Development of high performance 1280×1024 InGaAs SWIR FPAs detector at room temperature Jiaxin Zhang1,2, Wei Wang1,2, Zaibo Li1, Haifeng Ye1, Runyu Huang1, Zepeng Hou1, Hui Zeng1, Hongxia Zhu1, Chen Liu1, Xueyan Yang1, Yanli Shi1* 1 School of Physics and Astronomy, Yunnan University, Kunming 650504, China 2 Shanxi Guohui Optoelectronic Technology com., LTD Taiyuan 030006, China *Corresponding author. E-mail:ylshikm@hotmail.com (Yanli Shi) Abstract :The 1280×1024 In0.53Ga0.47As short wave infrared (SWIR)focal plane array (FPA) detector with planar-type back illuminated process has been fabricated. With indium bump Flip chip bonding techniques, the InGaAs photodiode array (PDA) was hybrid- integrated to the CMOS Readout Integrated Circuit (ROIC) with Correlated Double Sampling (CDS). The response spectral is 0.9μm-1.7μm. The test results show that the dark current density is 2.25nA/cm2 at 25℃, the detectivity D*is up to 1.1× 1013cm · Hz1 / 2 / W and the noise electron is as low as 48e- under CDS mode, the quantum efficiency (QE) is 88% at 1550nm, and the operability is more than 99.9%. Moreover, the dark current and noise electron have been studied theoretically in depth. The results indicate that the diffusion current is the main contribution of the dark current, and the ROIC noise electron is the main source of FPA noise. Keywords: InGaAs SWIR FPA, ROIC, Flip chip bounding, Dark current, Quantum efficiency 1. Introduction PIN InGaAs shortwave infrared (SWIR) focal plane arrays (FPAs) detectors have attracted extensive attention due to high detectivity [1], high quantum efficiency, room temperature operation, low dark current and good radiation resistance [2]. Furthermore, InGaAs FPAs detectors have wide applications in many fields, such as aviation safety [3], biomedicine [4], camouflage recognition [5], infrared night vision [6]. Recently, InGaAs SWIR FPAs detector is developing to reduce the pitch and enlarge the format [7.8]. Aerius Photonics reported the 1280×1024 20μm InGaAs FPA detector. The dark current density was 3.85A/cm-2 at 25℃, and the operability was 99.88% [9]. SCD developed the 1280×1024 with pitch10μm InGaAs FPA detector. The quantum efficiency (QE) at 1550nm was 80%. The dark current density was 0.5nA/cm2at 7℃, and the operability was 99.5% [10]. FLIR researched and developed 1280×1024 15μm InGaAs detector. The QE was up to 70%. The noise electron was as low as 70e- in middle gain at 20℃, and the operability was up to 99.5% [11]. For space application, it is critical to develop large format PIN arrays with small pitch and low dark current density at higher operation temperature. However, dark current density reported up to now is more than 3nA/cm-2 at room temperature, and lower dark current density is required to gain higher sensitivity which is very important for low light level applications. The lattice matching of In0.53Ga0.47As with InP substrate constitutes a significant advantage to limit defects densities and then reduces Shockley Read Hall (SRH) generation-recombination dark currents. The high crystalline quality material is the key point to reduce the dark current. Besides, Zn diffusion depth is another process that affects dark current. if Zn diffusion depth exceeds the InP/InGaAs hetero-interface, the InGaAs is damaged and dot defects are caused by Zn impurity. The dot defects become carrier recombination centers in InGaAs absorption layer, resulting in increasing dark current. Therefore, the Zn diffusion depth should reach InP/InGaAs herero-interface precisely [12]. In this paper, the fabrication of high performance 1280 × 1024 InGaAs SWIR FPA detector with pitch 15μm is presented. The device was processed with planar-type back illuminated process by flip chip bounding with indium bump. The EPI material quality was optimized and the Zn diffusion depth was controlled precisely to reduce dark current. The test results show that the dark current density is 2.25nA/cm2 at 25℃, the operability is up to 99.98%, and the QE is 88% at 1550nm. Moreover, the contribution of various dark current and noise electronic mechanisms are analyzed theoretically. 2. Fabrication of InGaAs SWIR FPA 2.1 EPI structure growth The typical PIN InGaAs/InP heterostructure was grown by Metal Organic Chemical Vapor Deposition (MOCVD) on 4 inches n+ type InP substrates. The EPI structure consisted of 0.4 μm n+InP buffer layer, 2.8 μm In0.53Ga0.47As absorption layer, and a 1 μm n-InP cap layer. Defect density of the EPI was 0.1/cm2. 2.2 InGaAs FPA fabrication The developed design of InGaAs FPA is common for all array formats. The active region is composed of PIN photodiodes and surrounded by common N-contact pixels to apply uniform polarization voltage. Firstly, a SiN layer was deposited on the EPI wafer by ICPECVD after preclean with 1%HCl, then the Zn diffusion hole was fabricated with SiN dry and wet etch, and Zn diffusion with Zn3P2 in tube, Fig. 1 is cross-section of Zn diffusion. After that, the second SiN layer was deposited on the wafer for Zn activation anneal and SiN dry etch for p-metal evaporation. Secondly, The InP and InGaAs around the active region was etched to exposed n+-InP buffer layer for n-type metal evaporation with E-beam, then P metal and n-metal were annealed for ohmic contact. Thirdly, the connect metal was deposited with E-beam, and then InP substrate was lapped and polished for anti-reflection coating (ARC) layer deposition, Fig. 2 is cross-section of PDA. Fourthly, indium bump evaporation and reflow, Fig. 3 is the In bump after reflow. During the whole process, the Zn diffusion depth was controlled to the InGaAs/InP hetero-interface precisely by optimizing the diffusion time and temperature. The contact resistance of P-metal and N-metal are 2.69×10-5Ω·cm2 and 2.81×10-7Ω·cm2, respectively. Finally, after wafer dicing, the InGaAs PDA was hybrid-integrated to CMOS ROIC with indium bump by flip chip bonding. The ROIC circuit adopts snapshot mode, supporting integrated readout (ITR) and integral simultaneous read (IWR) mode, and CDS mode. CDS mode is used to reduce KTC noise and FPN noise. Fig. 4 is the ROIC circuit. The packaged 15μm 1280×1024 InGaAs FPA detector was packaged with high vacuum integrity metallic package and themo electric cooler (TEC). Fig. 5 is the packaged FPA chip. Moreover, the smaller format 640×512 15μm InGaAs SWIR detectors with similar processing were applied in space exploration in 2019. Fig. 1. Cross-section of Zn diffusion Fig. 2. Cross-section of PDA Fig. 3. The In bump after reflow Fig. 4. The circuit of ROIC Fig. 5. Packaged FPA chip Fig. 6. The dark value versus exposure time Fig. 7. Histograms of the dark current at 33℃ 2.3 Test result With Pulse Instruments 7700 FPA test system and EMVA 1288 standard, we tested the electrical characteristics and spectral response characteristics of the detector. The operability is up to 99.98%. The response non-uniformity is 4.2%. The quantum efficiency is 88% @1550nm. The detectivity D * reaches 1.1 × 1013cm · Hz1 / 2 / W under CDS mode, and the readout noise electron is 48 e- under CDS mode. The dark current density is measured as low as 2.25nA/cm2 and 5.06fA/pixel @ 25℃,as shown in Fig. 6. Besides, the histogram of the dark current is shown in Fig. 7, which is from the third party, the mean dark current of pixels is about 10 fA/pixel at 33℃. Because of the high temperature, the result is different from what we measured. But both results indicate that the dark current is very low. The dynamic range is 64dB. The responsivity is 1.1A/W. Table1 is the performances compare with other detectors. Table1 Performance comparison of 1K×1KInGaAs FPA R & D unit Spectrolab[14] SUI[15] Dark current D* (nAcm-2) (cm·Hz1/2W-1) QE Operability 0.7@280K >1013 80% >99% 2@12.5℃ >1013 65% >99% FLIR[11] <1@15℃ >1013 70% >99.5 Aerius Photonics[9] 3.85@RT >1013 80% 99.88% SCD[10] 0.5@280K >1013 80% >99.5% <5@RT 5.3×1012 75% >99% 2.25@RT 1.1×1013 88% >99.9% SITP[8] This work 3. Performance analysis 3.1 Dark current Dark current is a key parameter which must be decreased to improve signal to noise ratio and minimize the noise equivalent power. Dark current is composed of diffusion current, generaterecombination current, tunneling current, surface leakage current [13]. Dark current density Jexp is 2.25nA/cm2 at -0.1V with EMVA1288 standard, as shown in Fig. 6. The dark current was measured on test cells for photodiode diameters varying from 6 μm to 200μm, as shown in Fig. 8. Diffusion current density Jdiff and generated-recombined current density Jgr are calculated with the Formulae (1) and (2)[13], respectively, Intrinsic carrier concentration ni is given by formula (3) and depletion width Wd is given by formula (4)[13]. The result is shown in Fig. 9. At -0.1V, the diffusion current density Jdiff is 1.82nA/cm2 and the generated-recombined dark current density Jgr is 0.39nA/cm2. Hence, the diffusion current density Jdiff is the main contribution of the dark current density. The generated-recombined dark current density Jgr is about one fifth of the diffusion dark current density. Consequently, the gap between Jtotal and Jexp is tunneling current density and the surface leak current density, but the gap becomes bigger with reverse bias increase, this is because tunneling current is linear with reverse bias, then Jexp increase faster than Jtotal with reverse bias increase. Besides, the dark current density can be expressed as formula (5)[14], where P is the pixel perimeter and A is the pixel area, Jb is the bulk current, and Js is the surface-related current. Fig.10 shows Jd vs. P/A taken from variable size test diodes at room temperature. Js, the slope of fitting line, is 0.3pA/cm, Jb, the intercept of fitting line, is 2.29nA/cm-2. Therefore, we could eliminate influence of surface leak current. The results indicate good surface passivation by SiN and precise Zn diffusion process. 𝑞𝑉 𝐽𝑑𝑖𝑓𝑓 = 𝑞𝑛𝑖2 𝐻(𝐵 + 𝐶𝑁𝑑 + (𝑁𝑑 𝜏 𝑆𝐻𝑅 )−1 ) (𝑒 𝐾𝑇 − 1) (1) 𝑞𝑉 𝑞𝑛 𝑊 𝑖 𝑑 𝐽𝑔𝑟 = 𝜏𝑆𝐻𝑅 [𝑒 2𝐾𝑇 − 1] (2) 𝐸𝑔 𝑛𝑖2 = 𝑁𝑐 𝑁𝑉 𝑒 −𝐾𝑇 𝑊𝑑 = [ (3) 1 2𝜀0 𝜀𝑠 (𝑉0 −𝑉) 2 𝑞𝑁𝑑 (4) ] 𝑃 (5) 𝐽𝑑 = 𝐽𝑠 𝐴 + 𝐽𝑏 where q is electric quantity, ni is intrinsic carrier concentration of InGaAs, H is thickness of InGaAs, B is radiation recombination coefficient, C is Auger recombination coefficient, Nd is doping concentration of InGaAs, τSHR is the SHR lifetime, V0 is the voltage of built-in electric field, V is the bias, k is the Boltzmann constant, T is temperature, Nc is effective conduction band density of states, Nv is effective valence band density of states, Eg is energy gap. All the parameters used are in Table 2. Table 2 Parameters used in calculation[13] Eg Nc Nv B C τSHR (cm-3) eV (cm-3) (cm-3) (cm3/s) (cm3/s) (s) InGaAs 2×1015 0.74 2.1×1017 7.7×1018 9.5×10-11 8.1×10-29 4×10-4 13.9 InP 2×1017 1.34 5.7×1017 1.1×1019 1.2×10-10 9×10-31 1×10-9 12.5 material Nd Fig.8. Dark current versus bias εs Fig.9. Dark current density versus reverse bias Fig.10. Dark current density versus P/A 3.2 Noise electron The noise electron of InGaAs FPA contains PDA noise, ROIC noise and the couple noise of PDA and ROIC. The PDA noise comes from thermal noise and the shot noise of dark current. the ROIC noise electron and FPA noise electron are measured under CDS mode and non-CDS mode, respectively. The results show the ROIC noise electron is 42e-, and the InGaAs FPA noise electron is 72 e- under non-CDS mode, while the ROIC noise electron is 20e- and the InGaAs FPA noise electron is 48e- under CDS mode. The thermal noise electron Nthermal and the shot noise electron Nin,shot were calculated with the formula (6) and (7)[13], respectively. 2𝐾𝑇 2 Nthermal = 𝑞2𝑅 𝑇𝑖𝑛𝑡 (6) 𝑑 𝐼 2 Nin,shot = 𝑞𝑑 𝑇𝑖𝑛𝑡 (7) where q is the electric quantity, k is the Boltzmann constant, T is temperature, Id is the dark current, Rd is the resistance of pixel, Tint is the integration time. The calculation results of thermal noise and the shot noise of dark current are about 14 e- and 11 e-, respectively. The PDA noise electrons are 25e- at room temperature. Compared with the actual measurement results in Table 3, it is revealed the PDA noise is the main contribution of FPA noise under CDS mode, while the ROIC noise is the main contribution of FPA noise under non-CDS mode operation. Table 3 Noise measurement results of FPA and ROIC mode ROIC noise FPA noise With CDS 20 e- 48 e- Without CDS 42 e- 72 e- 3.3 Detectivity D* The detectivity D*is up to 1.1×1013cm﹒Hz1/2/W and the signal noise ratio(SNR)is 64dB under CDS mode. But under non-CDS mode the detectivity D*is 4.2×1012cm﹒Hz1/2/W, and the SNR is 52 dB. According to the previous analysis of readout noise electron, the FPA readout noise electron under CDS mode is lower than that under non-CDS mode, which causes the SNR under CDS mode larger than that under non-CDS mode. Therefore, as shown in formula (7), the D* is higher under CDS mode than that under non-CDS mode. The ROIC noise is the main reason that causes the SNR and the detectivity D* lower. 1 𝑅 𝐷 ∗ = 𝑁𝐸𝑃 = 𝑉𝑉 √𝐴𝑑 ∆𝑓 𝑛 (8) Where NEP is the noise equivalent power, Rv is the response voltage, Vn is the noise voltage, Ad is the photo-sensitive area of pixel, Δf is the noise equivalent bandwidth. 4. Conclusion In summary, the high performance 15μm 1280 × 1024 InGaAs PIN short wave infrared detector was fabricated by optimizing the EPI material quality and the Zn diffusion depth. The results indicate that the dark current is as low as 2.25nA/cm-2 at room temperature. The response nonuniformity is 4.2%. The operability is more than 99.9%, the detectivity D*is up to 1.1×1013cm﹒ Hz1/2/W, and the SNR is 64dB under CDS mode operation. The calculated noise electron of PDA is 25e-, which is the main contribution of FPA noise. Owing to larger noise from ROIC under nonCDS mode, the detectivity is 4.2×1012cm﹒Hz1/2/w, and the SNR is 52dB. The test results show the ROIC noise is the main reason that causes the SNR and the detectivity D* lower under non-CDS mode. In addition, the theoretical calculation data of dark current shows that the diffusion current is the main contribution of dark current. References [1] H. J. Gao, Y. H. 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