions: 1. Derive the mathematical formula of the specific heat of aluminum sAl using the measurable physical quantities: hot water mass m1 in step6, hot water mass m2 in step 10, aluminum block mass m, water specific heat cw, and the ratio of thermal capacity K=C1/C2. (C1 is the thermal capacity of water in step 6, C2 is the thermal capacity of water and aluminum blocks mixture in step 10, and C1, C2 are not included in the formula of aluminum specific heat.) 2. From (3), plot two curves of log(𝑇1 − 𝑇𝑟 ) vs time and log(𝑇2 − 𝑇𝑟 ) vs time. What is the physical meanings of the slope and the intercept of these two trend lines? And illustrate the way to find the value of K and its uncertainty △K from 12 -2 National Taiwan Normal University General Physics Experiment Handout Editing Group these two trend lines. thermometer metal pan Power Knob Figure 1 12 -3