The Periodic Table ALKALI METALS The group 1 elements are called the alkali metals. They are found in the s-block of the periodic table. They are very reactive, and as such not found free in nature but in a combined state. They are stored in oil to prevent them from reacting with the oxygen and water vapour in the air Physical Properties of Group 1 • They exist as silvery white solid at room temperature • They are soft and light • They have low melting and boiling point which decreases as you move down the group • They are very good conductors of heat and electricity Chemical properties They are univalent They ionize very readily to form positive ions by donating electrons, hence they are good reducing agent. The reducing property increases down the group. Example ; Na ----- e- Na+ K ------ e- K+ They react with cold water vigorously to liberate hydrogen gas and form metal hydroxides; so they are known as the alkali metals. K(s) + 2H2O(l) 2KOH(aq) + H2 They form basic oxides when react with oxygen, these oxides also dissolve in water to form very strong alkalis. For instance; Na(s) + O2(g) 2Na2O (s) Na2O + H2O NaOH Their trioxonitrates (IV) decomposes upon heating to form dioxonitrate (III) salts and oxygen KNO3 2KNO2 + O2 Their trioxocarbonate (IV) withstand heating but their hydrogen trixocarbonate (IV) decomposes to give trioxocarbonate (IV), carbon (IV) oxide and water . E.g NaHCO3 Na2CO3 +CO2 + H2O Electronegativity: this is the power of an atom in a molecule to attract electrons. Electronegativity decreases down the group, due to increasing distance between the valence electrons and nucleus. Across the period there is a steady increase in electronegativity =, due to decreasing distance between the valence electrons amd the nucleus. Ionization energy: this is the energy absorbed in order to remove the outermost electron from a gasesous atom. Ionization energy decreases steadily down the group, due to the steady increase in atomic size , as the electron to be removed is not strongly bound to the nucleus. Hence it will be easier to remove the outermost electron in K(2,8,8,1) than in the case of lithium (2,1). Across the period, ionization energy decreases in atomic size, as the electron to be remo