Back Print Name Class Date Assessment Chapter Test Stoichiometry In the space provided, write the letter of the term or phrase that best completes each statement or best answers each question. ______ 1. For the reaction SO3 H2O £ H2SO4, calculate the percentage yield if 500. g of sulfur trioxide react with excess water to produce 575 g of sulfuric acid. a. 82.7% b. 88.3% c. 91.2% d. 93.9% ______ 2. In the reaction 2Al2O3 £ 4Al 3O2, what is the mole ratio of aluminum to oxygen? a. 10:6 b. 3:4 c. 2:3 d. 4:3 ______ 3. Fewer steps are required to solve stoichiometry problems when the reactant is given in a. grams and the product is sought in grams. b. moles and the product is sought in moles. c. grams and the product is sought in liters. d. liters and the product is sought in number of atoms. ______ 4. Which of the following mathematical expressions correctly states the relationship among percentage yield, actual yield, and theoretical yield? percentage yield i. actual yield 100 theoretical yield actual yield ii. percentage yield 100 theoretical yield actual yield iii. theoretical yield 100 percentage yield a. i b. ii c. iii d. Both (b) and (c) Copyright © by Holt, Rinehart and Winston. All rights reserved. Holt Chemistry 54 Stoichiometry Back Print Name Class Date Chapter Test continued ______ 5. The participation of other reactants in a chemical reaction is restricted by the a. limiting reactant. b. limiting product. c. excess reactant. d. excess product. ______ 6. Which of the following expressions is not a legitimate conversion factor? 1 mol a. 6.022 1023 atoms 28.02 g N b. 2 1 mol N2 1gC c. 6.022 1023 atoms C 2.02 g H d. 2 1 mol H2 ______ 7. For the reaction P4(s) 5O2(g) £ P4O10(s), if 3 mol of phosphorus react with 10 mol of oxygen, the theoretical yield of phosphorus(V) oxide will be a. 1 mol. b. 2 mol. c. 3 mol. d. 10 mol. ______ 8. When a chemical reaction is performed in industry, the is often chosen as the excess reagent. a. least expensive and most abundant b. most expensive and least abundant c. least expensive and least abundant d. most expensive and most abundant chemical ______ 9. A convenient stoichiometric measurement for an evolving gas is a. volume. b. mass. c. atoms. d. molecules. ______10. Percent yield represents the a. efficiency b. speed c. individual steps d. rate of a chemical reaction. Copyright © by Holt, Rinehart and Winston. All rights reserved. Holt Chemistry 55 Stoichiometry Back Print Name Class Date Chapter Test continued ______11. The pollution produced by combustion engines can be partially controlled by which of the following? a. the use of a catalytic converter b. adjusting the contents of the gasoline c. having a well-tuned engine d. All of the above ______12. The limiting reactant of a reaction can be used to calculate the a. actual yield. b. theoretical yield. c. experimental yield. d. Both (a) and (c) ______13. The excess reactant when starting a gasoline (isooctane) engine is a. C8H18. b. CO2. c. O2. d. H2O. ______14. Which of the following factors does not affect the actual yield of a reaction? a. side reactions that compete with the main reaction b. reactions that are the reverse of the main reaction c. a mixture of reactants and products d. particles no longer reacting with each other ______15. If the percentage yield for a chemical reaction is 80.0%, the a. actual yield is 80.0 g for every theoretical yield of 100. g. b. theoretical yield is 80.0 g for every actual yield of 100. g. c. actual yield is 80 times as much as the theoretical yield. d. theoretical yield is 80 times as much as the actual yield. ______16. In the reaction, CH4(g) 2O2(g) £ CO2(g) 2H2O(g), a mass of 125 g CH4 is reacted with excess oxygen. The following expression 1 mol CH4 2 mol H2O 18.02 g H2O 125 g CH4 16.05 g CH4 1 mol CH4 1 mol H2O calculates the a. mass of oxygen reacted. b. mass of carbon dioxide produced. c. mass of water produced. d. None of the above Copyright © by Holt, Rinehart and Winston. All rights reserved. Holt Chemistry 56 Stoichiometry Back Print Name Class Date Chapter Test continued ______ 17. How many mole ratios can be correctly obtained from the following chemical equation? P4O10 6H2O £ 4H3PO4 a. b. c. d. 1 3 6 9 ______18. In most chemical reactions, the amount of product obtained is a. equal to the theoretical yield. b. less than the theoretical yield. c. more than the theoretical yield. d. more than the percentage yield. 1 ______19. The expression mass has the unit molar mass a. g/mol. b. mol/g. c. g. d. mol. ______20. In the formation of silicon carbide, given by the chemical equation, SiO2(s) 3C(s) £ SiC(s) 2CO(g), 8 mol of each reactant are available for the reaction. What substance is the excess reactant? a. SiO2(s) b. C(s) c. SiC(s) d. CO(g) Copyright © by Holt, Rinehart and Winston. All rights reserved. Holt Chemistry 57 Stoichiometry Back Print Name Class Date Chapter Test continued Answer the following items in the spaces provided. 21. Explain why the limiting reactant may not be used completely when the percentage yield for a reaction is 70%. 22. Why should you use moles in stoichiometric problems? 23. The equation for the burning of gasoline shows that carbon dioxide, water, and energy are the only products of combustion. Yet burning gasoline in car engines causes air pollution. What information not revealed by the equation accounts for the pollutants? Copyright © by Holt, Rinehart and Winston. All rights reserved. Holt Chemistry 58 Stoichiometry Back Print Name Class Date Chapter Test continued Answer each of the following problems in the spaces provided. 24. What mass in grams of potassium chloride is produced if 100. g of potassium chlorate decompose according to the following equation? 2KClO3(s) –heat –£ 2KCl(s) 3O2(g) 25. A research chemist designing an air bag is looking at carbon dioxide as a possible gas for bag inflation. One of the reactions the chemist is working with is the following. MgCO3(s) £ MgO(s) CO2(g) How many grams of magnesium carbonate are needed to produce enough carbon dioxide to inflate an air bag to a volume of 65.0 L? Use 1.961 g/L as the density of carbon dioxide gas. Copyright © by Holt, Rinehart and Winston. All rights reserved. Holt Chemistry 59 Stoichiometry Back Print TEACHER RESOURCE PAGE Answer Key Quiz—Section: Calculating Quantities in Reactions 1. 2. 3. 4. 5. d c c d b 6. 7. 8. 9. 10. 21. Thirty percent of the expected product is not produced. Therefore, thirty percent of the limiting reactant must be part of reverse or side reactions. 22. Moles are used because the coefficients in a balanced equation show the number of moles of reactants and products in the chemical reaction. 23. The equation does not show other components of air, such as nitrogen and organic compounds. It also does not show impurities in gasoline, such as compounds of nitrogen and sulfur. During combustion, these substances are also oxidized, producing pollutants such as nitrogen, sulfur oxides, and hydrocarbons. In addition, the equation does not show that incomplete combustion can occur, in which case carbon monoxide is also produced. 1 mol KClO3 24. 100. g KClO3 122.5 g KClO3 74.55 g KCl 2 mol KCl 1 mol KCl 1 mol KClO3 c a c c c Quiz—Section: Limiting Reactants and Percentage Yield 1. 2. 3. 4. 5. b d c c b 6. 7. 8. 9. 10. c a d d b Quiz—Section: Stoichiometry and Cars 1. 2. 3. 4. 5. b c c c c 6. 7. 8. 9. 10. d b a b b 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. d b a d a c c b d a 60.8 g KCl 1.961 g CO 1 L CO2 1 mol CO2 1 mol MgCO 3 44.01 g CO2 1 mol CO2 84.31 g MgCO 3 244 g MgCO3 1 mol MgCO3 25. 65.0 L CO2 2 Chapter Test 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. d d b d a c b a a a Copyright © by Holt, Rinehart and Winston. All rights reserved. Holt Chemistry 90 Stoichiometry