Electronics for IT Dr. Engs. Wesam Bachir, PhD. Computer Engineering Vistula University b.wesam@vistula.edu.pl ENGAGE Lecture Introduction to Semiconductors 2 Semiconductors In the 1940s, researchers developed a new technology that lead to new components that were, literally, a quantum-leap improvement over vacuum tubes. These new components were called semiconductors. Copyright © 2022 Pearson Education, Inc. All Rights Reserved 3 Lecture Outline The basic structure of semiconductors and how they conduct current The atomic structure of silicon and germanium Covalent bonding in silicon Explain how current occurs with electrons and holes in a semiconductor The properties of n-type and p-type semiconductors Copyright © 2022 Pearson Education, Inc. All Rights Reserved 4 Why Semiconductors ? 5 Silicon and Germanium Atoms silicon (Si), a nonmetallic chemical element in the carbon family (Group 14 [IVa] of the periodic table). The germanium valence electrons are at higher energy levels than those in silicon and, therefore, require a smaller amount of additional energy to escape from the atom. This property makes germanium more unstable than silicon at high temperatures, which is the main reason silicon by far is the most widely used semiconductive material. 6 Copyright © 2022 Pearson Education, Inc. All Rights Reserved Atomic Bonding When certain atoms combine to form a solid material, they arrange themselves in a fixed pattern called a crystal. The atoms within the silicon crystal structure are held together by covalent bonds, which are created by the sharing of the valence electrons of each atom. The center silicon atom shares an electron with each of the four surrounding silicon atoms, creating a covalent bond with each. Copyright © 2022 Pearson Education, Inc. All Rights Reserved Bonding diagram. The red negative signs represent the shared valence electrons. 7 Conduction Electrons and Holes A pure silicon crystal at room temperature has sufficient heat (thermal) energy for some valence electrons to jump the gap from the valence band into the conduction band, becoming free electrons. 8 Copyright © 2022 Pearson Education, Inc. All Rights Reserved Electron-hole pair Copyright © 2022 Pearson Education, Inc. All Rights Reserved 9 Electron and Hole Current The applied voltage across a piece of silicon, will attract the thermally generated free electrons in the conduction band, to the positive end. This movement of free electrons is called electron current. 10 Copyright © 2022 Pearson Education, Inc. All Rights Reserved The hole current It occurs at the valence level. Electrons remaining in the valence band are still attached to their atoms and are not free to move randomly in the crystal structure. A valence electron can move into a nearby hole, with little change in its energy level, thus leaving another hole where it came from. The hole has effectively, although not physically, moved from one place to another, it is called hole current. 11 Hole electron currents 12 Copyright © 2022 Pearson Education, Inc. All Rights Reserved Energy Gap There exist three types of materials (insulators, semiconductors, and conductors). Pure semiconductors are neither insulators nor good conductors because the current in a material depends directly on the number of free electrons. The energy gap for an insulator is so wide that hardly any electrons acquire enough energy to jump into the conduction band. The valence band and the conduction band in a conductor (such as Metals) overlap as there are always many conduction electrons, even without the application of external energy. A semiconductor has an energy gap that is much narrower than that in an insulator. 13 Copyright © 2022 Pearson Education, Inc. All Rights Reserved Energy Gap 14 Copyright © 2022 Pearson Education, Inc. All Rights Reserved Types of Semiconductors Because of the limited number of free electrons in the conduction band and holes in the valence band in pure semiconductors, They do not conduct current well. To make them conductive they must be modified by increasing the free electrons and holes. This can be done by adding impurities to the semiconductive material. Two types of (impure) semiconductive materials, n-type and p-type, are the key building blocks for all types of electronic devices. 15 Copyright © 2022 Pearson Education, Inc. All Rights Reserved The Doping Process Adding impurities to the (pure) semiconductive material makes them more conductive. The conductivities of silicon can be increased and controlled by this process. This process s called doping. The aim is to increase the number of current carriers (electrons or holes). The two categories of impurities are n-type and p-type. Copyright © 2022 Pearson Education, Inc. All Rights Reserved 16 N-Type Semiconductor The goal is to increase the number of conduction-band electrons in pure semiconductors such as silicon material. Doner atoms such as arsenic (As), phosphorus (P) can be used to provide pentavalent impurity to silicon. These doners are atoms, with five valence electrons, provide an extra electron to the semiconductor’s crystal structure. 17 Copyright © 2022 Pearson Education, Inc. All Rights Reserved N-Type Semiconductor Each doner atom (Sb) forms covalent bonds with four adjacent silicon atoms. Four of the Sb atom’s valence electrons are used to form the covalent bonds with silicon atoms The extra electron from the Sb atom becomes a free electron. 18 Copyright © 2022 Pearson Education, Inc. All Rights Reserved P-Type Semiconductor The aim is to increase the number of holes in pure silicon. Trivalent impurity atoms can be added. These are atoms with three valence electrons, such as aluminum (Al), boron (B), and gallium (Ga). These atoms are known as acceptor atoms because they leave a hole in the semiconductor’s crystal structure. 19 Copyright © 2022 Pearson Education, Inc. All Rights Reserved P-Type Semiconductor Each trivalent atom (boron) forms covalent bonds with four adjacent silicon atoms. All three of the boron atom’s valence electrons are used in the covalent bonds; and, since four electrons are required, a hole is formed with each trivalent atom. The number of holes can be controlled by the amount of trivalent impurity added to the silicon. Copyright © 2022 Pearson Education, Inc. All Rights Reserved 20 What is next? To understand electronic devices a basic knowledge of the structure of atoms is required. Semiconductive materials are used in manufacturing diodes as well as other semiconductive components such as transistors and integrated circuits. An important concept is that of the pn junction that is formed when two different types of semiconductive material are joined. The pn junction is fundamental to the operation of a diode. Copyright © 2022 Pearson Education, Inc. All Rights Reserved 21 End of Lecture 7 22