Chapter 11 Revision A) PROBLEMS: Write the answer on the line to the left. Show all your work in the space provided. 1. Convert a pressure of 0.400 atm to the following units: _________ a. torr _________ b. Pa 2. _________________ A 250. mL sample of gas is collected at 57C. What volume will the gas sample occupy at 25C? 3. _________________ H2 reacts according to the following equation representing the synthesis of ammonia gas: N2(g) 3H2(g) 2NH3(g) If 1 L of H2 is consumed, what volume of ammonia will be produced at constant temperature and pressure, based on GayLussac’s law of combining volumes? 4. _________________ A 7.00 L sample of argon gas at 420. K exerts a pressure of 625 kPa. If the gas is compressed to 1.25 L and the temperature is lowered to 350. K, what will be its new pressure? 5. _________________ Chlorine in the upper atmosphere can destroy ozone molecules, O3. The reaction can be represented by the following equation: Cl2(g) 2O3(g) 2ClO(g) 2O2(g) How many liters of ozone can be destroyed at 220. K and 5.0 kPa if 200.0 g of chlorine gas react with it? B) In the space provided, write the letter of the term or phrase that best completes each statement or best answers each question. _____ 1. The SI unit of pressure is a. newtons. b. pascals. c. atmospheres. d. torr. _____ 2. Most manometers and barometers contain a. water. b. alcohol. c. mercury. d. oil. _____ 3. Pressure = a. force area b. c. d. _____ 4. The unit of pressure known as the pascal is equal to a. 14.700 psi. b. 760 mm Hg. c. 1 atm. d. 1 N/m2 . _____ 5. Air is about 78% nitrogen, 21% oxygen, and 1% other gases. After all the oxygen is removed from a sample of air in a glass tube and the temperature remains constant, the pressure exerted by the remaining air a. does not change. b. is reduced by 78%. c. is reduced by 50%. d. is reduced by 21%. _____ 6. Which graph illustrates Boyle’s law? a. _________________ Volume vs. Pressure for a Gas at Constant Temperature b. __________________ Volume Vs. Temperature for a Gas at Constant Pressure c. __________________ Pressure Vs. Temperature for a Gas at Constant Volume d. None of the graphs _____ 7. The law that relates the temperature and volume of a gas to each other is known as a. Charles’s law. b. Boyle’s law. c. Gay-Lussac’s law. d. Graham’s law. _____ 8. Gay-Lussac recognized that at constant temperature and pressure, the volumes of gaseous reactants and products a. can be expressed as ratios of small whole numbers. b. add up to 22.4 L. c. equal R. d. always equal 1 L. _____ 9. Which of the following expressions relates the kelvin and Celsius temperature scales? a. K = 273.15 + °C b. K = 273.15 + °C c. °C = 273.15 K d. K = 273.15°C _____ 10. At constant temperature and pressure, gas volume is directly proportional to the a. molar mass of the gas. b. number of moles of gas. c. density of the gas at STP. d. rate of diffusion. _____ 11. What is the conversion factor that should be used to determine the number of moles of a gas at STP when you are given the volume of the gas? a. b. c. d. _____ 12. The ratios of the volumes of the gaseous reactants and products in a chemical reaction at constant temperature and pressure can be determined from the a. formulas. b. coefficients in the balanced equation. c. subscripts in the balanced equation. d. gas constant. _____ 13. For the balanced equation 2CO(g) + O2(g) 2CO2(g), the ratio 2:1:2 refers to all the following except a. volumes. b. moles. c. molecules. d. pressures. _____ 14. The law of combining volumes applies only to gas volumes a. measured at constant temperature and pressure. b. that equal 1 L. c. that equal 22.4 L. d. measured at STP. _____ 15. According to Avogadro’s law, 1 L of H2(g) and 1 L of O2(g) at the same temperature and pressure a. have the same mass. b. have the same molar mass. c. contain 1 mol of gas each. d. contain equal numbers of molecules. _____ 16. The passage of gas particles through a small opening is called a. diffusion. b. pressurization. c. effusion. d. vaporization. _____ 17. Which of these gases effuses the slowest under the same conditions? a. Ne b. NH3 c. NO2 d. CO2 _____ 18. In the figure above, the curve that represents an ideal gas is curve a. A. b. B. c. C. d. D. _____ 19. Gases tend to deviate from the ideal gas law at a. high pressures. b. low pressures. c. high temperatures. d. low pressures and high temperatures. _____ 20. A 10.2-L canister of oxygen gas contains 58.6 mol of gas at a temperature of 25.0°C. What is the pressure of the gas? a. b. c. d. 7.11 X 10 3 atm 8.48 X 10 2 atm 11.8 atm 141 atm _____ 21. Hydrogen gas is collected by water displacement. If the barometric pressure is 752.0 torr and the water vapor pressure is 17.5 torr, what is the partial pressure of the hydrogen collected? a. 769.5 torr b. 752.0 torr c. 734.5 torr d. 17.5 torr _____ 22. A sample of helium gas has a volume of 250.0 mL when its pressure is 0.935 atm. If the temperature remains constant, what will the pressure of the gas be when it has a volume of 175.0 mL? a. 1.34 atm b. 1.00 atm c. 0.935 atm d. 0.654 atm _____ 23. You collect 552 mL of argon gas at 23.0°C. What volume will the gas occupy at 46.0°C if the pressure remains constant? a. 276 mL b. 512 mL c. 595 mL d. 1104 mL _____ 24. The gas in an aerosol container is at a pressure of 3.50 atm at 24.0°C. The caution on the container warns against storing it at temperatures above 95°C. What would the gas pressure in the container be at 95°C? a. 4.34 atm b. 8.68 atm c. 13.9 atm d. 84.0 atm _____ 25. What is the ratio of the rate of effusion of helium (atomic mass 4.00 amu) to that of oxygen gas (molecular mass 32.0 amu)? a. 0.125 b. 0.354 c. 2.83 d. 8.00