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Water

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WATER
LEARNING OBJECTIVES
• Describe chemical tests for water using
cobalt (II) chloride and copper (II) sulphate
• Describe, in outline, the treatment of the
water supply in terms of filtration and
chlorination.
2
Uses Of Water
USES OF WATER
Water In Industry
As A Coolant Too
Water treatment process flow diagram
WATER
TREATMENT
Water treatment is any process that improves the quality of water to
make it more acceptable for a specific end use
Describe, in outline, the treatment of
*Sludge
Coagulants
Sludge
the water supply in terms of filtration
and chlorination
Raw Water
Screening
Coagulation
Flocculation
Sedimentation
Distribution
Storage
Disinfection
Filtration
Cl2
Sludge
*sludge = Wet muddy solid/semisolid
Screening
WATER
TREATMENT
Remove large solids like logs, branches and twigs, fishes…
Coagulation
Destabilization of stable suspension by the addition of chemicals (coagulants)
Colloidal suspensions are:
Describe, in outline, the treatment of
 negatively charged due to dissolved organic matter
the water supply in terms of filtration
 stable due to charge repulsion
and chlorination
- - - - - - - - -- -- - - - - -- -- - - - - - - - - -- -- -- Negatively charged colloids
(size < 1μm)
Addition of coagulants
(Fe2+, Al3+ …)
Neutralization
Neutralized particle
Flocculation and Sedimentation
WATER
TREATMENT
Flocculation: The process of particle aggregation
Sedimentation: Settling of large flocs
Describe, in outline, the treatment of
Collision
the water supply in terms of filtration
due to Brownian motion of
the medium or agitation
and chlorination
Neutralized particle
calm water
Flocculation
Coagulation, flocculation and sedimentation removes:
 dissolved organic materials or Natural Organic Matter
 suspended particles and inorganic precipitates such as iron
 between 27-84% of viruses and between 32 and 87% bacteria
(most bacteria and viruses are attached with NOM)
Sedimentation
Filtration
WATER
TREATMENT
The process of separating suspended particles/ particulate matter from a liquid
by forcing the liquid through a filter media
Two Major Types (based on filter media)
Describe, in outline, the treatment of
1. Sand Filtration
the water supply in terms of filtration
and chlorination
raw water
Raw water
Raw water
Mechanical
Adsorption
Lodging of large particles
Sticking to the filter media
sand
coarse sand
gravel
water out
Filtration
WATER
TREATMENT
2. Membrane Filtration
virus
bacteria
multivalent ions
monovalent ions
the water supply in terms of filtration
and chlorination
Raw water
Describe, in outline, the treatment of
Pure water
suspended solid
Ultra filtration
Reverse osmosis
< 1nm
(0.1μm – 0.01μm)
Micro filtration
(10μm – 0.1μm)
Nano filtration
(10nm – 1nm)
Sand Filtration Removes
 Suspended particulate matter
 Slow sand filtration also removes considerable amount bacteria, virus and protozoa
Chlorination
WATER
TREATMENT
 Used for disinfecting the water- i.e. the removal, deactivation or killing of
pathogenic microorganisms.

Describe, in outline, the treatment of
the water supply in terms of filtration
and chlorination
Chlorinating agents : Cl2(g), Ca(OCl)2 (calcium hypochlorite) and NaOCl (sodium hypochlorite)
Chemistry of chlorination (Cl2)
Chlorine gas + Water  Hypochlorous acid + Hydrochloric acid
Cl2(g) + H2O  HOCl (hypochlorous acid) + HCl
HOCl
H+ + OCl- (at 250C and pH7.5)
When a hypochlorite is used
NaOCl + H2O  OCl- (hypochlorite ion) + OH Together, HOCl and OCl- are referred as free chlorine
 HOCl and OCl- are both disinfection agents
 HOCl is 80-100 times more effective than OCl-
Chlorination
WATER
TREATMENT
Mechanism of Action
 Negatively charged hypochlorite ions damages the cell membrane
 Neutral HClO molecules penetrates the cell wall and disrupts the cell respiration
Describe, in outline, the treatment of
and DNA activity
the water supply in terms of filtration
and chlorination
Cl
H
O
Cl
Cl
O
-
Cl
-
O
O
Other uses of chlorination
It oxidize Fe, Mn, taste and odour compounds, remove colour and destroy H2S
Global water use
USES OF WATER
8% Residential
22% Industrial
70% Agricultural
Name some of the uses of water in
industry and in the home
Major residential uses of water
Toilet
24-32.6%
Faucet
20-27%
Shower
20-27%
Clothes washer
16-20%
Leaks +other
21-28%
Major industrial uses of water
USES OF WATER
Name some of the uses of water in
Thermal Power Plants
Wood and Paper Industry
Steel Industry
steam production and as
coolant
cooking, bleaching and
washing
cooling, concentrating the ore,
dust suppression…
Refineries
Distilleries
Textile Industry
cooling
malting, mashing and dilution
washing, dyeing, bleaching,
Fertilizer Industry
Leather and Sugar
Chemicals (e.g. H2SO4)
industry and in the home
World water crisis- Some facts
EFFECTS OF
WATER SCARCITY
844M
5000
40%
People
living without access to
clean water
Children
World’s Food
die everyday from water
related diseases
currently cultivated in
artificially irrigated areas
Discuss the implications of an
inadequate supply of water, limited to
safe water for drinking and water for
irrigating crops
55%
70%
Global Water Demand
Agricultural Production
increases by 2050
need to expand by 2050
World water crisis- Causes
EFFECTS OF
WATER SCARCITY
Water Pollution
Discuss the implications of an
Misuse and overuse
inadequate supply of water, limited to
safe water for drinking and water for
irrigating crops
Most sources of water in rural area are
polluted due to poor sanitation and lack
of waste water treatment facility
Flood irrigation, poor crop choice, leaky taps,
overwatering of plants, long baths…..
Ground water over drafting
Occurs when water removal exceeds water
recharge. This leads to drying up of wells,
deterioration in quality, reduction in water level
in streams and rivers
Climate change
Changes in rain and evaporation pattern
Corruption, mismanagement, lack of
infrastructure, unfair pricing….
Effect of inadequate water supply on plants
EFFECTS OF
WATER SCARCITY
Discuss the implications of an
Plants need water for
Photosynthesis
Germination
Transpiration
Nutrient transfer
6CO2+ 6H2O C6H12O6 +6O2
water activate the
process and softens
the seed
continual flow of water
keep the cell firm
plants absorb and
transfer only ions
dissolved in water
inadequate supply of water, limited to
safe water for drinking and water for
irrigating crops
Implications of water stress
Symptoms of mild water stress
Symptoms of severe water stress
Slow and stunted growth

Yellowing of leaves
Leaves turn from shiny to dull

Wilting of leaves

Burning and scorching the edges
of the leaves

Dropping some or all the leaves
Inadequate supply of drinking water
EFFECTS OF
WATER SCARCITY
Discuss the implications of an
inadequate supply of water, limited to
safe water for drinking and water for
Drinking water requirement by age (in litres)
0.7 -0.8
1.3 -1.7
2.5
3.0
2.2
Babies and Infants
Children
Boys & Girls (age 9-13)
Men
Women
Health effects due to lack of water
irrigating crops
Fatigue and lack of energy
Due to decrease in enzymatic activity
Overweight and obesity
Water maintains healthy metabolism and
releases more toxic and waste products
from the body
Premature aging
Reduces antioxidant activity in the
body
Constipation
Due to dehydration of intestine
stool will not form easily
Inadequate supply of drinking water
EFFECTS OF
WATER SCARCITY
Discuss the implications of an
inadequate supply of water, limited to
Water quality refers to biological, chemical, physical and radiological characteristics of water
No
safe water for drinking and water for
irrigating crops
Pathogens
Poisonous chemicals
Colour
Radioactive
virus, bacteria,
protozoa
Heavy metals (Pb, Hg..)
Pesticides…
Heavy water (<600mg/L)
odour, taste
pH = 6.5-8.5
materials
Essential electrolytes and minerals in drinking water
Fe
oxygen transport, metabolism of
neurotransmitters , DNA synthesis….
I
a critical component of thyroid
hormones
P
a structural component of bones
Cu
Zn
Mg
responsible for catalytic properties of
enzymes…
Ca
primary structural constituent of the
skeleton , regulates many enzyme and
hormonal responses…..
Sodium, potassium, chloride…..
Inadequate drinking water and health effects
EFFECTS OF
WATER SCARCITY
Health effects due to biological contamination
Typhoid
Discuss the implications of an
(Salmonella typhi)
high fever, diarrhea, vomiting
Cholera
(Vibrio cholerae)
watery diarrhea,
vomiting, muscle cramps
inadequate supply of water, limited to
safe water for drinking and water for
irrigating crops
Amoebiasis
(Entamoeba)
Bloody diarrhea, abdomen pain
Dysentery, Malaria, Jaundice…
Hepatitis A and E
(Virus)
abdomen pain, dark urine,
loss of appetite
Inadequate drinking water and health effects
EFFECTS OF
WATER SCARCITY
Health effects due to chemical contamination
Arsenic
Fluorides (Fluorosis)
Discuss the implications of an
Causes liver damage,
skin cancer & vascular disease
Yellowing of teeth
and damages spinal cord
inadequate supply of water, limited to
NO3-
safe water for drinking and water for
irrigating crops
Pb
As
Lead
Accumulates in the body and
damages central nervous system
F-
Pesticides, Herbicides & Insecticide
Damages central nervous system,
causes cancer, endocrinal damage …
Nitrates
Restrict the amount of
oxygen in the brain
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SIJI GEORGE (sijiparekattil@gmail.com)
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