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Periodic Properties - UA

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Ipm 10
1A* 10'
=
Calculation of Period/ Group No.
Period
no:
Group
no:
Highest
-
Top
e-if-subshell
Zoff
left
no
1 to 6
x 1, 2
=
Gp.10
ns*+(n-1)d*
Go no. x+ y
npt
Gp.NO
x
=
=
Group
12 + x
-
Zeff (Effective nuclear charge)
sypsd f
Poor
Fully filled
orbitals
provide
>
Atomic
rc
<
Covalent
Radius
Um<Uy
>
>
better
Zeff
=
hun
Right
<
A
re=
Cation
=
e--e-
-
repulsion
At
same
species
·
Ionisation Potential
Metallic
Energy
Vander Waals
of e-,-ve charge
charge - 1
Heterodiatomic
-
3)
EN =0
P
2. I
·
BE
eg. PH
p-n=up+
un
FO eg.
Factors
affecting
+ve
H-F
..
to
atom
&
2)Size 2
A B
needed
gaseous
) Zeff
-
ve
Anion
charge
IE
2
charge
e-from
H:
always
an
isolated
the
I.E:
5)
I.E
Radius
Radius
an
remove
Ionic
4) Stable Configuration <I.E
Peneration Effect2 IE
I.E
1
-
no
Ionic
Covalent
2
A
Cation
size 4
+ ye
Radius
+
e-
I
site t
Effective Zeff*
Parentatom
A
He 4p
Up
Isoelectronic
Anion
A
shielding
Homodiatomic
AA
size
Ions
·
Zeffdominate
shielding
*
of A, B
shells k
Ionic Radius
ne<Mp
Power:
of
&
Bottom
3
At
Screening
Electronegativity
size
Always
=
un,"B:
General Trend
f-block
d-block
=
Schomaker
=
Last ets-subshell last :p-subshell laster:d-subshell last
ngx
10-m
Equation
GA-B eA+VB-0.9/k-4B
Bonk
GA-B=
length (A-B) VA/Us=radius of AlB
Stevenson
'n' value.
p-block
S-Block
(um=
=
-<p> d> f
I. E
n Sam2
=
>
Be
2
252
n
21 0
=
=
1- diff
B
2p
2(1
n=
=
p3
d5
pC
b10
For 2"*
3
Li
Period
Be
<
>
4
2s
5
B
-6
2p
252
n
-
N s0<
Factors
F NR
9
10
2p6
2p5
2p32pY
↓
2p2
n=
2
·
halffilled
2
=
11
=
Top left
PE
<
Zeff
·
Bc
NCF
c < 0 <
<
Successive I.E:IE, IEIE3
Right
IEK
·
Min IP in
Bottom
Blockwise
gas
any
Period:Alkali metal
any
Man IP
in
Min IP
in
Comparison
any
any
Period
-
period
-........
3523p5
Re
&
Ga
Al
In
of
the
greater tendency
to
charge. Exx1-ve charge
Filled
Br> I
> F>
Similarly Onygen family
>0
53Se>
size
↳ small
->
e,repulsion
EGE N
TiV Cr Ni
Fe
Electronegativity
.. a
.
Zeff ENC"/size
EN
201-ve 0.S
EN2
·
a
ENGYs-character
-
EN2
-.
_I
.
__E!
------
In
3d series
<Fe>
c0
> (n
>
Mn> Ti>
Ni>
y> Cr
Applications of Electronegativity
Calculations of bond
length CAB
Sc
>
·
Electron affinity or Electron gain Enthalpy
be
·Heg:may
A t
EA
The energy
released
2
-
k
=
·
(g)
-500 K5 mol-
EGE
energy changed
The
-Meg
=
-500
EGE
The
entrally change
F
2522p5
e
+
-
when
F-
->
an e-
①Heg=-
EA
a neutral
is added
to
(Noblegas).
If
stable
&2522p6
ve
-
will
e
is
be
gaseous
-
character
atom
successfully added, the energy
is
released and EGE
generally-ve
1IC:
U+VB-0.0914n-uBl
=
16(4- YB)
+ 3.5
B
YA-VB
VA-4B
=
=
1 Ionic
A
or the
ve
A
-
&H
I
Eq 5 00
-
Te
2522p5
B
Th
gaine-
(ns2)
F
And to k
·
Family
Alkaline Earth Metal
CIS
shows
configuration
gases
half filled
N
Halogens:2
Is
Elements
Boron
Noble
Fully
He
-
M
IE.----
·
period:Inert
Max IP in
Size 4 I.E
Enx/size
Zeff
stable
Ex
·
-
1. <B
EAC
=
10
ofsteg
affecting EA
Here-ve value
UA-UB
> 1.7
Ionic
< 1.7
1.7
=
covalent
50% Ionic
+
50% Covalent
(4-4B)2
the
0.S
r e
·
Mendeleev’s Periodic Table
Acidic and Basic Nature of oxides
Non-metals
"termost
↓
HPOn
ne
+2
the physical andchemicalproperties
Table
1) It is basedonatomic
2) 63 elements were known,
gases
3)
I
columns
6) Eachgroup upto
He
was
systematic
Horizontal
4)
are
the
is scientist to
manner
rows
is
are
classify
in horizontal
called
series
called
VIIt
is
groups
weight
noble
weren'tdiscovered.
rows
and
the elements
in
a
and vertical columns
there
periods
were I
Mendeley's Periodic Table
in
5) Vertical
are
periodic
Characteristics of
Mendeleev's
BizO3
3
elements
of
and there were 8
divided into A and B
groups in Mendlee'speriodic Table
subgroups. Asubgroup elements
called transition elements
called normal elements, and B group elements are
VIII
in 3 rows.
2) The
group consist a elements
to same
exhibit similar
8) The elements
are
belonging
of
group
properties.
Modern Periodic Table
Moseley did an experiment
differentmetal surfaces
on
Characteristic
a
·
verticals
ist
·
called
gases
group
were
·7
Horizontal
to
groups of
·
·
It is
It
is
also called
based
I
Periods
and
on
18
as
the
inert
Modern
"Bour-Bury
columns
by Ramsay,
Periodic Table
and
atomic number
vertical
gases
Periodic Table
in
periods
called
long form/Presentform of
·
Table
Groups.
introduced
Rows
highspeed
X-Rays.
ofModern Periodic
columns
XIII
to
Inert
·
bombarded
andobtained
in whichhe
Rang,
(groups)
Herner
Periodic
Table
e-
I
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