Key Factors for Deep Cement Mixing Construction for Undredged Offshore Land Reclamation Downloaded from ascelibrary.org by Hong Kong University of Sci and Tech (HKUST) on 11/07/22. Copyright ASCE. For personal use only; all rights reserved. K. S. Yin 1; L. M. Zhang, F.ASCE 2; H. F. Zou 3; H. Y. Luo 4; and W. J. Lu 5 Abstract: Deep cement mixing (DCM) is an environmentally friendly technique for offshore ground improvement without dredging or much disturbance to the marine ecological system. Several field construction factors can influence the unconfined compressive strength (UCS) of cement-stabilized soil. In this study, key construction factors are evaluated referring to site investigation records, construction records, and quality test results of a large offshore DCM construction project. The key factors were attributed to geological conditions, construction procedures, and curing conditions. Specific field construction factors include fluctuations of tidal level, original soil type, volume fraction of injected water, volume fraction of injected cement slurry, injection rate of cement slurry, penetrating and mixing time per meter, curing age, and moisture content. The importance of these construction factors on the DCM strength has been quantified using a statistical method based on construction records. The injected water volume and original soil type are noted to be the two most dominant factors on the UCS of the treated soils. Longer mixing time improved the strength of the treated soils. DOI: 10.1061/(ASCE)GT.19435606.0002848. © 2022 American Society of Civil Engineers. Author keywords: Deep cement mixing (DCM); Ground improvement; Land reclamation; Offshore construction; Unconfined compressive strength (UCS); Marine deposit. Introduction Land reclamation is one way to ease the land shortage problem in coastal areas. Deep mixing is one of the most preferred techniques for undredged land reclamation due to its capability to improve the strength and stiffness of soft marine clays and avoid up-heave problems. This technique also minimizes disturbance to the natural marine ecological system from dredging activities. The deep mixing technique was originated in Japan in the late 1960s and adopted worldwide starting in the 1970s. The injected binders, either in the form of dry powder or wet slurry containing cement or lime, are mixed with in-situ soils during construction, forming columns or clusters of cemented binder–soil mixtures. This study concerns 1 Postdoctoral Research Associate, Dept. of Civil and Environmental Engineering, Hong Kong Univ. of Science and Technology (HKUST), Kowloon, Hong Kong 999077, China. ORCID: https://orcid.org/0000 -0003-1350-4497 2 Chair Professor and Head, Dept. of Civil and Environmental Engineering, Hong Kong Univ. of Science and Technology, Kowloon, Hong Kong 999077, China; Professor, HKUST Shenzhen-Hong Kong Collaborative Innovation Research Institute, Shenzhen 518000, China (corresponding author). ORCID: https://orcid.org/0000-0001-7208-5515. Email: cezhang@ ust.hk 3 Assistant Engineer, AECOM Asia Limited Company, 138 Shatin Rural Committee Rd., Hong Kong 999077, China. 4 Postdoctoral Research Associate, Dept. of Civil and Environmental Engineering, Hong Kong Univ. of Science and Technology, Kowloon, Hong Kong 999077, China. ORCID: https://orcid.org/0000-0002-2986 -9418 5 Postdoctoral Research Associate, Dept. of Civil and Environmental Engineering, Hong Kong Univ. of Science and Technology, Kowloon, Hong Kong 999077, China. ORCID: https://orcid.org/0000-0002-0526 -7471 Note. This manuscript was submitted on August 22, 2021; approved on April 25, 2022; published online on June 7, 2022. Discussion period open until November 7, 2022; separate discussions must be submitted for individual papers. This paper is part of the Journal of Geotechnical and Geoenvironmental Engineering, © ASCE, ISSN 1090-0241. © ASCE deep cement mixing (DCM) widely used in offshore undredged land reclamations. DCM improves the consistency, shear strength, deformation characteristics, and permeability of natural marine soils for practical engineering purposes, including bearing capacity improvement, settlement reduction, seepage control, and excavation support. Famous land reclamation projects involving largescale DCM include the second-phase artificial island of Kansai International Airport (Furudoi 2005) and the D-runway project of Haneda International Airport (Watabe and Noguchi 2011). Laboratory tests and numerical analyses have been performed to evaluate the mechanical characteristics of DCM-improved soil considering numerous factors, including water content (Horpibulsuk et al. 2012), stress concentration ratio (Jiang et al. 2013), column diameter, length and distribution (Liu et al. 2012), column stiffness (Yapage et al. 2014), column material (Abusharar et al. 2009), column permeability (Yin and Fang 2006), surrounding soil properties (Rogers and Glendinning 1997), and penetration ratio (Yang et al. 2014). Other studies investigated key contributory factors to DCM mixture strength, including soil type, water content, binder amount and type, curing period, mixing time, and humidity (Kitazume et al. 2015; Mohammadinia et al. 2019; Disfani et al. 2021; Subramaniam and Banerjee 2020; Bellato et al. 2020). The unconfined compressive strength (UCS) of cement–soil mixtures exhibited significant spatial variation (Lee et al. 2006; Chen et al. 2011; Wijerathna and Liyanapathirana 2018, 2019), with measured autocorrelation distances ranging from far less than a cluster’s diameter to around 50 m (Honjo 1982; Larsson et al. 2005a, b; Navin 2005), indicating the heterogeneous nature of DCM strength (Chen et al. 2016). Some empirical relations were proposed to predict the UCS of cement–soil mixtures (Horpibulsuk et al. 2003; Lorenzo and Bergado 2004; Lee et al. 2005). Although the relationships between DCM strength and strengthimprovement factors have been investigated, most were based on laboratory tests under controlled conditions, which could significantly deviate from conditions in the field. It is necessary to investigate and quantify the impacts of actual field conditions, facilities, specifications, and techniques on DCM-treated offshore 04022063-1 J. Geotech. Geoenviron. Eng., 2022, 148(8): 04022063 J. Geotech. Geoenviron. Eng. (a) DCM Construction 500 BH-5 Test DCM Borehole BH-4 Longitude distance (m) Downloaded from ascelibrary.org by Hong Kong University of Sci and Tech (HKUST) on 11/07/22. Copyright ASCE. For personal use only; all rights reserved. soils. The significance level of impacts from the actual construction process may be evaluated based on the recorded construction data. This study aimed to identify the mechanisms and key construction factors that influence DCM quality indicated by the homogeneity and magnitude of UCS. The construction process of a practical offshore DCM project was investigated in close association with cement–soil chemical and physical reactions. The main objective was to assess the impact of key construction factors on the DCM strengths in dominant types of natural marine deposits referring to site investigation records, construction monitoring records and quality assessment test results. 400 Site Condition BH-3 300 BH-2 200 BH-6 BH-7 BH-1 100 BH-8 0 0 200 400 600 800 1000 1200 Latitude distance (m) (b) Fig. 1. Study site information: (a) soil stratification records; and (b) plan view of test DCM clusters and boreholes. Table 1. Properties of the marine deposit at study site Properties Range Plastic limit (%) Liquid limit (%) Plasticity index (%) Clay content Silt content Sand content Gravel content Void ratio at p00 ¼ 1 kPa Compression index Natural moisture content (%) Saturated density (kN=m3 ) 21–59 44–91 22–59 0.39–0.55 0.40–0.42 0.12–0.19 0.01–0.09 1.54–1.93 0.42–0.53 43–124 12.5–18.4 The study site was at the Pearl River estuary in the south China Sea, where the stratigraphy of seabed soil can be divided into five categories along depth: marine clay, alluvial crust, lower alluvium deposit, completely decomposed granite, and bedrock. Subsoil profiles from eight boreholes at the site prior to DCM construction are shown in Fig. 1(a). Soft silty clay and sandy– silty clay dominated above −25 mPD, beneath which lay granular deposits, including sand, silt, and gravel. To lower disturbances to the marine ecological system, the seabed mud was not dredged but improved with more than 4,000 DCM columns involving 630,000 m3 of marine soil. The properties of the marine deposits prior to DCM construction are summarized in Table 1. The deposits were mainly composed of clayey and silty soils with natural moisture content occasionally over 100%. The average depth of DCM clusters was −30mPD, with the majority located within the clay layer. Selected DCM clusters were cored and tested after construction for quality check. The layout of the test columns is shown in Fig. 1(b). DCM Construction Procedure The offshore DCM was conducted using special barges equipped with mixing units, leaders, pumping units, slurry agitators, binder silos, power plants, and operation rooms, shown in Fig. 2(a). Wet cement slurry instead of dry powder was applied as the DCM cementing material in this project to achieve higher homogeneity of the stabilized soil, more uniform strength along depth, and smoother penetration in competent strata. The primary components Fig. 2. Sketches of (a) DCM barge; (b) DCM mixing unit; and (c) arrangement of mixing shafts for a DCM cluster. © ASCE 04022063-2 J. Geotech. Geoenviron. Eng., 2022, 148(8): 04022063 J. Geotech. Geoenviron. Eng. Table 2. Numbers of coring samples for quality testing Curing age group Dominant soil type Downloaded from ascelibrary.org by Hong Kong University of Sci and Tech (HKUST) on 11/07/22. Copyright ASCE. For personal use only; all rights reserved. Clayey soils Silty soils Sandy soils Gravelly soils Total Fig. 3. Pattern of installed DCM panels. of the mixing unit are shown in Fig. 2(b). A single mixing cluster involved four shafts with an overlapped area between two adjacent clusters, as illustrated in Fig. 2(c). The DCM clusters were designed as separate panels to enhance the stability of the seawall in the tangent direction (Fig. 3). The plan view of the DCM panels and their designed embedded depths, levels of installation and competent stratum, required unconfined compressive strengths (RUCSs), and cement slurry injection rates are shown in Fig. 4. The design installation depth followed the tentative level of competent strata. The cement was ordinary portland cement. In the mix design, the water–cement ratio (w=c) of the cement slurry was set at 0.8, which corresponded to a wet density of 1,641 kg=m3 . The injected water during the penetration stage and natural soil water were not included in the design w=c ratio. The cement dosage for mixing cement slurry was approximately 260 kg=m3. The volume fraction of injected cement slurry measures the cement content per DCM cluster in practice. The construction started by installing a geotextile layer and sand blanket. Subsequently, the DCM barge was anchored at a designated location, followed by the penetration of the mixing units into the marine soils with the mixing shafts rotating. During the penetration stage, the blades attached to the mixing shaft end broke and disturbed the soil, reducing its strength, allowing the mixing shafts to be driven by their self-weight. The average volume fraction of injected water during the penetration stage reached 12% for 28–40 days 40–60 days 60–80 days 1,071 48 57 0 1,176 623 28 39 32 722 446 38 17 16 517 a single cluster in this study. The penetration was terminated when the mixing shafts reached the designed embedded depth within the competent stratum. The bottom treatment was then conducted to assure a sufficient shaft resistance of the DCM cluster in the competent soil layer. Finally, in the withdrawal stage, the mixing unit mixed the cement slurry and the surrounding soil horizontally at a fixed rotating speed, providing a cross-section of the DCM clusters, as shown in Fig. 2(c). The cement slurry injection rate for bottom treatment and withdrawal was set as equal, from 0.48 to 0.57 m3 per minute. The penetrating and withdrawal mixing rates were estimated at 0.45 and 0.28 m per minute. DCM Quality Tests After the completion of DCM construction, the stabilized cement– soil mixture was sampled and tested for uniformity, continuity, dimensions, and permeability. The verification of quality was conducted with full-depth coring and unconfined compression tests at various curing ages, from 28 to 80 days. The detailed sample sizes are summarized in Table 2. The measured results and frequency statistics are shown in Fig. 5. The Kolmogorov–Smirnov test was performed for normality checking, suggesting that the measurements do not strictly follow the normal distribution at confidence level of 0.05. From the measured UCS values of cored DCM specimens, the design strength requirements were exceeded substantially. The actual average UCS of 3.12 MPa was more than twice the design value [Fig. 4(d)]. The interval of the natural soil moisture content (Table 1) was also reduced from 0.43–1.24 to 0.036–0.956, demonstrating the effectiveness of DCM. Fig. 4. Construction layout of DCM clusters in longitudinal direction: (a) design installation level; (b) design embedded depth; (c) tentative level of competent stratum; (d) required unconfined compressive strength (RUCS); and (e) cement slurry injection rate. © ASCE 04022063-3 J. Geotech. Geoenviron. Eng., 2022, 148(8): 04022063 J. Geotech. Geoenviron. Eng. 0.16 Mean: 3.12 MPa COV: 0.45 p-value (KS test): 1.31E-13 0.12 0.10 0.08 0.06 0.04 0.02 0.00 0 (a) 2 4 6 8 UCS (MPa) 0.16 Mean: 45.95 % COV: 0.27 p-value (KS test): 5.7E-6 Relative Frequency 0.14 0.12 0.10 0.08 0.06 0.04 0.02 0.00 0 20 40 60 80 Moisture content (%) (b) 0.16 0.14 Relative Frequency Downloaded from ascelibrary.org by Hong Kong University of Sci and Tech (HKUST) on 11/07/22. Copyright ASCE. For personal use only; all rights reserved. Relative Frequency 0.14 0.12 Mean: 1639.43 kg/m3 COV: 0.046 p-value (KS test): 0.047 0.10 0.08 0.06 0.04 0.02 0.00 1400 1500 1600 1700 1800 1900 2000 2100 Density (kg/m3) (c) Fig. 5. Quality assurance test results from sampled DCM clusters: (a) unconfined compressive stress (UCS); (b) moisture content; and (c) density. Identification of Construction Impact Factors Micromechanism of Cement–Soil Strength Formation Micromechanisms of strength formation of cement-stabilized soil can refer to the chemical reactions (i.e. cement hydration, cation exchange, and pozzolanic reactions) and physical contacts between soil particles and cement slurry shown in Fig. 6. Cement hydration is a collection of chemical reactions operating in series, primarily the reaction between water and the cement calcium silicate with tricalcium aluminate, which produce an alkaline environment with calcium hydroxide, hydrated calcium silicate, and calcium aluminate gels that harden with time (Bullard et al. 2011). The amounts of basic reactants, such as cement dosage, cement slurry quality, and water volume, can influence the hydration reactions. Negatively charged silicate particles from natural marine soils are attached with some cations, including Naþ and Kþ . Equivalent exchange can occur immediately between these positive ions and calcium ions released from the calcium hydroxide, reducing water adsorption of the clay particles. The increased electric charge decreases the repulsion between the negatively charged clay particles and the thickness of the adsorbed water layer, gradually forming © ASCE flocculation. Factors that impact the cation exchange with flocculation during deep mixing include the natural soil type and water content. With the calcium ions continuously accumulating, the active calcium ions can react with the silica and alumina from the soil in an alkaline environment, generating hydrated calcium silicate (CSH) and hydrated calcium aluminate (CAH) cementitious matrices with a fibrous crystal structure (Sherwood 1993). The exposed positive ions continuously adsorb hydroxide ions, forming solidification wrapping around the soil particle. This process is the so-called pozzolanic reaction, which is sensitive to soil type with different concentrations of silica, alumina, and water as reactants. Furthermore, the long-period reaction in an alkali environment can be impacted by disturbance to the alkalinity during DCM construction. Among the previous chemical reactions, physical contact [Fig. 6(b)] plays an important role. Various contact degrees of cement slurry with soil particles can occur during DCM construction. When the soil particle surface was isolated from the adhesion of other substances, the voids between them were filled with cement slurry, leading to an ideal reinforcement effect. The soil grains and pore water can obstruct the pore channel, resulting in partial filling with less contact. Some soil aggregates may not be fully crushed 04022063-4 J. Geotech. Geoenviron. Eng., 2022, 148(8): 04022063 J. Geotech. Geoenviron. Eng. Downloaded from ascelibrary.org by Hong Kong University of Sci and Tech (HKUST) on 11/07/22. Copyright ASCE. For personal use only; all rights reserved. Fig. 6. Mechanism of strength gain of cement stabilized soil referring to: (a) chemical reactions; and (b) physical contact between cement slurry and soil aggregates. during the penetration and mixing process, and the cement slurry only wraps on their interfaces without filling the voids. Construction Impact Factors The UCS of DCM mixtures can be influenced by binder characteristics, soil conditions, mixing conditions, and curing conditions (Terashi 1997) based on laboratory studies. However, many of the conditions cannot be well controlled in field conditions, and how the strength of cement-stabilized soil behavior is influenced by construction techniques and site conditions has not been fully explored in the previously reported studies in the literature. In this study, given the illustrated DCM construction workflow and the mechanisms of DCM strength formation shown in Fig. 7, several key construction factors that may influence the DCM final strength are identified. These factors are associated with construction site conditions, construction procedures, and curing conditions. Impact factors related to construction site conditions include fluctuation of tidal level (m/hour) and soil type. Large fluctuations of tidal level can disturb the mixing shafts and blades during the penetration, lifting, and mixing stages of DCM construction, leading to partial contact between cement slurry and soil aggregates. Different soil types provide varied cation exchange capacities because the cations can be held by the negatively charged particles of fine-grained soils with thin and plate structures, and sand cannot exchange cations without electrical charge. Hence, soils with a © ASCE higher clay fraction adsorb metal ions better than sandy soils, leading to a higher concentration of adsorbed calcium ions during cation exchange (e.g., Manrique et al. 1991). Furthermore, the varying silica and aluminate and pH levels in different soils can affect the pozzolanic reaction. The soil pore structure provides distinct permeability properties, which may also affect the heterogeneity of the strength of DCM treated soil. Macropores (>0.075 mm) are more abundant in coarse-grained soils (sandy soils), accounting for about 35%–50% of the overall pore volume, whereas fine-grained soils (silty and clayey soils) are dominated by micropores (<0.03 mm) and have smaller particle spacing (SSGTC and SSSA 2008). The key factors related to the construction procedure include the volume fraction of injected water, volume fraction of injected cement slurry, cement injection rate (m3 =min), and penetrating and mixing time per meter (min=m). The volume fraction of injected water is the ratio of the injected water volume during penetration to the bulk volume of a single DCM cluster, representing the water quantity for each cluster. Water is a reactant involved in hydration, cation exchange, and pozzolanic reactions. Nevertheless, excessive water can reduce the concentration of other reactants and the environmental alkalinity in chemical reactions and increase water pockets not filled by cement slurry, leading to strength reduction. The volume fraction of injected cement slurry indicates the cement quantity as a basic reactant for hydration. The produced calcium hydroxide also participates in subsequent cation exchange and pozzolanic reactions, contributing to the strength gain of the 04022063-5 J. Geotech. Geoenviron. Eng., 2022, 148(8): 04022063 J. Geotech. Geoenviron. Eng. Downloaded from ascelibrary.org by Hong Kong University of Sci and Tech (HKUST) on 11/07/22. Copyright ASCE. For personal use only; all rights reserved. Fig. 7. Workflow of DCM mixing unit and associated key factors affecting strength formation. cement–soil mixture. A higher cement injection rate can provide greater initial kinetic energy of cement slurry from nozzles, facilitating the cement slurry to permeate into the voids between soil particles more thoroughly at the bottom treatment, lifting, and mixing stages. At the penetrating and mixing stages, the mixing units crushed the natural soil mass into small aggregates through cutting blades, allowing sufficient contact between the soil particles and the injected cement slurry. Increasing penetration and mixing time can increase the contact surface area and accelerate the second phase of the cement hydration and pozzolanic reaction. The influence of the curing condition is observed through test samples’ age and moisture content. The pozzolanic reaction can last months to years for long-term strength formation, leading to the variation of sample strength at different ages. The moisture contents of cored samples indicate wetness at the curing stage. Excessive water can reduce the alkalinity and concentration of silica and alumina for pozzolanic reactions during the curing stage. Considering water injection during construction, the multiple stages of pozzolanic reaction, and the hydrate crystal products, the curing moisture content at time of coring is used as a direct field indicator to indicate the water content in DCM samples rather than the moisture content in natural soil. Interpretation of Construction Effects Based on Field Records In order to quantify the influence of each key in-situ construction factor, project field records were analyzed along with the construction conditions and measured DCM strengths. Processing of Field Records According to the site borehole records and geotechnical site investigations, the average UCS of cored DCM-stabilized soil mixtures was calculated for four principal soil types: clayey, silty, sandy, and gravelly soils. This study grouped curing ages into four sets from © ASCE 28 to over 80 days in 20-day intervals. The increase of cementstabilized soil strength tended to level off beyond 60 days when the initial water content of the original soil was high. The whole DCM construction was performed in the marine area and under the seabed level, and water was injected while penetrating the soil for protecting the mixing units and smoothing the penetration process. The injected water and cement slurry volumes were recorded in the penetrating and mixing stages. These volumes were transformed into volume fractions by dividing the individual bulk volume of the tested DCM column to normalize the influence of the DCM cluster size. The scatterplots of the average UCS versus seven influence factors for marine clay are presented in Fig. 8, reflecting the quantity and fluctuation of UCS with these factors. The coefficients of variation (COV, ratio of standard deviation and mean) of UCS associated with these factors are shown in Fig. 9. The COV reflects the homogeneity level of UCS in the construction site. A greater value of COV indicates decreased homogeneity of UCS and greater uncertainty from the influence factors. The average UCS and the COV for dominant natural soil types are summarized in Fig. 10. Importance of Influence Factors Sensitivity analysis was performed to identify the key construction factors that impact the strength and uniformity of DCM constructions, based on the out-of-bag (OOB) importance estimation. The OOB estimation measures how influential the predictor variables (i.e., DCM construction factors) are in predicting the response (i.e. observed UCS) by permutation using a random forest model (e.g., Altmann et al. 2010). The influence of a particular construction factor can be manifested by the variation of model error by random permutations. If a construction factor has a greater influence on the UCS, then permutating its value should affect the model error significantly, whereas if a construction factor is not influential, there will be little variation of the model error after permutating its value. The error difference assuming a random forest model of T trees and P predictors is shown as follows: 04022063-6 J. Geotech. Geoenviron. Eng., 2022, 148(8): 04022063 J. Geotech. Geoenviron. Eng. dtj ¼ εtj − εt ¼ Pn i¼1 ðyi − ŷbag;tj Þ2 − n Pn i¼1 ðyi − ŷtj Þ2 n observations for each predictor variable j ¼ 1; : : : ; P, the generated UCS ŷbag and model error εtj can be estimated. The OOB predictor importance can be quantified by the ratio between the difference of errors averaged over all trees and the standard deviation dj =σj . The larger the ratio dj =σj , the more influence the key factor has on the DCM. The results of the predictor ð1Þ Average UCS (MPa) 8 8 8 8 7 7 7 7 6 6 6 6 5 5 5 5 4 4 4 4 3 3 3 3 2 2 2 2 1 1 0 0 0.2 0.3 0.4 0.48 0.50 (a) Average UCS (MPa) 0.52 0.54 0.56 0.58 1 1 0 0 Injection rate (m3 /min) Tidal fluctuation (m/h) 7 7 7 6 6 6 5 5 5 4 4 4 3 3 3 2 2 2 1 1 1 2.5 0.15 3.0 3.5 4.0 0 3.0 3.3 Penetration unit time (min/m) 3.6 0 10 3.9 Mixing unit time (min/m) 20 0.25 0.30 0.27 0.30 30 40 50 0.33 0.36 0.39 0.42 Injected slurry volume fraction (d) 60 70 80 Moisture content (%) (f) (e) 0.20 (c) 8 2.0 0.10 (b) 8 1.5 0.05 Injected water volume fraction 8 0 1.0 (g) COV of UCS Fig. 8. Relationships between the average UCS of marine clay and key DCM construction factors: (a) tidal fluctuation (m=h); (b) injection rate (m3 =min); (c) injected water volume fraction; (d) injected slurry volume fraction; (e) penetration unit time (min/m); (f) mixing unit time (min/m); and (g) moisture content (%). 1.0 1.0 1.0 1.0 0.8 0.8 0.8 0.8 0.6 0.6 0.6 0.6 0.4 0.4 0.4 0.4 0.2 0.2 0.2 0.2 0.0 0.2 0.3 0.0 0.4 Tidal fluctuation (m/h) 0.48 0.50 0.52 0.54 Injection rate 0.56 0.58 0.0 (m3 /min) 1.0 0.8 0.8 0.8 0.6 0.6 0.6 0.4 0.4 0.4 0.2 0.2 0.2 2.0 2.5 3.0 3.5 Penetration unit time (min/m) (e) 0.15 4.0 0.0 3.0 3.3 0.20 0.25 0.30 (c) 1.0 1.5 0.10 Injected water volume fraction 1.0 0.0 1.0 0.05 (b) (a) COV of UCS Downloaded from ascelibrary.org by Hong Kong University of Sci and Tech (HKUST) on 11/07/22. Copyright ASCE. For personal use only; all rights reserved. where for each tree t ¼ 1; : : : ; T; n = number of samples; εt = OOB error estimated by the mean squared error; yi = observed UCS; and ŷ = predicted UCS from the model. After randomly permutating the 3.6 3.9 0.0 10 Mixing unit time (min/m) (f) 20 30 40 50 0.0 0.27 0.30 0.33 0.36 0.39 0.42 Injected slurry volume fraction (d) 60 70 80 Moisture content (%) (g) Fig. 9. Relationships between the COV of UCS of marine clay and key DCM constructions factors: (a) tidal fluctuation (m=h); (b) injection rate (m3 =min); (c) injected water volume fraction; (d) injected slurry volume fraction; (e) penetration unit time (min/m); (f) mixing unit time (min/m); and (g) moisture content (%). © ASCE 04022063-7 J. Geotech. Geoenviron. Eng., 2022, 148(8): 04022063 J. Geotech. Geoenviron. Eng. 28-40days 40-60days 60-80days 0.7 3 2 28-40days 40-60days 60-80days 0.6 COV of UCS Average UCS (MPa) Downloaded from ascelibrary.org by Hong Kong University of Sci and Tech (HKUST) on 11/07/22. Copyright ASCE. For personal use only; all rights reserved. 4 0.5 0.4 0.3 0.2 1 0.1 0 Clayey CLAY soils Silty SILT soils Sandy SAND soils 0.0 Gravelly GRAVEL soils Dominant soil type Clayey CLAY soils Silty SILT soils Sandy SAND soils Gravelly GRAVEL soils Dominant soil type Fig. 10. Average and COV of UCS from DCM samples for varied natural dominant soil types. Fig. 11. Out-of-bag permuted predictor importance estimates for key factors from offshore DCM construction. A larger value suggests a greater influence. importance estimates for all key factors are summarized in Fig. 11. As can be seen, for the DCM offshore construction project, the amount of water injected during drilling and type of native soil are the most important factors, whereas the difference in grouting rate in the range of 0.48–0.58 m3 =min does not affect the strength substantially. Influence of Key Factors The influence of nine key factors on the UCS was demonstrated referring to the strengths of cored samples and strength gain mechanisms of cement–soil mixtures. Original dominant soil type. Based on borehole records, four dominant soil types were involved: clayey, silty, sandy, and gravelly soils. The average UCS of the DCM samples was approximately 2.5 MPa. The UCS of the samples originating in marine clay was the highest, leading by almost 0.5 MPa for all ages compared to DCM mixtures in other soil types [Fig. 10(a)]. The inherent difference in dominant soils’ cation exchange capacity (CEC) could be considered a contributing factor for strength gains in different types of soil. The marine clays had the highest clay fraction, composed of negatively charged clay particles with greater CEC than other dominant soil types. Therefore, a higher concentration of calcium ions adsorbed to clay particles can be achieved from © ASCE cation exchange, which further influences the pozzolanic reactions that form long-term strength. There was an ascending trend in the COV from marine clay to gravel, indicating that the homogeneity level of UCS becomes lower with increasing particle size or coarse content. It is reasonable because large voids are more likely to form when the soil aggregates are large, which easily introduce varied cement slurry saturation degrees when the same construction technique is applied to all soil types during DCM construction. An exception was the COV for silt soil, which was larger than the COV for sandy soil. One explanation is that silt soil has a dualporosity structure compared to clays and sand, and its mechanical behavior is controlled by soil aggregates and coarse particles together (e.g., Zhao et al. 2013). This structure with large interaggregate pores leads to varying degrees of permeation of cement slurry into the voids during construction [Fig. 6(b)], possibly leading to heterogeneity in the treated soil. Fluctuation of tidal level. Another potential disturbance of offshore DCM construction is the tidal impact on the mixing units on the DCM barge. Reduction of the average UCS and large fluctuations in the COV could be observed after tidal fluctuation reached 0.38 m per hour [Fig. 8(a)]. Large tidal fluctuations may introduce vibrations of the mixing shafts and blades that operate in the lifting and rotating stages. Such vibrations may disturb the mixing unit 04022063-8 J. Geotech. Geoenviron. Eng., 2022, 148(8): 04022063 J. Geotech. Geoenviron. Eng. Downloaded from ascelibrary.org by Hong Kong University of Sci and Tech (HKUST) on 11/07/22. Copyright ASCE. For personal use only; all rights reserved. to varying extents and produce uneven contact conditions between the soil particles and cement slurry, leading to uncertainty in the homogeneity of cement-stabilized soil. Volume fraction of injected water. The volume fraction of injected water, primarily in the range of 0.05–0.30, represents the volume of injected water for protecting the mixing unit and smoothening the penetration activity. It does not include the water in the natural soils and cement slurry. The average UCS decreases with increasing injected water volume, from an initial 3.5 MPa to around 2.5 MPa [Fig. 8(c)]. Although the injected water constitutes the primary reactant for the hydration and pozzolanic reactions in the cement soil mixtures, excessive water injection can reduce the alkalinity of the environment and concentration of other reactants involved in the cation exchange, hydration, and pozzolanic reactions. The redundant water contributes to the separation of soil aggregates by water pockets, leading to reduced UCS. Volume fraction of injected cement slurry. The average UCS increased with the injected volume fraction of cement slurry in the range of 0.27–0.42 [Fig. 8(d)]. Cement slurry is the main reactant for generating hydrated calcium-based gels and forming cementitious matrices with a fibrous crystal structure, which dominates the strength formation of cemented soils. The increased volume fraction of cement slurry directly improves the principal components contributing to the strength. The COV reached a minimum value at around 0.2 when the injected slurry increased to 0.41 [Fig. 9(d)]. Injection of sufficient cement slurry ensures the cement slurry fills the off-contact gaps between soil aggregates, contributing to higher physical contact degree and homogeneity of strength. The COV was high initially. When the amount of cement slurry injected is low, only part of the pores in the soil are filled, thus producing a nonuniform distribution of hydration products. When the injected volume rises, more pores are filled and the reactants are in good contact, leading to a reduced COV. Cement slurry injection rate. A higher cement slurry injection rate provides larger kinetic energy of cement slurry from the nozzles of the mixing units, improving the contact degree of cement slurry and soil aggregates. The injection rate ranges between 0.48 and 0.57 m3 =min, leading to approximately 0.35 m3 =m of the grout volume fraction under identical mixing time per meter. The average UCS and COV [Figs. 8(b) and 9(b)] varied little within this range of injection rate, as did the grout penetration in soil aggregates. The effect of the change in grout volume per unit time on the UCS can be obscured by the variation of the volume fraction of cement slurry. Hence this factor is the least sensitive construction factor in terms of the estimated OOB importance (Fig. 11). Penetrating time per meter. When mixing units are drilled through a stiff soil layer or a hard obstruction during the penetration stage, additional time is required, and a larger amount of water will be injected to protect the mixing units and smooth the penetration process. Therefore, the average UCS and COV variations with penetration time per meter [Figs. 8(e) and 9(e)] are similar to those of the injected water volume fraction. As mentioned, the drilling process broke up large soil clods into smaller pieces and improved the contact conditions of the cementation reactants. However, the drilling process was accompanied by water injection, so its effect on strength was overshadowed by the dominant factor, water volume, as illustrated in Fig. 11. Mixing time per meter. With the increased mixing time from 3.1 to 3.9 min per meter, the average UCS improved from an initial 3 to 3.5 MPa [Fig. 8(f)], and the homogeneity level of UCS also improved, indicated by a decrease in the COV [Fig. 9(f)]. The increased mixing time per meter ensures the mixing blades thoroughly cut the original soil aggregates into small pieces and increases the contact area of the reactants for chemical reactions © ASCE associated with the strength gain of cement–soil mixtures. The increased mixing time also reduces the incomplete filling of the voids between soil aggregates by the cement slurry, leading to improved homogeneity. Age. Cement-stabilized soil strength grows slowly over 60 days when the initial water content of the natural soils is high (Kawasaki et al. 1981). Indeed, in this project, the magnitude and homogeneity level of strength increased substantially during the curing ages of 28–60 days for marine clayey, silty, and sandy soils, as shown in Fig. 10. With the increasing curing age, the pozzolanic reactions tend to complete, with more cemented calcium silicate and calcium aluminate hydrate accumulating and surrounding the soil particles, improving the cementation strength. After 60 days, the UCS for the silty and gravelly marine soils reached a stabilized level, but those for the clayey and sandy soils continued to grow. This can be explained by the difference in the pore structure. Both the dualporosity structure of the silty soil with coarse particles and the macropores of gravelly soils introduce high permeability characteristics, allowing ease of fluid flow. With water infiltration, the environmental alkalinity decreases, and the concentration of activated calcium ions is diluted. Therefore, the reduced concentration of reactants in the pozzolanic reaction leads to a mitigated reaction degree and stabilized strength. Moisture content. The moisture content of the cement–soil mixture was measured during the UCS test [Figs. 8(g) and 9(g)]. The average UCS gradually decreased to around 2 MPa at a moisture content of 80% in the cement–soil mixtures. The initial water in the cement–soil mixture serves as a reactant for pozzolanic reactions. However, the excessive amount of water can decrease the concentration of reactants and the alkaline chemical reaction environment, which then delays the long-term strength formation process of cement-stabilized soils. Large fluctuations in COV are observed after the moisture content is greater than 60% for different curing ages. High moisture content can cause uneven distribution of excessive water, which requires additional time to react with the silica and alumina from the soil and calcium hydroxide during pozzolanic reactions, leading to the varying COV at different curing ages. Summary and Conclusions Compared to traditional dredged land reclamation methods, offshore DCM construction is more environmentally friendly without dredging or disturbance to the marine ecological system. An offshore DCM project for undredged land reclamation was evaluated to identify key construction factors that affect the homogeneity and magnitude of UCS. These factors are related to geological conditions, construction procedures, curing conditions, and chemical and physical mechanisms of cement-stabilized soils. Several conclusions can be drawn: 1. The impact on the UCS from the volume fraction of injected water and the natural moisture content is most significant among all the evaluated factors from offshore DCM construction. The volume of injected water must be carefully calibrated, especially when the marine soils to be treated have high natural water contents. Additional injected water at the penetration stage may exceed the hydration and pozzolanic requirements and decrease the concentration of other reactants and alkalinity of the environment, affecting the strength formation of cement-stabilized soils. 2. The varying soil types at the construction site significantly impacted the UCS of offshore DCM in terms of both homogeneity and magnitude. Due to the inherent variation of the cation 04022063-9 J. Geotech. Geoenviron. Eng., 2022, 148(8): 04022063 J. Geotech. Geoenviron. Eng. Downloaded from ascelibrary.org by Hong Kong University of Sci and Tech (HKUST) on 11/07/22. Copyright ASCE. For personal use only; all rights reserved. exchange capability, fine-grained marine soils with high clay fractions generate greater cement–soil mixture strength compared to coarse-grained sandy soils. Hence specific injection and mixing methodologies should be recommended for different soils, including using extra mixing time and cement slurry injection to ensure adequate cutting effects of mixing blades and increase the contact degree between the cement slurry and soil aggregates. 3. Longer mixing time during construction did not reduce the UCS but promoted it, whereas large tidal-level fluctuations may lead to vibrations of the mixing units and produce strength variations. 4. The strength of DCM increases with curing age within a curing age up to 80 days for the dominant clayey and sandy marine soils. For silty and gravelly soils, the UCS appeared to reach a stabilized level 60 days after the DCM treatment. Data Availability Statement Some or all data, models, or code generated or used during the study are available from the corresponding author by request. Acknowledgments The work presented in this paper was substantially supported by Eunsung O&C Offshore Marine and Construction (No. EUNSUNG19EG01). References Abusharar, S. W., J. J. Zheng, and B. G. Chen. 2009. “Finite element modelling of the consolidation behavior of multi-column supported road embankment.” Comput. Geotech. 36 (4): 676–685. https://doi.org/10 .1016/j.compgeo.2008.09.006. Altmann, A., L. Toloşi, O. Sander, and T. Lengauer. 2010. “Permutation importance: A corrected feature importance measure.” Bioinformatics 26 (10): 1340–1347. https://doi.org/10.1093/bioinformatics/btq134. Bellato, D., I. P. Marzano, and P. Simonini. 2020. “Microstructural analyses of a stabilized sand by a deep-mixing method.” J. Geotech. Geoenviron. Eng. 146 (6): 04020032. https://doi.org/10.1061/(ASCE)GT.1943-5606 .0002254. Bullard, J. W., H. M. Jennings, R. A. Livingston, A. Nonat, G. W. Scherer, J. S. Schweitzer, and J. J. Thomas. 2011. “Mechanisms of cement hydration.” Cem. Concr. Res. 41 (12): 1208–1223. https://doi.org/10 .1016/j.cemconres.2010.09.011. Chen, E. J., Y. Liu, and F. H. Lee. 2016. “A statistical model for the unconfined compressive strength of deep-mixed columns.” Géotechnique 66 (5): 351–365. https://doi.org/10.1680/jgeot.14.P.162. Chen, J., F. H. Lee, and C. C. Ng. 2011. “Statistical analysis for strength variation of deep mixing columns in Singapore.” In Geo-frontiers: Advances in geotechnical engineering, GSP No. 211, edited by J. Han and D. E. Alzamora, 576–584. Reston, VA: ASCE. Disfani, M. M., A. Mohammadinia, A. Arulrajah, S. Horpibulsuk, and M. Leong. 2021. “Lightly stabilized loose sands with alkali-activated fly ash in deep mixing applications.” Int. J. Geomech. 21 (3): 04021011. https://doi.org/10.1061/(ASCE)GM.1943-5622.0001958. Furudoi, T. 2005. “Second phase construction project of Kansai International Airport—Large-scale reclamation works on soft deposits.” In Vol. 16 of Proc. of the Int. Conf. on Soil Mechanics and Geotechnical Engineering, 313. Amsterdam, Netherlands: IOS Press BV. Honjo, Y. 1982. “A probabilistic approach to evaluate shear strength of heterogeneous stabilized ground by deep mixing method.” Soils Found. 22 (1): 23–38. https://doi.org/10.3208/sandf1972.22.23. Horpibulsuk, S., A. Chinkulkijniwat, A. Cholphatsorn, J. Suebsuk, and M. D. Liu. 2012. “Consolidation behavior of soil-cement column © ASCE improved ground.” Comput. Geotech. 43 (Jun): 37–50. https://doi .org/10.1016/j.compgeo.2012.02.003. Horpibulsuk, S., N. Miura, and T. S. Nagaraj. 2003. “Assessment of strength development in cement-admixed high-water content clays with Abrams’ law as a basis.” Géotechnique 53 (4): 439–444. https://doi.org /10.1680/geot.2003.53.4.439. Jiang, Y., J. Han, and G. Zheng. 2013. “Numerical analysis of consolidation of soft soils fully penetrated by deep-mixed columns.” KSCE J. Civ. Eng. 17 (1): 96–105. https://doi.org/10.1007/s12205-013-1641-x. Kawasaki, T., A. Niina, S. Saitoh, Y. Suzuki, and Y. Honjo. 1981. “Deep mixing method using cement hardening agent.” In Vol. 3 of Proc., 10th Int. Conf. on Soil Mechanics and Found. Eng., 721–724. London: ISSMGE. Kitazume, M., M. Grisolia, E. Leder, I. P. Marzano, A. A. S. Correia, P. J. V. Oliveira, and M. Andersson. 2015. “Applicability of molding procedures in laboratory mix tests for quality control and assurance of the deep mixing method.” Soils Found. 55 (4): 761–777. https://doi.org/10 .1016/j.sandf.2015.06.009. Larsson, S., M. Dahlström, and B. Nilsson. 2005a. “A complementary field study on the uniformity of lime-cement columns for deep mixing.” Proc. Inst. Civ. Eng. Ground Improv. 9 (2): 67–77. https://doi.org/10 .1680/grim.2005.9.2.67. Larsson, S., M. Dahlström, and B. Nilsson. 2005b. “Uniformity of limecement columns for deep mixing: A field study.” Proc. Inst. Civ. Eng. Ground Improv. 9 (1): 1–15. https://doi.org/10.1680/grim.2005.9.1.1. Lee, F. H., C. H. Lee, and G. R. Dasari. 2006. “Centrifuge modelling of wet deep mixing processes in soft clays.” Géotechnique 56 (10): 677–691. https://doi.org/10.1680/geot.2006.56.10.677. Lee, F. H., Y. Lee, S. H. Chew, and K. Y. Yong. 2005. “Strength and modulus of marine clay–cement mixes.” J. Geotech. Geoenviron. Eng. 131 (2): 178–186. https://doi.org/10.1061/(ASCE)1090-0241(2005)131:2(178). Liu, S. Y., Y. J. Du, Y. L. Yi, and A. J. Puppala. 2012. “Field investigations on performance of T-shaped deep mixed soil cement column–supported embankments over soft ground.” J. Geotech. Geoenviron. Eng. 138 (6): 718–727. https://doi.org/10.1061/(ASCE)GT.1943-5606.0000625. Lorenzo, G. A., and D. T. Bergado. 2004. “Fundamental parameters of cement-admixed clay—New approach.” J. Geotech. Geoenviron. Eng. 130 (10): 1042–1050. https://doi.org/10.1061/(ASCE)1090-0241(2004) 130:10(1042). Manrique, L. A., C. A. Jones, and P. T. Dyke. 1991. “Predicting cationexchange capacity from soil physical and chemical properties.” Soil Sci. Soc. Am. J. 55 (3): 787–794. https://doi.org/10.2136/sssaj1991 .03615995005500030026x. Mohammadinia, A., M. M. Disfani, D. Conomy, A. Arulrajah, S. Horpibulsuk, and S. Darmawan. 2019. “Utilization of alkali-activated fly ash for construction of deep mixed columns in loose sands.” J. Mater. Civ. Eng. 31 (10): 04019233. https://doi.org/10.1061/(ASCE)MT.1943-5533 .0002878. Navin, M. P. 2005. “Stability of embankments founded on soft soil improved with deep-mixing-method columns.” Doctoral Dissertation, Dept. of Civil Engineering and Environmental Engineering, Virginia Tech. Rogers, C. D. F., and S. Glendinning. 1997. “Improvement of clay soils in situ using lime piles in the UK.” Eng. Geol. 47 (3): 243–257. https://doi .org/10.1016/S0013-7952(97)00022-7. Sherwood, P. T. 1993. Soil stabilization with cement and lime—State of the art review. London: Transport Research Laboratory, Dept. of Transport, HMSO publications. Soil Science Glossary Terms Committee and Soil Science Society of America. 2008. Glossary of soil science terms 2008. Madison, WI: Soil Science Society of America. Subramaniam, P., and S. Banerjee. 2020. “Dynamic properties of cementtreated marine clay.” Int. J. Geomech. 20 (6): 04020065. https://doi.org /10.1061/(ASCE)GM.1943-5622.0001673. Terashi, M. 1997. “Theme lecture: Deep mixing method—Brief state of the art.” In Vol. 4 of Proc. 14th Int. Conf. on Soil Mech. and Found. Eng., 2475–2478. Rotterdam, Netherlands: A.A. Balkema. Watabe, Y., and T. Noguchi. 2011. “Site-investigation and geotechnical design of D-runway construction in Tokyo Haneda airport.” Soils Found. 51 (6): 1003–1018. https://doi.org/10.3208/sandf.51.1003. 04022063-10 J. Geotech. Geoenviron. Eng., 2022, 148(8): 04022063 J. Geotech. Geoenviron. Eng. Downloaded from ascelibrary.org by Hong Kong University of Sci and Tech (HKUST) on 11/07/22. Copyright ASCE. For personal use only; all rights reserved. Wijerathna, M., and D. S. Liyanapathirana. 2018. “Reliability-based performance of embankments improved with deep mixing considering spatial variability of material properties.” ASCE-ASME J. Risk Uncertainty Eng. Syst. Part A: Civ. Eng. 4 (4): 04018035. https://doi.org/10.1061 /AJRUA6.0000987. Wijerathna, M., and D. S. Liyanapathirana. 2019. “Significance of spatial variability of deep cement mixed columns on reliability of columnsupported embankments.” Int. J. Geomech. 19 (8): 04019087. https://doi .org/10.1061/(ASCE)GM.1943-5622.0001473. Yang, T., J. Z. Yang, and J. Ni. 2014. “Analytical solution for the consolidation of a composite ground reinforced by partially penetrated impervious columns.” Comput. Geotech. 57 (Apr): 30–36. https://doi.org/10 .1016/j.compgeo.2014.01.001. © ASCE Yapage, N. N. S., D. S. Liyanapathirana, R. B. Kelly, H. G. Poulos, and C. J. Leo. 2014. “Numerical modeling of an embankment over soft ground improved with deep cement mixed columns: Case history.” J. Geotech. Geoenviron. Eng. 140 (11): 04014062. https://doi.org/10 .1061/(ASCE)GT.1943-5606.0001165. Yin, J. H., and Z. Fang. 2006. “Physical modelling of consolidation behavior of a composite foundation consisting of cement-mixed soil column and untreated soft marine clay.” Geotechnique 56 (1): 63–68. https://doi .org/10.1680/geot.2006.56.1.63. Zhao, H. F., L. M. Zhang, and D. S. Chang. 2013. “Behavior of coarse widely graded soils under low confining pressures.” J. Geotech. Geoenviron. Eng. 139 (1): 35–48. https://doi.org/10.1061/(ASCE)GT.1943 -5606.0000755. 04022063-11 J. Geotech. Geoenviron. Eng., 2022, 148(8): 04022063 J. Geotech. Geoenviron. Eng.