Thermodynamics 1 Otto Cycle, Diesel Cycle & Dual Combustion Cycle Internal combustion engine is a heat that derives its power from the energy liberated by the explosion of a mixture gaseous of or some hydrocarbon, vaporized atmospheric air. form, in with Spark – Ignition (SI) or Gasoline Engine Four-Stroke Cycle Gasoline Engine Intake stroke - piston moves down the cylinder and draws in fuel-air mixture Compression stroke - piston compresses the mixture in the cylinder and the spark plug ignites the mixture Power stroke - burning gases push the piston down Exhaust stroke - piston pushes the burned gases out Four strokes of the piston and two revolutions are required to complete a cycle. Air-Standard Otto Cycle 1-2: isentropic compression 2-3: constant volume addition of heat 3-4: isentropic expansion 4-1: constant volume rejection of heat Air-standard cycle means that air alone is the working medium QA = mcv (T3 – T2) QR = mcv (T1 –T4) = -mcv (T4 – T1) W = QA – QR = mcv (T3 – T2) – mcv (T4 – T1) e= W QA mcv T3 −T2 − mcv (T4 −T1 ) = mcv (T3 −T2 ) T4 −T1 = 1{1} T3 −T2 1 =1- where rk = x 100 rkk−1 π1 , π2 the isentropic compression ratio Derivation of the formula for e: Process 3-4: Process 1-2: • π2 π1 = V1 V2 • k−1 Process 3-4: • = V4 k−1 V3 = V4 k−1 V3 = V1 k−1 V2 • T3 = T4rk k−1 {3} • T2 = T1rk k−1 {2} π3 π4 π3 π4 = V1 k−1 V2 • T3 = T4rk k−1 {3} Substituting equations {2} and {3} in equation {1} e = 1e=1- T4 −T1 T4 rkk−1 −T1 rkk−1 1 rkk−1 Work from the pV plane: p V −p V p V −p V W = ∑W = 2 2 1 1 + 4 4 3 3 1−k 1−k Clearance volume, percent clearance rk = V1 V2 = VD + V3 V3 = VD + cVD cVD = 1+c c Where: c = percent clearance V3 = clearance volume VD = displacement volume Ideal standard of comparison Cold-air standard, k = 1.4 Hot air standard, k < 1.4 The thermal efficiency of the theoretical Otto cycle is • Increased by increase in rk • Increased by increase in k • Independent of the heat added “The average family car has a compression ratio of about 9:1. The economic life of the average car is 8 years or 80,000 miles of motoring.” Sample Problem 1: Otto Cycle 1. An Otto cycle operates on 0.1 lb/s of air from 13psia and 130°F at the beginning of compression. The temperature at the end of combustion is 5000°R; compression ratio is 5.5; hot-air standard k = 1.3. (a) Find V1, p2, t2, p3, V3, t4, and p4. (b) Compute QA, QR, W, e, and the corresponding hp Sample Problem 1: Otto Cycle Point 3: Solution m = 0.1 lb/s rk = 5.5 k = 1.3 p1 = 13psia T1 = 130 + 460 = 590°R T3 = 5000°R V1 = αΉπΉπ»π ππ p 2 = p1 T2 = T1 = (π.π)(ππ.ππ)(πππ) (ππ)(πππ) = 1.681 π½π π½π π V2 = π½π ππ πππ π = p1(rk)k = (13)(5.5)1.3 π½π π−π π½π = ππ π»π πππ π = (5000) πππ.π πππ.π = 605.8psia π½π π−π π π.π−π T4 = T3 = (5000) = 2998°R π½π π.π π ππ p4 = T4 π = (2998) = 66.1psia π»π πππ b) cv = πΉ π−π = ππ.ππ (πππ)(π.π−π) = 0.2285 π©ππ πππΉ° QA = mcv(T1 – T4) = (0.1)(0.2285)(5000 – 983.9) π.πππ π.π = T1(rk)k-1 = (590)(5.5)1.3-1 = 0.3056 π©ππ = 91.77 π QR = mcv(T1 – T4) = (0.1)(0.2285)(590 – 2998) = -55.03 = 983.9°R = 523.9°F • p3 = T3 • = 119.2psia • • • Point 2: • V3 = V2 = 0.3056 Point 4: a) Point 1: • • αΊ = QA –QR = 91.77 – 55.03 = 36.75 e= πππ π π©ππ π W= πΎ πΈπ¨ = ππ.ππ ππ.ππ = 0.4005 or 40.05% π©ππ π )(ππ ) π πππ π©ππ ππ.π (πππ)(ππ) (ππ.ππ = 52hp π©ππ π Sample Problem 2: Otto Engine 2. The conditions at the beginning of compression in an Otto engine operating on hot-air standard with k = 1.34, are 101.3kPa, 0.038m3 and 32°C. The clearance is 10% and 12.6kJ are added per cycle. Determine (a) V2, T2, p2, T3, p3, T4 and p4, (b) W, (c) e, and (d) pm. Sample Problem 2: Otto Engine Solution p1 = 101.3kPa V1 = 0.038m3 T1 = 32°C + 273 = 305K cv = πΉ π−π = π.πππππ π.ππ−π m= ππ π½π ππ»π = (πππ.π)(π.πππ) (π.πππππ)(πππ) = ππ± 0.8444 πππ² = 0.04396 kg rk = π+π π = π + π.ππ π.ππ • = π.πππ ππ V2 = • • T2 = T1rkk-1 = p2 = p1rk k = = 0.003455m3 (305)(11)1.34-1 = 689 K (101.3)(11)1.34 = 2518 kPa π»π π»π = (2518) ππππ πππ = 3757kPa Point 4: • T4 = T3 π½π π−π π½π = T3 π π−π ππ = (1028) π π.ππ−π ππ = 455 K • • p3 = p2 = 11 a) Point 2: π½π ππ Point 3: QA = mcv (T3 – T2) 12.6 = (0.04396)(0.8444)(T3 – 689) • T3 = 1028 K p4 = p3 π½π π π½π = p3 π π−π ππ = (3757) π π.ππ ππ = 151 kPa b) QR = mcv (T1 – T4) = (0.04396)(0.8444)(305 – 455) = -5.57kJ W = QA – QR = 12.6 – 5.57 = 7.03 kJ c) e = πΎ πΈπ¨ d) pm = = πΎ π½π« π.ππ ππ.π = = 0.558 or 55.8% πΎ π½π − π½π = ππ.π π.πππ−π.ππππππ = 364.7kPa Compression Ignition or Diesel Engine Four-Stroke Cycle Diesel Engine Intake stroke - piston moves down and draws air into the cylinder Compression stroke - piston rises and compresses the air to a temperature of about 900°F (480°C) Power stroke - oil is injected into the cylinder, it mixes with the hot air and burns explosively Exhaust stroke - gases produced by combustion push the piston up and forces the burned gases out of the cylinder Air-Standard Diesel Cycle 1-2: isentropic compression 2-3: constant pressure addition of heat 3-4: isentropic expansion 4-1: constant volume rejection of heat Air-standard cycle means that air alone is the working medium QA = mcp (T3 – T2) QR = mcv (T1 – T4) = -mcv (T4 – T1) W = QA – QR = mcp (T3 – T2) – mcv (T4 –T1) e= W QA = mcp (T 3− T2 )− mcv (T4 − T1 ) mcp (T3 − T2 ) =1- T4 − T1 k(T3 − T2 ) =1- rck −1 rkk−1 k(rc −1) {4} 1 V1 V2 V3 V2 where rk = is the compression ratio and rc = is the cutoff ratio and Point 3 is called the cut-off point. Derivation of the formula for e: Process 1-2: • π2 π1 = • V1 k−1 V2 • T2 = T1 (rkk-1) π3 π2 = V3 V2 {5} = rc • T3 = T1 (rkk-1) (rc) π4 π3 = • T4 = Process 2-3: • Process 3-4: {6} V3 k−1 V4 T1 (rkk-1) = V2 rc k−1 V1 (rc) = rck−1 rkk−1 rck−1 rkk−1 • T4 = T1 (rck) {7} Substituting equations {5}, {6} and {7} in equation {4} e=1- e=1- T1 (rck )− T1 k T1 rkk−1 rc − T1 (rkk−1 ) rck −1 rkk−1 k(rc −1) 1 Relation among rk, rc and re (expansion ratio) re = rk = π4 π3 π1 π2 = = π1 π3 π3 π2 π1 π3 rk = (rc)(re) The efficiency of the Diesel cycle differs from that of the Otto cycle by the bracketed factor rck −1 . k(rc −1) This factor is always greater than 1, because rc is always greater than 1. Thus, for a particular compression ratio rk, the Otto cycle is more efficient. However, since the Diesel engine compresses air only, the compression ratio is higher than in an Otto engine. “An actual Diesel engine with a compression ratio of 15 is more efficient than an actual Otto engine with a compression ratio of 9.” Sample Problem 1: Diesel Cycle 1. A Diesel cycle operates with a compression ratio of 13.5 and with a cut-off occurring at 6% of the stroke. State 1 is defined by 14 psia and 140°F. For the hot-air standard with k = 1.34 and for an initial 1 cu ft., Compute (a) t2, p2, V2, t3, V3, p4, and t4, (b) QR, (c) W, (d) e and pm (e) For a rate of circulation of 1000cfm, compute the horsepower Sample Problem 1: Diesel Cycle Solution a) Point 2: rk = 13.5 • T1 = 140+460 = 600°R V1 = 1 cu ft. = ππ.ππ (πππ)(π.ππ−π) = π©ππ 0.2016 π₯ππ° cp = kcv = (1.34)(0.2016) = m= π©ππ 0.2702 π₯ππ° ππ π½π ππ»π = π ππ.π = 0.0741 ft3 T2 = T1 (rkk-1) = (600) (13.5)1.34 – 1 = 1454°R = 994°F • p2 = p1 (rkk-1) = (14) (13.5)1.34 = 457.9psia Point 3: • V3 = V2 + 0.06VD = V2 + 0.06(V1 – V2) • V3 = 0.0741 + (0.06) (1 – 0.0741) = 0.1297 ft3 p1 = 14psia cv = π½π ππ • k = 1.34 πΉ π−π V2 = = (ππ)(πππ)(π) (πππ)(ππ.ππ) • π½π π−π π½π = (1454) π.ππππ π.ππππ = 2545°R = 2085°F Point 4: • • = 0.630lb T3 = T2 T4 = p4 = π½π π−π T3 π½π π½π π p3 π½π = (2545) = (457.9) π.ππππ π.ππ−π π π.ππππ π.ππ π = 1271°R = 811°F = 29.7psia Sample Problem 1: Diesel Cycle b) QA = mcp (T3 – T2) = (0.063) (0.2702) (2545 – 1454) = 18.57 Btu QR = mcv (T1 – T4) = (0.063) (0.2016) (600 – 1271) = 8.52Btu c) W = QA – QR = 18.57 – 8.52 = 10.05Btu d) e = e) W = πΎ πΈπ¨ = ππ.ππ ππ.ππ = 0.5412 or 54.12% and pm = πππ πππππππ π©ππ ππ.ππππ ππ π©ππ ππ.ππ π ππ = 237hp ππ.ππ (πππ) π−π.ππππ (πππ) = 58.64psi Sample Problem 2: Diesel Engine 2. There are supplied 317 kJ/cycle to an ideal Diesel engine operating on 227 g air: p1 = 97.91kPa, t1 = 48.9°C. At the end of compression, p2 = 3930kPa. Determine (a) rk, (b) c, (c) rc, (d) W, (e) e, and (f) pm. Sample Problem 2: Diesel Engine Solution m = 0.227kg p1 = 97.91kPa T1 = 48.9 + 273 = 321.9 K p2 = 3930kPa QA = 317kJ/cycle • Point 1: • V1 = Point 2: • • π¦ππ»π ππ V2 = V1 T2 = T1 = π ππ π ππ (π.πππ)(π.πππππ)(πππ.π) ππ.ππ = (0.2143) π− π ππ π ππ = (321.9) ππ.ππ ππππ ππππ ππ.ππ π π.π = 0.2143 m3 = 0.0153m3 π.π−π π.π • V3 = = (0.0153) ππππ πππ.π a) rk = π½π π½π b) rk = π+π ; π = = (2312) π.ππππ π.ππππ π.ππππ π.π−π π.ππππ = 1161 K = 14 π+π π 14 = c = 0.0769 or 7.69% π½π π½π = π.ππππ π.ππππ = 2.50 d) QR = mcv (T1 – T4) = (0.227) (0.7186) (321.9 – 1161) = 924.4 K = 0.0383m3 π½π π−π π½π T4 = T3 c) rc = Point 3: QA = mcp (T3 – T2) 317 = (0.227) (1.0062) (T3 – 924.4) • T3 = 2312 K π» V2 π π»π Point 4: = -136.9kJ W = QA – QR = 317 – 136.9 = 180.1 kJ e) e = πΎ πΈπ¨ f) pm = πΎ π½π« = πππ.π πππ = = 0.5681 or 56.81% πΎ π½π − π½π = πππ.π π.ππππ− π.ππππ = 905kPa Dual Combustion Engine “In modern compression ignition engines the pressure is not constant during the combustion process. The major part of combustion can be considered to approach a constant-volume process, and the late burning, a constantpressure process.” Air-Standard Dual Cycle 1-2: isentropic compression 2-3: constant volume addition of heat 3-4: constant pressure addition of heat 4-5: isentropic expansion 5-1: constant volume rejection of heat Air-standard cycle means that air alone is the working medium QA = mcv(T3 – T2) + mcp (T4 – T3) QR = mcv (T1 – T5) = -mcv (T5 – T1) W = QA – QR = mcv (T3 – T2) = mcv (T4 – T3) – mcv (T5 – T1) e= W QA =1– =1– = mcv T3 − T2 +mcp T4 − T3 −mcv (T5 − T1 ) mcv T3 − T2 +mcp (T4 − T3 ) T5 − T1 T3 − T2 + k (T4 − T3 ) 1 {8} rp rkk−1 −1) rkk−1 rp −1+ rp k (rc − 1) p where rp = 3 is the pressure ratio during the constant volume portion of p2 V V combustion, rk = 1 is the compression ratio and rc = 4 is the cut-off ratio V2 V3 The thermal efficiency of this cycle lies between that of the ideal Otto and the ideal Diesel. Derivation of the formula for e: Process 4-5: Process 1-2: • T2 T1 = • T2 = T1rkk-1 Process 2-3: • T3 T2 = p3 p2 T4 T3 = V4 V3 {9} • T5 = = rp • T3 = T1rkk-1 (rp) Process 3-4: • • V1 k−1 V2 {10} = rc • T4 = T1rkk-1 (rp)(rc) V4 k−1 V4 k−1 = = V5 V1 V2 rc k−1 rck− 1 = k− 1 V1 rk T5 T4 T1rkk-1(rp)(rc) • T5= T1(rp)(rc) = V3 rc k−1 V1 = rck− 1 rkk− 1 {12} k Substituting equations {9}, {10}, {11} and {12} in equation {8} e= 1- {11} e = 1- π1 ππ ππ π − π1 π1 πππ− 1 ππ − π1 πππ−1 + π(π1 πππ−1 ππ ππ − π1 πππ−1 ππ ) 1 ππ ππ π −1 πππ−1 ππ −1 + ππ π(ππ −1) Sample Problem 1: Dual Cycle 1. At the beginning of compression in an ideal dual combustion cycle, the working fluid is 1 lb of air at 14.1 psia and 80°F. The compression ratio is 9, the pressure at the end of the constant volume addition of heat is 470psia, and there are added 100Btu during the constant pressure expansion. Find (a) rp, (b) rc, (c) the percentage clearance, (d) e and (f) pm Sample Problem 1: Dual Cycle Solution m = 1lb air p1 = 14.1 psia T1 = 80 + 460 = 540°R p3 = 470 psia rk = 9 Q3-4 = 100Btu Point 1: • V1 = π¦ππ»π ππ = π ππ.ππ (πππ) ππ.π (πππ) π½π ππ ππ.πππ π = 14.186ft3 Point 2: • V2 = = • T2 = T1 π½π π−π π½π • p 2 = p1 π½π π π½π = 1.576ft3 = (540) (9)1.4 – 1 = 1300°R = (14.1) (9)1.4 – 1 = 305.6psia Point 3: • T3 = T2 ππ ππ = (1300) πππ πππ.π = ππππ°R Point 4: Q3-4 = (m) (cp) (T4 – T3) 100 = (1) (0.24) (T4 – 1999) • T4 = 2416°R • V4 = V3 π»π π»π = (1.576) ππππ ππππ = 1.905ft3 Point 5: • T5 = π½π π−π T4 π½π = (2416) π.πππ π.π−π ππ.πππ = 1082°R Sample Problem 1: Dual Cycle a) rp = ππ ππ = πππ πππ.π = 1.54 b) rc = π½π π½π = π.πππ π.πππ = 1.21 c) rk = π+π ; π 9= π+π π c = 0.125 or 12.5% d) QA = Q2-3 + Q3-4 = (m) (cv) (T3 – T2) + 100 = (1) (0.1714) (1999 – 1300) + 100 = 219.8Btu QR = (m) (cv) (T1 – T5) = (1) (0.1714) (540 – 1082) = -92.9Btu e= πΎ πΈπ¨ pm = πππ−ππ.π πππ.π = πΎ π½π − π½π = = 0.5773 or 57.73% πππ.π (πππ) ππ.πππ−π.πππ (πππ) = 54.37psi Sample Problem 2: Dual Cycle 2. An ideal dual combustion cycle operates on 454g of air. At the beginning of compression, the air is at 96.53kPa, 43.3°C. Let rp = 1.5, rc = 1.60 and rk = 11. Determine (a) the percentage clearance, b) p, V, and T at each corner of the cycle, (c) QA, (d) e, and (e) pm. Sample Problem 2: Dual Cycle Solution m = 0.454 kg of air p1 = 96.53 kPa T1 = 43.3 + 273 = 316.3 K rp = 1.5 rc = 1.60 rk = 11 a) b) π+π π+π rk = ; 11 = ; π π ππΉπ»π π.πππ V1 = = ππ V2 = π½π ππ T2 = T1 = π.ππππ ππ π½π π−π π½π = c = 0.10 or 10% π.πππππ (πππ.π) ππ.ππ = 0.4271m3 0.03883m3 = T1 (rk) k-1 = (316.3) (11) 1.4-1 = 825.4 K p2 = p 1 π½π π π½π = p1 (rk) k = (96.53) (11)1.4 = 2770.8kPa p3 = (p2) (rp) = (2770.8) (1.5) = 4156.2 kPa ππππ.π ππππ.π ππ ππ = (825.4) T4 = T3 π½π π½π = (1238.1) (1.6) = 1981 K T5 = T4 π½π π−π π½π T3 = T2 = 1238.1 K V4 = (V3) (rc) = (0.03883) (1.60) = 0.06213m3 p5 = p1 π»π π»π = (1981) = (96.53) π.πππππ π.π−π π.ππππ πππ.π πππ.π = 916.2 K = 279.6kPa c) QA = (m) (cv) (T3 – T2) + (m) (cp) (T4 – T3) = (0.454)(0.7186)(1238.1 – 825.4) + (0.454) (1.0062) (1981 – 1238.1) = 474 kJ d) QR = (m) (cv) (T1 – T5) = (0.454)(0.7186)(316.3 – 916.2) = 195.7kJ W = QA – QR = 474 – 195.7 = 278.3 kJ e= πΎ πΈπ¨ e) pm = = πππ.π πππ πΎ π½π − π½π = = 0.5871 or 58.71% πππ.π π.ππππ − π.πππππ = 716.8kPa Thermodynamics 1 Reference: Sta. Maria, H. B. (1990). Thermodynamics 1. Mandaluyong City, Philippines: National Book Store. Presentation made by David Anthony C. Manalo & Gino Carlo O. Cadao