1. Introduction to Grain Fumigation: o Definition and purpose of grain fumigation. o Historical methods of grain fumigation. o The importance of fumigation in agriculture and storage. 2. Phosphine as a Fumigant: o Chemical properties of phosphine. o Mechanism of action as a fumigant. o Safety, environmental, and health considerations. o Regulations and guidelines for phosphine use. 3. Smart IoT Systems in Agriculture: o Overview of IoT in smart agriculture. o Benefits of IoT for crop monitoring and pest control. o Case studies of IoT applications in grain storage and protection. 4. Fumigant Dispenser Systems: o Types of fumigant dispensers. o Automated control mechanisms. o Precision dosing and controlled release technologies. 5. Fumigation Chamber Design: o Design principles for effective fumigation chambers. o Materials and construction techniques. o Sealing and leakage prevention in chamber design. 6. Air Circulation Systems: o Role of air circulation in fumigation. o Types of fans and blowers (focus on centrifugal fans). o Design considerations for uniform distribution of fumigant. 7. Sensors and Monitoring in Fumigation Systems: o Types of sensors used (e.g., gas concentration, humidity, temperature). o Data acquisition and processing. o Real-time monitoring and feedback mechanisms. 8. IoT Integration and Network Communication: o Communication protocols for IoT devices. o Data security and privacy in IoT networks. o Integration of sensors, dispensers, and fans into an IoT framework. 9. Control Systems and Automation: o Automated control system design. o Algorithms for decision making and process control. o User interfaces and interaction with the automated system. 10. Safety and Compliance: o Ensuring safety in automated fumigation systems. o Compliance with international standards and regulations. o Emergency response and fail-safes. 11. Environmental Impact and Sustainability: o Impact of phosphine and fumigation practices on the environment. o Measures to minimize ecological footprints. o Sustainable practices in grain fumigation. 12. Economic Analysis: o Cost-benefit analysis of implementing smart fumigation systems. o Comparison with traditional fumigation methods. o Market potential and economic incentives. 13. Future Trends and Innovations: o Emerging technologies in fumigation and IoT. o Research frontiers in smart fumigation systems. o Potential developments in regulation and standards.