2.3– TRANSFEROFTHERMALENERGY 2.THERMALPHYSICS 2.3– TRANSFEROFTHERMALENERGY Learning Outcomes Students should be able to: 1. Describe experiments to distinguish between good and bad thermal conductors 2. Describe thermal conduction in all solids in terms of atomic or molecular lattice vibrations and also in terms of the movement of free (delocalised) electrons in metallic conductors 3. Explain convection in liquids and gases in terms of density changes and describe experiments to illustrate convection 4. Describe the process of thermal energy transfer by infrared radiation and know that it does not require a medium 5. Describe the effect of surface colour (black or white) and texture (dull or shiny) on the emission, absorption and reflection of infrared radiation 6. Describe how the rate of emission of radiation depends on the surface temperature and surface area of an object 7. Describe experiments to distinguish between good and bad emitters of infrared radiation 8. Describe experiments to distinguish between good and bad absorbers of infrared radiation PREPARED BY ERWANDI H. 1 2.3– TRANSFEROFTHERMALENERGY 9. Explain everyday applications using ideas about conduction, convection and radiation, including: (a) heating objects such as kitchen pans (b) heating a room by convection (c) measuring temperature using an infrared thermometer (d)using thermal insulation to maintain the temperature of a liquid and to reduce thermal energy transfer in buildings PREPARED BY ERWANDI H. 2 2.3– TRANSFEROFTHERMALENERGY 2.3.1-CONDUCTION The handle of a metal spoon held in a hot drink soon gets warm. Heat passes along the spoon by conduction. Conduction: flow of thermal energy through matter from places of higher temperature to places of lower temperature without movement of the matter as a whole. 1. Describe experiments to distinguish between good and bad thermal conductors Some materials are good thermal conductors, whereas some are bad thermal conductors (good insulator). Most metals are good conductors of heat; materials such as wood, glass, cork, plastics and fabrics are bad conductors i.e. they are good insulators. Metal objects below body temperature feel colder than those made of bad conductors because they carry thermal energy away faster from the hand. Below is an experiment to distinguish the conduction power of various metals: ֎ match iron rod using a little melted wax. The other ends are copper rod aluminium rod paraffin wax A match is fixed to one end of each rod tripod heated by a burner. ֎ When the temperatures of the far ends reach the melting point of wax, the matches drop off. brass rod ֎ The best conductor is the one where the match falls off first (in this case copper). burner PREPARED BY ERWANDI H. 3 2.3– TRANSFEROFTHERMALENERGY 2. Describe thermal conduction in all solids in terms of atomic or molecular lattice vibrations and also in terms of the movement of free (delocalised) electrons in metallic conductors In terms of atomic or molecular lattice vibrations; ֎ When an object is heated up, thermal energy is transferred to particles, making them vibrate more vigorously (i.e. kinetic energy increases). ֎ These particles then collide with neighbouring atoms. ֎ Energy is thus transferred to these neighbouring atoms. However, in metals, conduction is faster. This is because, in addition to molecular lattice vibration, they have a large number of “free-moving” (delocalised) electrons, as illustrated by the green particles in the diagram below. In terms of the movement of free (delocalised) electrons ; ֎ When a metal is heated up, the particles will vibrate vigorously and strike / collide with the free-moving electrons. ֎ The electrons move faster (their kinetic energy increases) and further. ֎ These electrons will travel to distant particles, transferring the thermal energy. In summary: Conduction in metals (faster) Atomic /Molecular Lattice Vibration Conduction in non-metals (slower) Atomic /Molecular Lattice Vibration Movement of electrons PREPARED BY ERWANDI H. 4 2.3– TRANSFEROFTHERMALENERGY WORKEDEXAMPLES 1 How is heat conducted in a metal? A. by movement of electrons through the metal only B. by movement of atoms through the metal only C. by vibration of atoms and movement of electrons through the metal D. by vibration of atoms only ANS: C. 2 A metal can and a plastic bottle, both containing liquid, are cooled by placing melting ice, as shown in Fig. 4.1. them themininaa jug jug of of jug melting ice Fig. 4.1 The liquid in the metal can cools down faster than the liquid in the plastic bottle. Suggest why this happens. ANS: Metal is a good conductor of heat - it carry thermal energy away faster. 3 Describe and explain, in terms of free electrons, how thermal energy is transferred through the copper base of the saucepan. Thermal energy is transferred to the particles, making them vibrate more [1] ........................................................................................................................................... These particles will strike the free-moving electrons [1] ........................................................................................................................................... These electrons will gain energy, thus travelling to and hitting distant particles, ........................................................................................................................................... transferring the thermal energy. [1] ........................................................................................................................................... ........................................................................................................................................... ...................................................................................................................................... [3] PREPARED BY ERWANDI H. 5 2.3– TRANSFEROFTHERMALENERGY 2.3.2-CONVECTION 3. Explain convection in liquids and gases in terms of density changes and describe experiments to illustrate convection Convection is the usual method by which thermal energy travels through fluids (liquids and gases). Convection: flow of thermal energy through a fluid from places of higher temperature to places of lower temperature by movement of the fluid itself. Let’s look at what happens to a. Fluids are heated up at the b. The particles expand - fluids when they are heated bottom their up. volume increases. Therefore, density decreases c. The less dense / heated d. The denser particles will rise up particles will sink / cooler e. This movement of fluids due to difference in its density sets up a convection current PREPARED BY ERWANDI H. 6 2.3– TRANSFEROFTHERMALENERGY Experiment to Illustrate Convection in Liquids. ֎ Drop a few crystals of potassium permanganate down a tube to the bottom of a beaker / flask of water. ֎ The beaker is heated just below the crystals ֎ Purple streaks of water rise upwards and fan outwards. Experiment to Illustrate Convection in Gases. A laboratory demonstration of convection currents smoke in air can be given using the apparatus in the opposite diagram. lighted touch paper glass chimneys ֎ Touch paper is lighted, producing smoke. box ֎ The smoke is directed down the chimney. ֎ The direction of the convection current created by the candle is made visible by the smoke from the touch paper lighted candle glass window WORKEDEXAMPLE When a refrigerator is switched on for the first time, the air surrounding the ice-box is cooled. ice-box What happens to the density of this air and to its position inside the refrigerator? density position of the air A decreases sinks to the bottom B decreases stays at the top C increases sinks to the bottom D increases stays at the top ANS: C PREPARED BY ERWANDI H. 7 2.3– TRANSFEROFTHERMALENERGY WORKEDEXAMPLE A copper saucepan with a wooden handle contains cold water. The saucepan is placed on a red-hot heating element that is a part of an electric cooker. Fig. 4.1 shows the saucepan on the heating element. water saucepan wooden handle heating element Fig. 4.1 Describe and explain how thermal energy is transferred upwards through the water. ....H ...e..a..te ...d...w..a..t.e..r..e ..x..p..a..n..d..s...a..n..d...i.s...le ..s..s...d..e..n..s..e...[.1..].................................................................. The heated / less dense water will rise [1] ........................................................................................................................................... Denser / colder water will sink [1] ........................................................................................................................................... 2.3.3-RADIATION 4. Describe the process of thermal energy transfer by infrared radiation and know that it does not require a medium Whereas conduction and convection both need matter to be present, radiation can occur in a vacuum (region of space void of any particles of matter). ֎ Thermal radiation is infrared radiation and it does not require a medium. ֎ It travels with the speed of light and has all the properties of electromagnetic waves (topic 3.3) All objects emit radiation – when it falls on an object; it is partly reflected, partly transmitted and partly absorbed. o An object can cool down as it emits radiation o An object can heat up as it absorbs radiation PREPARED BY ERWANDI H. 8 2.3– TRANSFEROFTHERMALENERGY 5. Describe the effect of surface colour (black or white) and texture (dull or shiny) on the emission, absorption and reflection of infrared radiation 8. Describe experiments to distinguish between good and bad absorbers of infrared radiation shiny surface electric heater Some surfaces absorb radiation better than others, dull black surface as may be shown in this experiment. The inside surface of one lid is shiny and the other dull black. The coins are stuck on the outside with candle wax. coin The heater is midway so each lid receives the same candle wax tin lid amount of radiation. After a few minutes the wax on the black lid melts and the coin falls off. The shiny lid stays cool and the wax unmelted. ֎ Dull black surfaces are better absorbers of radiation than shiny white surfaces. ֎ Shiny white surfaces are good reflectors of radiation. 5. Describe the effect of surface colour (black or white) and texture (dull or shiny) on the emission, absorption and reflection of infrared radiation 7. Describe experiments to distinguish between good and bad emitters of infrared radiation Some surfaces also emit radiation better than others when they are hot. hot copper sheet with one side polished and the other blackened back of hands towards sheet One side of a hot copper sheet is polished and the other side blackened. If you hold the backs of your hands on either side, it will be found that the dull black surface is warmer i.e. it emits more heat. ֎ Dull black surfaces are better emitters of radiation than shiny white surfaces. ֎ If dull black surfaces emits more heat (loses more heat), they will cool down faster. PREPARED BY ERWANDI H. 9 2.3– TRANSFEROFTHERMALENERGY Absorber Emitter Dull black surfaces Better (heats up faster) Better (cools down faster) Shiny white surfaces Poor (heats up slower) Poor (cools down slower) WORKEDEXAMPLES 1. The tubes inside solar heating panels use the Sun’s radiation to warm water. Why are the tubes painted black? A. Black surfaces absorb radiation well. B. Black surfaces conduct heat well. C. Black surfaces emit radiation well. D. Black surfaces reflect radiation well. ANS: A. Make sure you understand the question! Even though black surfaces emit radiation well (c), the tubes are painted black because we want to heat up the water – and so we want it to absorb more radiation. 2. A slice of bread is placed under a red-hot electric grill to make toast. grill slice of bread How does heat energy reach the bread? A. conduction and convection B. conduction only C. convection and radiation D. radiation only ANS: D. In convection, thermal energy is carried upwards (heated particles rise because they are less dense). Since the slice of bread is beneath the grill, the heated gas particles cannot reach the bread via convection. PREPARED BY ERWANDI H. 1 0 2.3– TRANSFEROFTHERMALENERGY 6. Describe how the rate of emission of radiation depends on the surface temperature and surface area of an object Rate of Coolling A thermometer is placed in hot water. The temperature is recorded every 30s as the water cools away. A student recorded the following as the water is cooled in air and plotted a temperature against time graph: Time/s 0 30 60 90 120 150 180 Temp/oC 80 63 51 42 36 31 28 Temperature falls down faster (more emission) If the surface temperature of an object is higher than its surroundings, it emits radiation at a faster rate than it absorbs radiation from its surrounding i.e. it cools down. From the experiment above, radiation is emitted faster when the temperature is higher. Rate of cooling down / rate of emission is affected by two factors: ֎ Surface temperature: the higher it is, the greater the quantity of radiation it emits (it cools down faster) ֎ Surface area: the higher it is, the greater the quantity of radiation it emits (it cools down faster) PREPARED BY ERWANDI H. 1 1 2.3– TRANSFEROFTHERMALENERGY 9. Explain everyday applications using ideas about conduction, convection and radiation, including: (a) heating objects such as kitchen pans (b) heating a room by convection (c) measuring temperature using an infrared thermometer (d) using thermal insulation to maintain the temperature of a liquid and to reduce thermal energy transfer in buildings 2.3.4– CONSEQUENCESOFTHERMALENERGYTRANSFER a) Heating objects such as kitchen pans Good conductors are used whenever heat is required to travel quickly through something. Saucepans, boilers, and radiators are made of metals such as copper which are all good conductors that transfer thermal energy quickly. The handles of saucepans are made of insulators (bad thermal conductors) so thermal energy does not flow easily. b) Heating a room by convection Convection currents set up by electric, gas and oil heaters help to warm our homes. Warm air produced by the heater rises (less dense), and the cold air sinks. The cold air will then be warmed up by the heater and a convection current is set up. c) Measuring temperature using an infrared thermometer An infrared thermometer detects the thermal radiation emitted by an object and converts it into an electrical signal. PREPARED BY ERWANDI H. 1 2 2.3– TRANSFEROFTHERMALENERGY d) Using thermal insulation to maintain the temperature of a liquid and to reduce thermal energy transfer in buildings Thermal insulators are used when a slow transfer of thermal energy is required. A polysterene cup will help keep hot liquids warm or cold liquids cool. Single-glazed Double-glazed Air is one of the worst conductors (best insulator). This is why houses with cavity walls (two layers of bricks separated by an air space) and double-glazed windows keep warmer in winter and cooler in summer i.e. thermal energy is not transferred away easily. Materials that trap air, such as wool, felt, fur, feathers, polystyrene foam, fibreglass, are also poor conductors. Some of these materials are used to insulate water pipes, hot water cylinders, ovens, refrigerators and the walls and roofs of houses so thermal energy is not easily lost. PREPARED BY ERWANDI H. 1 3 2.3– TRANSFEROFTHERMALENERGY EXAM-STYLEQUESTIONS 1 (a) No thermal energy (heat) is transferred from the surface of the Sun to the Earth by either conduction or convection. Explain why this is so. .......................................................................................................................................... .......................................................................................................................................... ...................................................................................................................................... [2] (b) In a certain country, the climate is very sunny and hot during the day and extremely cold during the night. Explain how painting the houses white helps to maintain a comfortable temperature both during the day and during the night. during the day: ................................................................................................................. .......................................................................................................................................... .......................................................................................................................................... during the night: ............................................................................................................... .......................................................................................................................................... .......................................................................................................................................... [3] PREPARED BY ERWANDI H. 1 4