B.1 Thermal Energy Transfers B. The Particulate Nature of Matter Syllabus Content Syllabus Content Syllabus Content Syllabus Content Thermal Energy Transfer • Demonstration - Balloon • What is going on inside the balloon? • Why does it keep its shape? • What makes matter solid, liquids, or gases? What are their properties? Thermal Energy Transfer 6 assumptions in the Kinetic Model/Kinetic Molecular Theory: 1.Gases are composed of a large number of particles that behave like hard, spherical objects in a state of constant, random motion. 2.These particles move in a straight line until they collide with another particle or the walls of the container. Particles are in constant random motion. 3.These particles are much smaller than the distance between particles. Most of the volume of a gas is therefore empty space. Thermal Energy Transfer 6 assumptions in the Kinetic Model/Kinetic Molecular Theory: 4.There is no force of attraction between gas particles or between the particles and the walls of the container. 5.Collisions between gas particles or collisions with the walls of the container are perfectly elastic. None of the energy of a gas particle is lost when it collides with another particle or with the walls of the container. 6.The average kinetic energy of a collection of gas particles depends on the temperature of the gas and nothing else. Thermal Energy Transfer Properties of Solids, Liquids, and Gases https://phet.colorado.edu/sims/html/states-of-matter-basics/latest/states-of-matter-basics_en.html Phases of Matter and Their Properties Density When solids and liquids are heated to higher temperatures, they typically undergo a slight expansion (as long as the container allows that to happen) as the particles within them experience a small increase in separation. Consequently, this results in a minor reduction in their densities. Typical Values for Densities Thermal Energy Transfer Answer questions 1-5, p178 Thermal Energy Transfer HEAT TEMPERATURE Using a Venn diagram, write the differences between heat and temperature based on the given characteristics below A. Transfer of thermal energy between objects due to difference in temperature B. Measures the average kinetic energy of the particles. C. Form of energy D. Not a form of energy E. Cannot be measured directly F. Can be measured directly G. Unit J/kgoC H. Joule (J) I. Deals with energy and matter J. Dependent on molecules Thermal Energy Transfer HEAT Answer TEMPERATURE C A J E G F B D H I A. Transfer of thermal energy between objects due to difference in temperature B. Measures the average kinetic energy of the particles. C. Form of energy D. Not a form of energy E. Cannot be measured directly F. Can be measured directly G. Unit Joule (J) H. Unit OC or K or OF I. Deals with energy and matter J. Dependent on molecules Thermal Energy Transfer The resultant flow of thermal energy is always from higher temperature to lower temperature Thermal Equilibrim All temperatures within a system are constant. If there is no net transfer of thermal energy between A and B, then they must be at the same temperature. Figure B1.5 Two objects (A and B) at different temperatures, insulated from their surroundings but not from each other, will reach thermal equilibrium Thermal Energy Transfer Celsius (scale of temperature): Temperature scale based on the melting point (0°C) and boiling point (100°C) of pure water. Kelvin scale of temperature: Also known as the absolute temperature scale. The kelvin, K, is the fundamental SI unit of temperature. T (in K) = 0 °C + 273. Absolute zero Temperature at which (almost) all molecular motion has stopped (0 K or −273 °C). Thermal Energy Transfer • Answer questions 8-11 on page 182 TASK Thermal Energy Transfer All gases, at the same temperature, contain particles with the same average translational kinetic energy The particles in most gases are molecules, which means that they also have other forms of kinetic energy (not just translational), for example, rotational kinetic energy and vibrational kinetic energy Thermal Energy Transfer Particles can have potential energy as well as kinetic energy. In solids and liquids, it is the electrical forces (between charged particles) that keep particles from moving apart or moving closer together. Wherever there are electrical forces there will be electrical potential energy in a system. Thermal Energy Transfer Answer questions 12-15 on page 184 TASK Thermal Energy Thermal energy is the transfer of energy because of a temperature difference: a net flow from hotter to colder. Three principal ways in which thermal energy can be transferred: • Thermal conduction. In which kinetic energy is transferred between particles. • Convection. In which differences in the densities of liquids and gases result in their movement. • Thermal radiation. In which electromagnetic radiation is emitted by surfaces. Thermal Conduction Thermal conduction occurs because of the transfer of kinetic energy between particles. Solids are generally better thermal conductors than liquids, and liquids conduct better than gases considering the closeness of particles and the strength of forces between them Thermal Conduction A larger number means that the substance is better at conducting thermal energy: more energy is transferred under similar conditions. (Metals are good conductors because they contain many free / delocalized electrons.) Thermal Conduction Task Answer questions 16-20 page 187 Quantitative treatment of thermal conductivity k is a constant, different for each substance. It is called the thermal conductivity of the substance (as shown in Table B1.4). Unit:Wm−1K−1. āšø is a flow of energy per second (a power) so it is āš measured in watts. Insulation The best insulator for limiting thermal energy flowing out of, or into, homes is air. If the air can move, thermal energy can also be transferred by convection currents . • Parallel sheets of glass (known as double glazing), can be used to trap air and limit thermal energy flow through a window. • Double glazing has the added benefit of reducing the transfer of sound. Task Task Answer questions 24-25 page 190 Thermal Convection • When part of a fluid (gas or liquid) is heated, there will be a localized decrease in density. • Because of increased buoyancy, the warmer part of the fluid will then rise and flow above the cooler part of the fluid, which has a slightly greater density. • This movement of thermal energy in a fluid is called thermal convection. Group Task (Poster) • In pairs, explain how convection happens in: • Group 1: Ovens • Group 2: Air conditioners • Group 3: heaters/radiators • Group 4: sea and land breeze • Group 5: Thunderstorm • Group 6: Refrigerators • You will be assessed according to the following criteria: • Accuracy of the explanation [3 marks] • Diagrams/illustrations [3 marks] • Ability to answer questions [3 marks] Task Answer questions 27-29 p191 Thermal Radiation Thermal radiation Electromagnetic radiation emitted because of the movement of charged particles in the atoms of all matter at all temperatures. Most commonly, infrared. Infrared Radiation is an electromagnetic radiation emitted by all objects (depending on temperature) with wavelengths longer than visible light Convection http://www.pinterest.com/pin/452400725040236330/ During daytime, as the Sun shines, land heats up more quickly than the sea. This results in air being warmed and rising. This warmer air is replaced by cooler air coming in from the sea. The reverse happens during nighttime. The sea remains warmer than the land, which cools down more quickly. Above the sea the warm air rises, and it is replaced by cooler air coming in from the land. Convection Convection in the home 1. As the convector heater gets warmer, it heats air immediately above it. 1 http://imgarcade.com/1/air-convection-currents/ Convection Convection in the home 1. As the convector heater gets warmer, it heats air immediately above it. 2. The warm air rises, carrying thermal energy all around the room. 2 1 http://imgarcade.com/1/air-convection-currents/ Convection Convection in the home 1. As the convector heater gets warmer, it heats air immediately above it. 2. The warm air rises, carrying thermal energy all around the room. 3. As the air cools, so it falls towards the floor before being heated again. 2 1 http://imgarcade.com/1/air-convection-currents/ 3 Convection Convection in the home http://chowlaiwan-physicsproject2009.blogspot.co.uk/ In the refrigerator, the cool air sinks below the freezer compartment. This sets up a circulating current of air which cools all food in the refrigerator. Thermal Radiation The power of the emitted radiation from any surface depends on: 1 Surface temperature. The radiated power is proportional to the fourth power of the surface temperature (in kelvin), T4. This means, for example, a metal bar at 600 K (323 °C) will emit 24 = 16 times as much radiation as the same bar at 300 K (23 °C). 2 Surface area The radiated power is proportional to the area, A. Note that the emitted power is not dependent on the chemical nature of the material. 3 Nature of the surface Thermal Radiation Black bodies • Black surfaces emit and absorb radiation well; • white surfaces are poor at absorbing and emitting. https://www.youtube.com/watch?v=BBwULYIOkfk Black-body emission spectra at three different temperatures The total power, P, emitted (across all wavelengths) from a perfect black body of surface area A can be calculated from the Stefan–Boltzmann law: σ is known as the Stefan–Boltzmann constant. It has the value of 5.67 × 10−8Wm−2K−4 Thermal Radiation Thermal Radiation Wien’s displacement law Relationship between absolute temperature and the wavelength emitted with maximum power by a black body at that temperature https://www.youtube.com/watc h?v=qjM73TlVkTo Thermal Radiation Task Answer questions 32 – 35 p196 Thermal Radiation and Stars Luminosity of a star (or other body), L= 4 σAT ā Luminosity (stellar) Total power of electromagnetic radiation emitted by a star (SI unit: W). Thermal Radiation and Stars Thermal Radiation and Stars We can write Polaris’s luminosity as L = 1600 Lā Thermal Radiation and Stars Task Betelguese is our nearest red giant star. It has a luminosity of 4.49 × 1031 W and emits radiation with a peak wavelength of 850 nm. Calculate the ratio of the radius of Betelgeuse rB to the radius of the Sun rs. Radius of the Sun rs = 6.95 × 108 m Answer Apparent Brightness, b and Intensity https://www.youtube.com/watch?v=GnFF NcJ5Aks Apparent Brightness, b and Intensity