Structure and Properties of Materials 1 No Course Content Tutorial (Assignment) Lab Lab 1 (Material classification) 1 Ah Classification of materials. ------- 2 Ad Atomic bonding. Ass 1 (Atomic bonding) ------- 3 Ad Crystallinity of materials. 4 Ad Crystallography 5 Ah Imperfections and Diffusion 6 Ah Solidification and Structure I 7 Ah Solidification and Structure II Mid Term Ass 2 (Unit cell and ------theoretical density) Ass 3 (Directions, Planes, Linear & planar ------density) Lab 2 (Sample ---preparation) Ass 4 (Grain size ---measurement) Lab 3 (Cooling ------curves) ------------- Phase diagram I Ass 5 (Phase diagram) ------- 10 R R Phase diagram II Ass 6 (Phase diagram) ------- 11 R Metals designation Ass 7 (Designation) Lab 4 (Polymer identification) 12 Ah Polymers 13 Ah Ceramics 14 Ah Mechanical Testing 15 Ah Case study and Review 8 9 Ass 8 (Polymers Dp and crystallinity) As 9 (Ceramic ------structure) Ass 10 (Mechanical --properties) Project --- Quiz/ Report/ Project Quiz 1 Report on Labs 1 & 2 Quiz 2 Report on labs 3& 4 Quiz 3 Oral and Project discussion 2 Grading Student Activities 25% Practical (Oral + Mid-Term Exam + notes+Project) Exam 25% 10% Final Exam 40% Assignments 10% Lab Report 8% Participation 7% References W.D. Callister “Materials Science and Eng.- an Introduction” , 7th edition, Wiley. عالم الكتب، المیتالورجیا الفیزیائیة،• أحمد سالم الصباغ 3 History https://www.scimap.tech/blog-1/materials-age 4 Materials Science vs Material Engineering • Materials science investigates the relationships that exist between the structures and properties of materials. • Materials engineering is, on the basis of these structure–property correlations, designs or engineers the structure of a material to produce a predetermined set of properties. • From a functional perspective, the role of a materials scientist is to develop or synthesize new materials, whereas a materials engineer is called upon to create new products or systems using existing materials, and/or to develop techniques for processing materials. 5 Case : Design/materials selection for a coffee cup Design specifications for coffee cup: ▪ Avoid burning the user’s hands ▪ Might be re-used ▪ Less danger to environment Materials properties for coffee cup: ▪ Excellent thermal insulation Reusable ▪ Recyclable Candidate Materials: Ceramics & Polymers Both appropriate due to their low thermal conductivity However: ▪ Polymers cup (polyethylene) should not be re-used (become poisonous) ▪ Disposing polymers cause environmental damage → unrecyclable ▪ Ceramics can be reused and less danger to environment. Proposed Material: Ceramics 6 Global relation Property-StructureProcessing-Performance Structure: Something made up of a number of parts that are held or put together in a particular way, A property is a material response to a specific imposed stimulus. Generally, definitions of properties are made independent of material shape and size. Important properties of solid materials may be grouped into six different categories: mechanical, electrical, thermal, magnetic, optical, and deteriorative. Stimulus Response Load Mech Prop (Strength) Electric field Elec Prop (elec conductivity) -------- ---- prop (------------) 7 Global relation Property-StructureProcessing-Performance 4-Perfermoance of 3 samples of Aluminum oxide: 3-Property Transparent* Translucent Opaque 2-Structure a single crystal Very small single crystals connected together. The boundaries scatter a portion of the light reflected from the printed page Many small, interconnected crystals, but also of a large number of very small pores. These pores scatter the reflected light and render this material opaque 1-Processing: These differences in optical properties are a consequence of differences in structure from the way the materials were processed 8 1-Processing Chemical Composition (Alloying) 2-Structure Thermal Heat Treatment Mechanical Manufacturing Processes 9 Is the structure an unchangeable feature? EXAMPLE: FORGING STRUCTURE Before forging tougher An ingot heated to high temperature is beaten After forging Crystal grains of the metal are large and non-uniform Crystal grains of the metal are small and uniform 1-Processing 2-Structure 10 Structure Classification Macrostructure Microstructure affects the chemical, physical, thermal, electrical, magnetic, and optical properties Nanostructure Short- and large range atomic arrangement Atomic structure μm = 10-6 m nm = 10-9 m Å = 10-10 m have a larger effect on mechanical properties and on the rate of chemical reaction ▪ ▪ ▪ ▪ ▪ ~ > 100 μm 10 – 1000 nm 1 – 100 nm 1-10 Å Up to 1 Å 11 Long range Vs. Short range • Atomic positions in a crystal exhibit a property called longrange order or translational periodicity; positions repeat in space in a regular array over a long distance • Short range order refers to the regular and predictable arrangement of atoms over a short distance, usually with one or two atom spacing’s. However, this regularity does not persist over a long distance. 12 Classification of structure Structure Crystalline Amorphous 13 The fundamental difference between single crystal , polycrystalline and amorphous solids is the length scale over which the atoms are related to one another by translational symmetry ('periodicity' or 'long-range order') Single crystals have infinite periodicity, polycrystals have local periodicity, and amorphous solids (and liquids) have no long-range order 14 What is a Property? Stimulus Response • Property gives the same measurement regardless of the size. • Density is a property, but mass is not Physical • • • • • Color, texture, shape, smell, state of matter (solid, liquid, and gas), • sound, • taste Chemical • pH • Surface energy • Surface tension • Specific internal surface area • Reactivity • Corrosion resistance 15 Electrical Magnetic Optical Thermal • Electrical • Permeability • Absorptivity •Thermal conductivity conductivity • Hysteresis • Reflectivity • Thermal diffusivity • Permittivity • Curie Point • Refractive index • Thermal expansion • Dielectric • Photosensitivity • Emissivity constant • Transmittance • Coefficient of thermal • Dielectric • Luminosity expansion strength • Scattering • Specific heat • Piezoelectric •Glass transition temperature constant • Melting point 16 Mechanical • Tensile strength • Ductility • Elastic modulus • Fatigue limit • Hardness • Poisson’s ratio • Shear modulus • Yield strength • Fracture toughness 17 17 Materials Engineering Those used in manufacture and become parts or products NonEngineering The chemicals, fuels, lubricants, and other materials used in the manufacturing process which do not become part of the product 18 Engineering Materials Metals & alloys Polymers Ceramics Composites An alloy is a homogeneous mixture of two or more elements, at least one of which is a metal, and where the resulting material has metallic properties 19 General Properties of … Metals • Polymers •Metallic luster; •Opaque; •Corrosive; •Relatively dense; •Strong (relatively high strength); •Deformable; •Extremely good conductors of electricity and heat. • Low density, • Hard but brittle; bad • Low melting point; deformable • Bad conductor to • High resistance to heat and electricity; high temp and harsh • Easily affected by environments; environmental • Good insulator to factors; heat and electricity; • Highly Deformable. • Chemically stable; • May be transparent, translucent, or opaque. Ceramics 20 Composites vs. Alloys Composites are mixture in macroscopic level Alloys are mixture in microscopic level 2/12/2020 21 In your Text book, study: Chapter 1. Introduction Lab: Materials identification visual observation of their finishes, touches, colors, texture, luster, and fracture appearance. 22